US4100039A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for plating palladium-nickel alloy
Assignee: International Business Machines Corp
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Filing: 1976-11-11
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Granted: 1978-07-11
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Expires: 1996-11-11
Abstract
Abstract A palladium-nickel alloy is plated on electrical components, such as frames, pins, connectors and in general various types of electrical contacts. The palladium-nickel alloys are deposited from a plating bath containing a palladosammine chloride, nickel sulfamate, ammonium sulfamate and ammonium hydroxide, the latter operative to solubilize the metals into the ammonia complex and to maintain the necessary bath pH. The bath can be used for either rack plating at current densities of 10 to 25 amperes per square foot or to barrel plate at a plating current of 1 to 3 amperes per square foot.
Inventors
- 👤 Jerome Joseph Caricchio, Jr.
- 👤 Edward Robert York
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 13:59
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/56; C25D3/567
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
177 words
A method for depositing a palladium-nickel alloy on a substrate, comprising the steps of: subjecting an anode to an aqueous bath solution consisting essentially of 3 to 6 grams per liter of palladium ion derived from palladosammine chloride, about 12 grams per liter of nickel ion derived from the group consisting of nickel sulfamate, nickel chloride and nickel sulfate, from 10 to 50 grams per liter of ammonium sulfamate, ammonium sulfate or ammonium chloride, between 1 and 1000 parts per million of a sulfite ion derived from sodium sulfite and sufficient 29% ammonium hydroxide to solubilize the palladium and nickel metal ions into soluble ammonia complexes and to maintain a pH between 8.8 and 9.6; immersing the substrate to be coated in said solution and in spaced relation to said anode; applying a plating current density of 0.3 to 3.0 amperes per square decimeter to said solution and substrate; agitating both said solution and substrate; and maintaining said solution at ambient temperature and without increasing the above concentrations of ingredients in the bath during the plating process.
Claim 2
Independent Claim
177 words
A method for depositing a palladium-nickel alloy on a substrate, comprising the steps of: subjecting an anode to an aqueous bath solution consisting essentially of 3 to 6 grams per liter of palladium ion derived from palladosammine chloride, about 12 grams per liter of nickel ion derived from the group consisting of nickel sulfamate, nickel chloride and nickel sulfate, from 10 to 50 grams per liter of ammonium sulfamate, ammonium sulfate or ammonium chloride, between 1 and 1000 parts per million of a sulfite ion derived from sodium sulfite and sufficient 29% ammonium hydroxide to solubilize the palladium and nickel metal ions into soluble ammonia complexes and to maintain a pH between 8.8 and 9.6; immersing the substrate to be coated in said solution and in spaced relation to said anode; applying a plating current density of 0.3 to 3.0 amperes per square decimeter to said solution and substrate; agitating both said solution and substrate; and maintaining said solution at ambient temperature and without increasing the above concentrations of ingredients in the bath during the plating process.
Claim 3
Dependent Claim
34 words
The invention according to claim 1 wherein said palladium and nickel ion concentrations are chosen, respectively, to yield between 75% and 50% palladium and between 25% and 50% nickel in the plated palladium-nickel alloy.
Claim 4
Dependent Claim
18 words
The method according to claim 1 wherein the solution is maintained at a pH between 9.0 and 9.3.
Claim 5
Dependent Claim
22 words
The method according to claim 1 wherein said solution consists of palladosammine chloride, nickel sulfamate, ammonium sulfamate, sodium sulfite and ammonium hydroxide.
Claim 6
Dependent Claim
27 words
The method according to claim 1 wherein said substrate surface is formed of a metal chosen from the group consisting of nickel, copper and a copper-beryllium alloy.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-10 | 1982-01-09 | 1982-07-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-10 | 1986-01-09 | 1986-07-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-10 | 1990-01-09 | 1990-07-11 | $7700.00 | Window Closed / Lapsed |