US4098996A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Regenerated cellulose film recovery process
Assignee: FMC Corp
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Filing: 1977-02-22
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Granted: 1978-07-04
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Expires: 1997-02-22
Abstract
Abstract Waste raw uncoated and/or coated (such as saran, nitrocellulose and vinyl) regenerated cellulose film is treated to recover its plasticizer and cellulose components for recycling in the manufacture of regenerated cellulose film. The platicizer is first recovered from comminuted waste film particles via extraction with water. The moist comminuted film particles are then converted to viscose, from which coating solids, if any, are removed. The viscose is thereafter employed in the manufacture of regenerated cellulose film.
Inventors
- 👤 Daniel John Ryan
- 👤 Edward Andrew Wielicki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 06:04
CPC Classifications
C; C08; C08J; C08J11/00; C08J11/04; C08B; C08B16/00; C08J2301/00; C08J2301/06; Y; Y02; Y02P; Y02P20/00; Y02P20/141; Y02P20/143; Y02W; Y02W30/00; Y02W30/50; Y02W30/62; Y10; Y10S; Y10S264/00; Y10S264/911; Y10S264/913; Y10S264/914
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
113 words
A process for recovering regenerated cellulose from plasticized regenerated cellulose film, at least a portion being coated film, which comprises (a) comminuting the regenerated cellulose film; (b) extracting the plasticizer from the comminuted cellulose film particles by leaching the cellulose with water at a temperature of between 5° C. to 70° C.; (c) after leaching, steeping the still moist comminuted cellulose film particles in caustic soda solution to form an alkali cellulose and thereafter xanthating the alkali cellulose with carbon bisulfide to provide a viscose which contains undissolved coating solids; and (d) separating the coating solids from the viscose thereby obtaining a viscose suitable for use in the manufacture of regenerated cellulose film.
Claim 2
Dependent Claim
113 words
A process for recovering regenerated cellulose from plasticized regenerated cellulose film, at least a portion being coated film, which comprises (a) comminuting the regenerated cellulose film; (b) extracting the plasticizer from the comminuted cellulose film particles by leaching the cellulose with water at a temperature of between 5° C. to 70° C.; (c) after leaching, steeping the still moist comminuted cellulose film particles in caustic soda solution to form an alkali cellulose and thereafter xanthating the alkali cellulose with carbon bisulfide to provide a viscose which contains undissolved coating solids; and (d) separating the coating solids from the viscose thereby obtaining a viscose suitable for use in the manufacture of regenerated cellulose film.
Claim 3
Dependent Claim
31 words
The process as defined in claim 1 wherein the plasticizer in the plasticized regenerated cellulose film is selected from the group consisting of polyethylene glycol, polypropylene glycol, glycerine, and mixtures thereof.
Claim 4
Dependent Claim
31 words
The process as defined in claim 1 wherein the coating on the film consists essentially of a material selected from the group consisting of nitrocellulose, polyvinylidene chloride, polyvinyl chloride and polyethylene.
Claim 5
Dependent Claim
16 words
The process as defined in claim 3 wherein all of the regenerated cellulose film is coated.
Claim 6
Dependent Claim
43 words
The process as defined in claim 1 wherein all of the comminuted cellulose film particles are less than 1/4 inch in their largest dimension and at least 90% by weight of such particles pass through a sieve of U.S. Sieve No. 10 mesh.
Claim 7
Dependent Claim
29 words
The process as defined in claim 1 wherein the plasticizer is leached from the comminuted cellulose film particles with water at a temperature of from 15° to 40° C.
Claim 8
Dependent Claim
70 words
The process as defined in claim 6 wherein the leaching of the plasticizer from the comminuted cellulose film particles with water is accomplished by countercurrent extraction so as to obtain an aqueous plasticizer extract which contains at least 5% by weight plasticizer, based on the weight of the extract, and cellulose particles which contain less than 1% by weight residual plasticizer after leaching, based on the weight of the cellulose.
Claim 9
Dependent Claim
47 words
The process as defined in claim 7 which further comprises (a) concentrating the aqueous plasticizer extract to a concentration of at least 10% by weight plasticizer, based on the weight of the extract, and (b) recycling the aqueous plasticizer concentrate into a regenerated cellulose film plasticizer bath.
Claim 10
Dependent Claim
19 words
The process as defined in claim 1 wherein the undissolved coating solids are separated from the viscose by centrifugation.
Claim 11
Dependent Claim
103 words
The process as defined in claim 1 wherein at least some of the coated film is coated with a coating consisting essentially of polyvinylidene chloride and which further comprises (a) washing the undissolved coating solids with water to remove residual viscose; (b) contacting the washed undissolved coating solids with a butyl acetate/toluene solvent mixture to selectively dissolve non-polyvinylidene chloride components from such solids; (c) thereafter contacting the undissolved coating solids with a tetrahydrofuran solvent to form a solution containing polyvinylidene chloride; and (d) recycling the polyvinylidene chloride solution into a polyvinylidene chloride-coating bath for use in preparing polyvinylidene chloride coated regenerated cellulose film.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-03 | 1982-01-02 | 1982-07-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-03 | 1986-01-02 | 1986-07-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-03 | 1990-01-02 | 1990-07-04 | $7700.00 | Window Closed / Lapsed |