Perfluoroalkylthioamido amine and ammonium compounds

Claim 1

A compound having the structure ##STR5## wherein R f is straight or branched chain perfluoroalkyl of 1 to 18 carbon atoms or said perfluoroalkyl substituted by perfluoroalkoxy of 2 to 6 atoms; R 1 is branched or straight chain alkylene of 1 to 12 carbon atoms, alkylenethioalkylene of 2 to 12 carbon atoms, alkyleneoxyalkylene of 2 to 12 carbon atoms of alkyleneiminoalkylene of 2 to 12 carbon atoms where the nitrogen atom contains as a third substituent hydrogen of alkyl of 1 to 6 carbon atoms; R 2 is hydrogen or straight or branched chain alkyl of 1 to 6 carbon atoms; R 3 and R 4 each is independently straight or branched chain alkylyl of 1 to 22 carbon atoms; R 5 is hydrogen or straight or branched chain alkyl of 1 to 6 carbon atoms, or R 5 is a covalent bond if a heterocyclic ring formed between the two nitrogens as defined below; R 6 is hydrogen or straight or branched chain alkyl of 1 to 22 carbon atoms that may also contain 1 or 2 hydroxyl groups, a free carboxylic acid group, an anionic function selected from sulfonate, sulfate, or carboxylate, or oxygen; E is a straight or branched chain alkylene of 1 to 12 carbon atoms or alkylene polyoxyalkylene of formula C.sub.m H.sub.2m (OC.sub.k H.sub.2k).sub.r where m is an integer of 1 to 12 k is an integer of 2 to 6 r is an integer of 1 to 40; X is an anion selected from the group consisting of Br, Cl, I, acetate, phosphate, sulfate, methosulfate or ethosulfate; y is 1 to 2, depending on the valence of X, and z is 0 or 1, with the proviso that when z is 0, y is 1 and R 6 must be oxygen or an anionic function; if z is 1 R 6 may not be oxygen.