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US4097437A Expired / Lapsed US ⏱️ 0.0 years remaining

Thixotropic aqueous coating composition of solubilized polymer with dispersion of quaternary ammonium clay in aliphatic hydrocarbon

Assignee: M&T Chemicals Inc
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Filing: 1977-05-27
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Granted: 1978-06-27
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Expires: 1997-05-27
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Abstract

Abstract Aqueous solutions of polymers are rendered thixotropic by addition of a dispersion in aliphatic hydrocarbon of quaternary ammonium modified smectite clay, monohydric alcohol, and cationic surfactant. Conventional soluble film forming polymers include polyvinyl alcohol, polyvinyl acetate, amine neutralized polyester, and acrylic and methacrylic acid copolymers. Also silica flatting agent, flow control agent, pigment, wax and aminoplast cross-linker can be added.

Inventors

  • 👤 Bhimashanker Gopal Dhake

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 02:17
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/04

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 213 words
A thixotropic aqueous coating composition comprising (1) from 15 to 25%, based on the weight of said composition, of a film-forming, solubilized polymer, (2) from 0.5 to 5%, based on the weight of said composition, of finely divided silica, (3) sufficient water to achieve a concentration of non-volatile materials of from 30 to 60%, based on the weight of said composition, (4) from 0.5 to 5%, based on the weight of said composition, of a smectite type clay which has been modified by reaction with a quaternary ammonium salt of the general formula R 2 1 R 2 2 N.sup.⊕ X.sup.⊖ wherein R 1 is alkyl and contains from 1 to 4 carbon atoms, R 2 is alkyl and contains from 12 to 20 carbon atoms and X is chlorine or bromine, said smectite clay being present as a dispersion in a water-immiscible liquid aliphatic hydrocarbon that constitutes from 1 to 10% of the total weight of said aqueous coating composition and boils within the range from 100° to 200° C. (5) from 0.1 to 1%, based on the weight of said composition, of a monohydric alcohol of a molecular weight from 32 to 118, and (6) from 0.5 to 5%, based on the total weight of said composition, of a cationic surfactant.
Claim 2
Dependent Claim 213 words
A thixotropic aqueous coating composition comprising (1) from 15 to 25%, based on the weight of said composition, of a film-forming, solubilized polymer, (2) from 0.5 to 5%, based on the weight of said composition, of finely divided silica, (3) sufficient water to achieve a concentration of non-volatile materials of from 30 to 60%, based on the weight of said composition, (4) from 0.5 to 5%, based on the weight of said composition, of a smectite type clay which has been modified by reaction with a quaternary ammonium salt of the general formula R 2 1 R 2 2 N.sup.⊕ X.sup.⊖ wherein R 1 is alkyl and contains from 1 to 4 carbon atoms, R 2 is alkyl and contains from 12 to 20 carbon atoms and X is chlorine or bromine, said smectite clay being present as a dispersion in a water-immiscible liquid aliphatic hydrocarbon that constitutes from 1 to 10% of the total weight of said aqueous coating composition and boils within the range from 100° to 200° C. (5) from 0.1 to 1%, based on the weight of said composition, of a monohydric alcohol of a molecular weight from 32 to 118, and (6) from 0.5 to 5%, based on the total weight of said composition, of a cationic surfactant.
Claim 3
Dependent Claim 15 words
An aqueous coating composition according to claim 1 wherein the film-forming polymer is a polyester.
Claim 4
Dependent Claim 13 words
An aqueous coating composition according to claim 1 wherein R 1 is methyl.
Claim 5
Dependent Claim 13 words
An aqueous coating composition according to claim 1 wherein R 2 is octadecyl.
Claim 6
Dependent Claim 22 words
An aqueous coating composition according to claim 1 wherein said liquid aliphatic hydrocarbon boils within the range from 179° to 198° C.
Claim 7
Dependent Claim 16 words
An aqueous coating composition according to claim 1 wherein said monohydric alcohol is methanol or ethanol.

References Cited (Backward Citations)

US2511895A Cited
US3631136A Cited
US3515689A Cited
US3887645A Cited
US3974125A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-26 1981-12-26 1982-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-26 1985-12-26 1986-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-26 1989-12-26 1990-06-27 $7700.00 Window Closed / Lapsed

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