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US4097437A
Expired / Lapsed
US
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Thixotropic aqueous coating composition of solubilized polymer with dispersion of quaternary ammonium clay in aliphatic hydrocarbon
Assignee: M&T Chemicals Inc
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Filing: 1977-05-27
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Granted: 1978-06-27
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Expires: 1997-05-27
Abstract
Abstract Aqueous solutions of polymers are rendered thixotropic by addition of a dispersion in aliphatic hydrocarbon of quaternary ammonium modified smectite clay, monohydric alcohol, and cationic surfactant. Conventional soluble film forming polymers include polyvinyl alcohol, polyvinyl acetate, amine neutralized polyester, and acrylic and methacrylic acid copolymers. Also silica flatting agent, flow control agent, pigment, wax and aminoplast cross-linker can be added.
Inventors
- 👤 Bhimashanker Gopal Dhake
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 02:17
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/04
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
213 words
A thixotropic aqueous coating composition comprising (1) from 15 to 25%, based on the weight of said composition, of a film-forming, solubilized polymer, (2) from 0.5 to 5%, based on the weight of said composition, of finely divided silica, (3) sufficient water to achieve a concentration of non-volatile materials of from 30 to 60%, based on the weight of said composition, (4) from 0.5 to 5%, based on the weight of said composition, of a smectite type clay which has been modified by reaction with a quaternary ammonium salt of the general formula R 2 1 R 2 2 N.sup.⊕ X.sup.⊖ wherein R 1 is alkyl and contains from 1 to 4 carbon atoms, R 2 is alkyl and contains from 12 to 20 carbon atoms and X is chlorine or bromine, said smectite clay being present as a dispersion in a water-immiscible liquid aliphatic hydrocarbon that constitutes from 1 to 10% of the total weight of said aqueous coating composition and boils within the range from 100° to 200° C. (5) from 0.1 to 1%, based on the weight of said composition, of a monohydric alcohol of a molecular weight from 32 to 118, and (6) from 0.5 to 5%, based on the total weight of said composition, of a cationic surfactant.
Claim 2
Dependent Claim
213 words
A thixotropic aqueous coating composition comprising (1) from 15 to 25%, based on the weight of said composition, of a film-forming, solubilized polymer, (2) from 0.5 to 5%, based on the weight of said composition, of finely divided silica, (3) sufficient water to achieve a concentration of non-volatile materials of from 30 to 60%, based on the weight of said composition, (4) from 0.5 to 5%, based on the weight of said composition, of a smectite type clay which has been modified by reaction with a quaternary ammonium salt of the general formula R 2 1 R 2 2 N.sup.⊕ X.sup.⊖ wherein R 1 is alkyl and contains from 1 to 4 carbon atoms, R 2 is alkyl and contains from 12 to 20 carbon atoms and X is chlorine or bromine, said smectite clay being present as a dispersion in a water-immiscible liquid aliphatic hydrocarbon that constitutes from 1 to 10% of the total weight of said aqueous coating composition and boils within the range from 100° to 200° C. (5) from 0.1 to 1%, based on the weight of said composition, of a monohydric alcohol of a molecular weight from 32 to 118, and (6) from 0.5 to 5%, based on the total weight of said composition, of a cationic surfactant.
Claim 3
Dependent Claim
15 words
An aqueous coating composition according to claim 1 wherein the film-forming polymer is a polyester.
Claim 4
Dependent Claim
13 words
An aqueous coating composition according to claim 1 wherein R 1 is methyl.
Claim 5
Dependent Claim
13 words
An aqueous coating composition according to claim 1 wherein R 2 is octadecyl.
Claim 6
Dependent Claim
22 words
An aqueous coating composition according to claim 1 wherein said liquid aliphatic hydrocarbon boils within the range from 179° to 198° C.
Claim 7
Dependent Claim
16 words
An aqueous coating composition according to claim 1 wherein said monohydric alcohol is methanol or ethanol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-26 | 1981-12-26 | 1982-06-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-26 | 1985-12-26 | 1986-06-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-26 | 1989-12-26 | 1990-06-27 | $7700.00 | Window Closed / Lapsed |