US4097364A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hydrocracking in the presence of water and a low hydrogen partial pressure
Assignee: Chevron USA Inc
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Filing: 1976-03-24
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Granted: 1978-06-27
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Expires: 1996-03-24
Abstract
Abstract Disclosed is a process for hydrocracking high-boiling hydrocarbons to lower-boiling hydrocarbons under hydrocracking conditions including high concentrations of water and water precursors and a low partial pressure of hydrogen. Also disclosed is a combination process for the production of synthetic hydrocarbons from CO and H 2 , wherein the CO and H 2 are contacted in a reaction zone containing both a Fischer-Tropsch hydrocarbon synthesis catalyst and a hydrocracking catalyst to produce a reaction product essentially free of oxygenated components. The synthetic hydrocarbons produced by the process of this invention are particularly useful as transportation fuels.
Inventors
- 👤 Clark J. Egan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 16:55
CPC Classifications
C; C10; C10G; C10G45/00; C10G3/00; C10G3/42; C10G3/44; C10G3/47; C10G3/48; C10G3/49; C10G45/58; C10G47/00; C10G47/32; C10G2300/00; C10G2300/10; C10G2300/1037; C10G2300/20; C10G2300/201; C10G2300/202; C10G2300/30; C10G2300/301; C10G2300/40; C10G2300/4006; C10G2300/4012; C10G2300/4018; C10G2300/80; C10G2300/805; Y; Y02; Y02P; Y02P30/00; Y02P30/20
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
178 words
A process for hydrocracking high-boiling hydrocarbons boiling in the range from 400° to 1000° F to form lower-boiling hydrocarbons boiling in the range from 80° to 700° F, which comprises contacting said high-boiling hydrocarbons, in a reaction zone, in a feedstock containing from 4 to 15 weight percent water and containing straight-chain olefins and oxygen-containing water precursors including CO and CO 2 and from about 1 to 20 weight percent of oxygen-containing organic compounds, based on said feedstock, said feedstock containing less than 5 ppm sulfur, by weight, and greater than 55 weight percent of water and oxygen-containing water precursors, with a hydrocracking catalyst including a Group VIB or Group VIII metal supported on a refractory cracking base at hydrocracking conditions including a partial pressure of hydrogen of from 50 to 450 psi and a temperature of from 450° to 750° F, to convert 75 to 99 percent of said oxygen-containing organic compounds to hydrocarbons, to convert said high-boiling hydrocarbons to said lower-boiling hydrocarbons, and to convert a substantial portion of said straight-chain olefins to isoparaffins and paraffins.
Claim 2
Dependent Claim
178 words
A process for hydrocracking high-boiling hydrocarbons boiling in the range from 400° to 1000° F to form lower-boiling hydrocarbons boiling in the range from 80° to 700° F, which comprises contacting said high-boiling hydrocarbons, in a reaction zone, in a feedstock containing from 4 to 15 weight percent water and containing straight-chain olefins and oxygen-containing water precursors including CO and CO 2 and from about 1 to 20 weight percent of oxygen-containing organic compounds, based on said feedstock, said feedstock containing less than 5 ppm sulfur, by weight, and greater than 55 weight percent of water and oxygen-containing water precursors, with a hydrocracking catalyst including a Group VIB or Group VIII metal supported on a refractory cracking base at hydrocracking conditions including a partial pressure of hydrogen of from 50 to 450 psi and a temperature of from 450° to 750° F, to convert 75 to 99 percent of said oxygen-containing organic compounds to hydrocarbons, to convert said high-boiling hydrocarbons to said lower-boiling hydrocarbons, and to convert a substantial portion of said straight-chain olefins to isoparaffins and paraffins.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein said feedstock is essentially free of organonitrogen compounds.
Claim 4
Dependent Claim
17 words
The process of claim 1 wherein said catalyst comprises palladium deposited on a cracking support containing zeolite.
Claim 5
Dependent Claim
17 words
The process of claim 1 wherein the partial pressure of hydrogen is from 150 to 360 psi.
Claim 6
Dependent Claim
55 words
The process of claim 1 wherein said hydrocracking conditions include a total pressure in the range 200 to 600 psi, a hydrogen partial pressure in the range 150 to 360 psi, a gas hourly space velocity in the range 500 to 1500 and a hydrocracking catalyst comprising palladium deposited on a cracking support containing zeolite.
References Cited (Backward Citations)
CA518758A
Cited
US2600452A
Cited
US2581560A
Cited
US2569463A
Cited
US3173853A
Cited
US3254023A
Cited
US3256176A
Cited
US3530194A
Cited
US3576899A
Cited
US3531396A
Cited
US3619410A
Cited
US3676331A
Cited
US3699036A
Cited
US3702874A
Cited
US3833499A
Cited
US3894102A
Cited
US4012455A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-26 | 1981-12-26 | 1982-06-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-26 | 1985-12-26 | 1986-06-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-26 | 1989-12-26 | 1990-06-27 | $7700.00 | Window Closed / Lapsed |