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US4097364A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrocracking in the presence of water and a low hydrogen partial pressure

Assignee: Chevron USA Inc
•
Filing: 1976-03-24
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Granted: 1978-06-27
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Expires: 1996-03-24
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Abstract

Abstract Disclosed is a process for hydrocracking high-boiling hydrocarbons to lower-boiling hydrocarbons under hydrocracking conditions including high concentrations of water and water precursors and a low partial pressure of hydrogen. Also disclosed is a combination process for the production of synthetic hydrocarbons from CO and H 2 , wherein the CO and H 2 are contacted in a reaction zone containing both a Fischer-Tropsch hydrocarbon synthesis catalyst and a hydrocracking catalyst to produce a reaction product essentially free of oxygenated components. The synthetic hydrocarbons produced by the process of this invention are particularly useful as transportation fuels.

Inventors

  • 👤 Clark J. Egan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:55
CPC Classifications
C; C10; C10G; C10G45/00; C10G3/00; C10G3/42; C10G3/44; C10G3/47; C10G3/48; C10G3/49; C10G45/58; C10G47/00; C10G47/32; C10G2300/00; C10G2300/10; C10G2300/1037; C10G2300/20; C10G2300/201; C10G2300/202; C10G2300/30; C10G2300/301; C10G2300/40; C10G2300/4006; C10G2300/4012; C10G2300/4018; C10G2300/80; C10G2300/805; Y; Y02; Y02P; Y02P30/00; Y02P30/20

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 178 words
A process for hydrocracking high-boiling hydrocarbons boiling in the range from 400° to 1000° F to form lower-boiling hydrocarbons boiling in the range from 80° to 700° F, which comprises contacting said high-boiling hydrocarbons, in a reaction zone, in a feedstock containing from 4 to 15 weight percent water and containing straight-chain olefins and oxygen-containing water precursors including CO and CO 2 and from about 1 to 20 weight percent of oxygen-containing organic compounds, based on said feedstock, said feedstock containing less than 5 ppm sulfur, by weight, and greater than 55 weight percent of water and oxygen-containing water precursors, with a hydrocracking catalyst including a Group VIB or Group VIII metal supported on a refractory cracking base at hydrocracking conditions including a partial pressure of hydrogen of from 50 to 450 psi and a temperature of from 450° to 750° F, to convert 75 to 99 percent of said oxygen-containing organic compounds to hydrocarbons, to convert said high-boiling hydrocarbons to said lower-boiling hydrocarbons, and to convert a substantial portion of said straight-chain olefins to isoparaffins and paraffins.
Claim 2
Dependent Claim 178 words
A process for hydrocracking high-boiling hydrocarbons boiling in the range from 400° to 1000° F to form lower-boiling hydrocarbons boiling in the range from 80° to 700° F, which comprises contacting said high-boiling hydrocarbons, in a reaction zone, in a feedstock containing from 4 to 15 weight percent water and containing straight-chain olefins and oxygen-containing water precursors including CO and CO 2 and from about 1 to 20 weight percent of oxygen-containing organic compounds, based on said feedstock, said feedstock containing less than 5 ppm sulfur, by weight, and greater than 55 weight percent of water and oxygen-containing water precursors, with a hydrocracking catalyst including a Group VIB or Group VIII metal supported on a refractory cracking base at hydrocracking conditions including a partial pressure of hydrogen of from 50 to 450 psi and a temperature of from 450° to 750° F, to convert 75 to 99 percent of said oxygen-containing organic compounds to hydrocarbons, to convert said high-boiling hydrocarbons to said lower-boiling hydrocarbons, and to convert a substantial portion of said straight-chain olefins to isoparaffins and paraffins.
Claim 3
Dependent Claim 14 words
The process of claim 1 wherein said feedstock is essentially free of organonitrogen compounds.
Claim 4
Dependent Claim 17 words
The process of claim 1 wherein said catalyst comprises palladium deposited on a cracking support containing zeolite.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein the partial pressure of hydrogen is from 150 to 360 psi.
Claim 6
Dependent Claim 55 words
The process of claim 1 wherein said hydrocracking conditions include a total pressure in the range 200 to 600 psi, a hydrogen partial pressure in the range 150 to 360 psi, a gas hourly space velocity in the range 500 to 1500 and a hydrocracking catalyst comprising palladium deposited on a cracking support containing zeolite.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-26 1981-12-26 1982-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-26 1985-12-26 1986-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-26 1989-12-26 1990-06-27 $7700.00 Window Closed / Lapsed

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