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US4096224A Expired / Lapsed US ⏱️ 0.0 years remaining

Molded styrene polymer articles from vacuum-formed or thermoformed S-B-S block copolymer sheets

Assignee: Huels AG
•
Filing: 1976-05-05
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Granted: 1978-06-20
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Expires: 1996-05-05
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Abstract

Abstract Sheets produced by the extrusion of a mixture of about 85 - 95 percent by weight of polystyrene or semi-impact-resistant polystyrene and about 5 - 15 percent by weight of a diene-styrene block copolymer having the structure S-B-S wherein S represents the styrene structure and B represents the butadiene or isoprene structure are used for the manufacture of molded articles in the vacuum-forming or thermoforming method.

Inventors

  • 👤 Gunter Simon
  • 👤 Walter Widmaier
  • 👤 Karl-Ulrich Reichert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 01:46
CPC Classifications
B; B29; B29C; B29C51/00; B29C51/002; C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/06; C08L53/00; C08L53/02

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 98 words
In the method of manufacturing molded articles comprising thermoforming extruded polystyrene sheets, the improvement comprising the use of sheets having a thickness of about 0.2 to 2.0 mm produced by extruding a mixture of about 85-95 percent by weight of polystyrene and about 5-15 percent by weight of a diene-styrene block copolymer having the structure S-B-S wherein S represents styrene and B represents butadiene or isoprene said block copolymer having a molecular weight of about 60,000 to 130,000; an RSV value in toluene of between 0.80 and 1.30 and a diene content of between 50 and 85 percent.
Claim 2
Dependent Claim 98 words
In the method of manufacturing molded articles comprising thermoforming extruded polystyrene sheets, the improvement comprising the use of sheets having a thickness of about 0.2 to 2.0 mm produced by extruding a mixture of about 85-95 percent by weight of polystyrene and about 5-15 percent by weight of a diene-styrene block copolymer having the structure S-B-S wherein S represents styrene and B represents butadiene or isoprene said block copolymer having a molecular weight of about 60,000 to 130,000; an RSV value in toluene of between 0.80 and 1.30 and a diene content of between 50 and 85 percent.
Claim 3
Dependent Claim 13 words
The method of claim 1, wherein said polystyrene is a homopolymer of styrene.
Claim 4
Dependent Claim 20 words
The method of claim 1, wherein said diene-styrene block copolymer has a diene proportion of about 55-80 percent by weight.
Claim 5
Dependent Claim 20 words
The method of claim 2, wherein said diene-styrene block copolymer has a diene proportion of about 55-80 percent by weight.
Claim 6
Dependent Claim 13 words
The method of claim 1, wherein said RSV value is 1.0 to 1.30.
Claim 7
Dependent Claim 13 words
The method of claim 1, wherein said RSV value is 1.15 to 1.30.
Claim 8
Dependent Claim 15 words
The method of claim 1, wherein said weight of diene-styrene block copolymer is 8-15 percent.
Claim 9
Dependent Claim 17 words
The method of claim 1, wherein said sheets have a thickness of about 0.5 to 1.0 mm.
Claim 10
Dependent Claim 19 words
The method of claim 2, wherein said homopolymer of styrene has a K value of about 55 to 70.
Claim 11
Dependent Claim 19 words
The method of claim 2, wherein said homopolymer of styrene has a K value of about 60 to 68.

References Cited (Backward Citations)

US3709967A Cited
US3853978A Cited
US3957940A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-19 1981-12-19 1982-06-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-19 1985-12-19 1986-06-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-19 1989-12-19 1990-06-20 $7700.00 Window Closed / Lapsed

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