US4096201A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Adhesive composition
Assignee: Denka Co Ltd
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Filing: 1977-01-06
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Granted: 1978-06-20
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Expires: 1997-01-06
Abstract
Abstract An adhesive composition comprises a redox system comprising a reducing agent and an oxidizing system comprising A. 5 to 30 wt. parts of an elastomer of a copolymer of butadiene and acrylonitrile or a copolymer of butadiene and acrylonitrile and less than 5 wt.% of a functional monomer or a graft copolymer of butadiene and at least one of acrylonitrile, styrene and methacrylic acid ester and B. 70 to 95 wt. parts of a monomer mixture comprising 30 to 80 wt.% of 2-hydroxy ethyl methacrylate or 2-hydroxy propyl methacrylate and 20 to 70 wt.% of a C 1-4 alkyl methacrylate to total monomers having ethylenically unsaturated double bond and C. 0.1 to 10 wt.% of an organic hydroperoxide to total monomers having ethylenically unsaturated double bond.
Inventors
- 👤 Ikuji Kishi
- 👤 Tatsuo Nakano
- 👤 Hiroshi Okai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 17:27
CPC Classifications
C; C09; C09J; C09J4/00; C09J4/06; C08; C08F; C08F279/00; C08F279/02; C08F285/00
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
135 words
An adhesive composition which comprises a redox system comprising a reducing system containing a reducing agent and an oxidizing system comprising a. 5 to 30 wt. parts of an elastomer of a copolymer of butadiene and acrylonitrile or a copolymer of butadiene and acrylonitrile and less than 5 wt. % of a functional monomer or a graft copolymer of butadiene and at least one of acrylonitrile, styrene and methacrylic acid ester and b. 70 to 95 wt. parts of a monomer mixture comprising 30 to 80 wt. % of 2-hydroxy ethyl methacrylate or 2-hydroxy propyl methacrylate and 20 to 70 wt. % of a C 1-4 alkyl methacrylate to total monomers having ethylenically unsaturated double bond and c. 0.1 to 10 wt. % of an organic hydroperoxide to total monomers having ethylenically unsaturated double bond.
Claim 2
Dependent Claim
135 words
An adhesive composition which comprises a redox system comprising a reducing system containing a reducing agent and an oxidizing system comprising a. 5 to 30 wt. parts of an elastomer of a copolymer of butadiene and acrylonitrile or a copolymer of butadiene and acrylonitrile and less than 5 wt. % of a functional monomer or a graft copolymer of butadiene and at least one of acrylonitrile, styrene and methacrylic acid ester and b. 70 to 95 wt. parts of a monomer mixture comprising 30 to 80 wt. % of 2-hydroxy ethyl methacrylate or 2-hydroxy propyl methacrylate and 20 to 70 wt. % of a C 1-4 alkyl methacrylate to total monomers having ethylenically unsaturated double bond and c. 0.1 to 10 wt. % of an organic hydroperoxide to total monomers having ethylenically unsaturated double bond.
Claim 3
Dependent Claim
28 words
An adhesive composition according to claim 1, wherein said reducing system further comprises a monomer or a mixture of said elastomer or the graft copolymer and a monomer.
Claim 4
Dependent Claim
26 words
An adhesive composition according to claim 1, wherein said reducing system is applied as a solution of the reducing agent in a solvent or a plasticizer.
Claim 5
Dependent Claim
24 words
An adhesive composition according to claim 1, wherein paraffin wax is included at a ratio of 0.01 to 2 wt. % of total components.
Claim 6
Dependent Claim
30 words
An adhesive composition according to claim 1, wherein a polymerization inhibitor is included at a ratio of 0.01 to 3 wt. % to total monomers having ethylenically unsaturated double bond.
Claim 7
Dependent Claim
27 words
An adhesive composition according to claim 1, wherein said monomer mixture comprises the other monomer at a ratio of less than 50 wt. % to total monomers.
Claim 8
Dependent Claim
21 words
An adhesive composition according to claim 1, wherein said graft copolymer (a) is a graft copolymer of butadiene, styrene and acrylonitrile.
Claim 9
Dependent Claim
23 words
An adhesive composition according to claim 1, wherein said graft copolymer (a) is a graft copolymer of butadiene, styrene and methacrylic acid ester.
Claim 10
Dependent Claim
22 words
An adhesive composition according to claim 1, wherein said graft copolymer is a graft copolymer of butadiene, styrene and methacrylic acid ester.
Claim 11
Dependent Claim
14 words
An adhesive composition according to claim 1, wherein said alkyl methacrylate is methyl methacrylate.
Claim 12
Dependent Claim
19 words
An adhesive composition according to claim 4, wherein said paraffin has a melting point of 40° to 60° C.
Claim 13
Dependent Claim
21 words
An adhesive composition according to claim 1, wherein said reducing system is applied on a substrate before applying said oxidizing system.
Claim 14
Dependent Claim
24 words
An adhesive composition according to claim 1, wherein said reducing system is mixed with said oxidizing system just before or during the bonding operation.
Claim 15
Dependent Claim
14 words
An adhesive composition according to claim 1 wherein said reducing agent is a thioamide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-19 | 1981-12-19 | 1982-06-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-19 | 1985-12-19 | 1986-06-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-19 | 1989-12-19 | 1990-06-20 | $7700.00 | Window Closed / Lapsed |