US4094852A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the production of polytriazines in the presence of high-boiling esters
Assignee: Bayer AG
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Filing: 1976-07-22
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Granted: 1978-06-13
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Expires: 1996-07-22
Abstract
Abstract A polytrimerizable mixture of 30 to 99.9% by weight of at least one aromatic, polyfunctional cyanic acid ester or a prepolymer thereof, and 0.1 to 70% by weight of at least one high-boiling ester with a boiling point above 250° C at 760 Torr, Said mixture results in polytriazines having a significant improvement in elasticity, flexibility and resistance to hydrolysis.
Inventors
- 👤 Rudolf Sundermann
- 👤 Gunther Rottloff
- 👤 Ernst Grigat
- 👤 Rolf Putter
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 02:19
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/0622; C08G73/0638; C08G73/065; C08G73/0655
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
267 words
A polytrimerizable mixture of 30 to 99.9% by weight of at least one aromatic cyanic acid ester of the formula ##STR7## wherein R is hydrogen, halogen, alkyl having 1 to 9 carbon atoms, phenyl, alkoxy having 1 to 4 carbon atoms or alkoxy carbonyl having 1 to 4 carbon atoms in the alkyl moiety, or two R substituents together on adjacent carbon atoms of the phenyl moiety to which they are attached together form a hydrocarbon ring containing from 5 to 6 carbon atoms or together form with O, S or N a 5 or 6-membered heterocyclic ring; R' has the same meaning as R or is the group ##STR8## A is a bond, alkylene having 1 to 9 carbon atoms or said alkylene substituted by phenyl or alkyl having 1 to 4 carbon atoms, a divalent cycloaliphatic or aromatic 5 or 6-membered ring or said divalent ring including oxygen as a hetero atom, oxygen, -SO 2 -, ##STR9## a is 0 to 5 when e is 1 and 2,5 when e is 1; b is 5 - a when e is 1 and 6 - a - d when e is 0; c is 5 - d; d is 0 to 5; and e is 0 to 3 with the proviso that the sum of a + d is always from 2 to 5. or a partially cross-linked prepolymer of said cyanic ester of said formula which is soluble in organic solvents and 0.1 to 70% by weight of at least one high boiling ester plasticizer having a boiling point above 250° C at 760 Torr.
Claim 2
Dependent Claim
267 words
A polytrimerizable mixture of 30 to 99.9% by weight of at least one aromatic cyanic acid ester of the formula ##STR7## wherein R is hydrogen, halogen, alkyl having 1 to 9 carbon atoms, phenyl, alkoxy having 1 to 4 carbon atoms or alkoxy carbonyl having 1 to 4 carbon atoms in the alkyl moiety, or two R substituents together on adjacent carbon atoms of the phenyl moiety to which they are attached together form a hydrocarbon ring containing from 5 to 6 carbon atoms or together form with O, S or N a 5 or 6-membered heterocyclic ring; R' has the same meaning as R or is the group ##STR8## A is a bond, alkylene having 1 to 9 carbon atoms or said alkylene substituted by phenyl or alkyl having 1 to 4 carbon atoms, a divalent cycloaliphatic or aromatic 5 or 6-membered ring or said divalent ring including oxygen as a hetero atom, oxygen, -SO 2 -, ##STR9## a is 0 to 5 when e is 1 and 2,5 when e is 1; b is 5 - a when e is 1 and 6 - a - d when e is 0; c is 5 - d; d is 0 to 5; and e is 0 to 3 with the proviso that the sum of a + d is always from 2 to 5. or a partially cross-linked prepolymer of said cyanic ester of said formula which is soluble in organic solvents and 0.1 to 70% by weight of at least one high boiling ester plasticizer having a boiling point above 250° C at 760 Torr.
Claim 3
Dependent Claim
50 words
A polytrimerisable mixture as claimed in claim 1, consisting of 90.0 to 99.9% by weight of said at least one aromatic cyanic acid ester or said prepolymer thereof and 0.1 to 10% by weight of at least one high-boiling ester with a boiling point above 250° C at 760 Torr.
Claim 4
Dependent Claim
50 words
A polytrimerisable mixture as claimed in claim 1, consisting of 50 to 90% by weight of said at least one aromatic cyanic acid ester or said prepolymer thereof and 10 to 50% by weight of at least one high-boiling ester with a boiling point above 250° C at 750 Torr.
Claim 5
Dependent Claim
23 words
A process for producing a polytriazine which comprises heating the mixture of claim 1 to a temperature of from about 100 to 350°C.
Claim 6
Dependent Claim
37 words
A process as claimed in claim 4 wherein said heating is carried out in the presence of a catalytic amount of a catalyst selected from the group consisting of zinc octoate, tin octoate, diazabicyclo-(2,2,2)-octane, pyrocatechol and bis-2,3-(4-hydroxyphenyl)-propane.
Claim 7
Dependent Claim
23 words
A process as claimed in claim 4, wherein the high-boiling ester is used in a quantity of from 0.1 to 10% by weight.
Claim 8
Dependent Claim
23 words
A process as claimed in claim 4, wherein the high-boiling ester is used in a quantity of from 10 to 50% by weight.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-12 | 1981-12-12 | 1982-06-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-12 | 1985-12-12 | 1986-06-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-12 | 1989-12-12 | 1990-06-13 | $7700.00 | Window Closed / Lapsed |