US4094804A
Expired / Lapsed
US
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Method for preparing a water base magnetic fluid and product
Assignee: Individual
•
Filing: 1977-01-05
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Granted: 1978-06-13
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Expires: 1997-01-05
Abstract
Abstract A water base magnetic fluid is provided by adding an unsaturated fatty acid with 18 carbon atoms or a salt thereof into a colloidal solution of a ferromagnetic oxide power in water, subsequently adding an acid solution to the colloidal solution to develop a precipitate by a flocculation, separating the precipitate from the solution, and adding an anionic surfactant with 8 to 30 carbon atoms, or a non-ionic surfactant with 8 to 20 carbon atoms and with H.L.B. of 12 or more, to the separated precipitate in water to peptize the precipitate. The water base magnetic fluid is a stable suspension of the ferromagnetic powder in water. Each particle of the ferromagnetic powder in the fluid is coated with a monomolecular layer of the ionized unsaturated fatty acid and with the non-ionic or anionic surfactant layer being adsorbed on the first monomolecular layer. The average particle size of the ferromagnetic powder may be 150 A or less.
Inventors
- 👤 Junzo Shimoiizaka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 21:24
CPC Classifications
H; H01; H01F; H01F1/00; H01F1/44; H01F1/445; B; B82; B82Y; B82Y30/00
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
308 words
A method for preparing a stable aqueous magnetic fluid comprising: preparing an aqueous colloidal solution of a ferromagnetic powder of the formula MO.Fe 2 O 3 wherein M is at least one metal selected from the group consisting of Fe, Mn, Zn, Cu, Co and Ni; making said solution alkaline and adding a first surfactant which is an unsaturated fatty acid containing 18 carbon atoms to the solution in an amount such that each particle of said powder is completely coated with a monomolecular layer of said first surfactant by adsorption with additional molecules of said first surfactant being adsorbed on said monomolecular layer whereby each particle is dispersed in the solution, said first surfactant being an unsaturated fatty acid having 18 carbon atoms or a salt thereof; adding an acid solution to said alkaline solution containing said dispersed particles to adjust the pH to a value not in excess of 7 whereby said dispersed particles precipitate of flocculation; separating said precipitated particles from the solution; washing said precipitated particles to remove the portion of said first surfactant from said particle which is in excess of the monomolecular layer coating said precipitated particles and to form a water admixture with said precipitated particles; and then adding a second surfactant to said admixture of the separated precipitated particles to form an absorbed coating of said second surfactant on said monomolecular layer of said first surfactant and to peptize and form an aqueous magnetic fluid in which said ferromagnetic powder particles are stably dispersed in water, said second surfactant being free of cationic surfactants and consisting essentially of an anionic surfactant containing between about 8 and 30 carbon atoms in its hydrophobic group other than said first surfactant, or a non-ionic surfactant having 8-20 carbon atoms in its hydrophobic group and having a hydrophile lipophile balance of at least 12.
Claim 2
Independent Claim
308 words
A method for preparing a stable aqueous magnetic fluid comprising: preparing an aqueous colloidal solution of a ferromagnetic powder of the formula MO.Fe 2 O 3 wherein M is at least one metal selected from the group consisting of Fe, Mn, Zn, Cu, Co and Ni; making said solution alkaline and adding a first surfactant which is an unsaturated fatty acid containing 18 carbon atoms to the solution in an amount such that each particle of said powder is completely coated with a monomolecular layer of said first surfactant by adsorption with additional molecules of said first surfactant being adsorbed on said monomolecular layer whereby each particle is dispersed in the solution, said first surfactant being an unsaturated fatty acid having 18 carbon atoms or a salt thereof; adding an acid solution to said alkaline solution containing said dispersed particles to adjust the pH to a value not in excess of 7 whereby said dispersed particles precipitate of flocculation; separating said precipitated particles from the solution; washing said precipitated particles to remove the portion of said first surfactant from said particle which is in excess of the monomolecular layer coating said precipitated particles and to form a water admixture with said precipitated particles; and then adding a second surfactant to said admixture of the separated precipitated particles to form an absorbed coating of said second surfactant on said monomolecular layer of said first surfactant and to peptize and form an aqueous magnetic fluid in which said ferromagnetic powder particles are stably dispersed in water, said second surfactant being free of cationic surfactants and consisting essentially of an anionic surfactant containing between about 8 and 30 carbon atoms in its hydrophobic group other than said first surfactant, or a non-ionic surfactant having 8-20 carbon atoms in its hydrophobic group and having a hydrophile lipophile balance of at least 12.
Claim 3
Dependent Claim
24 words
The method as claimed in claim 1, in which said first surfactant is one of oleic acid, linoleic acid, linolenic acid and salts thereof.
Claim 4
Dependent Claim
30 words
The method as claimed in claim 2 in which said salts are alkaline metal or ammonium salts, and said first surfactant is oleic acid or one of said salts thereof.
Claim 5
Dependent Claim
40 words
The method as claimed in claim 3, in which said second surfactant is selected from the group consisting of sodium alkyl sulfate, sodium alkyl benzene sulfonate, sodium alkyl phosphate, polyoxyethylene alkyl ether, polyoxyethylene alkyl ester, and polyoxyethylene alkyl phenyl ether.
Claim 6
Dependent Claim
23 words
The method as claimed in claim 4 wherein said aqueous alkaline solution containing said first surfactant has a pH of above about 11.
Claim 7
Dependent Claim
16 words
The method as claimed in claim 3, in which said second surfactant is sodium dodecyl sulfate.
Claim 8
Dependent Claim
17 words
The method as claimed in claim 3, in which said second surfactant is sodium dodecyl benzene sulfonate.
Claim 9
Dependent Claim
23 words
The method of claim 2 wherein said second surfactant is selected from the group consisting of alkyl sulfate, alkylbenzene sulfate, and alkyl phosphate.
Claim 10
Dependent Claim
26 words
The method of claim 2 wherein said second surfactant is selected from the group consisting of polyoxyethlene alkyl ether, polyoxyethylene alkyl ester, and polyoxyethylene alkylphenyl ether.
Claim 11
Dependent Claim
17 words
The method as claimed in claim 1, wherein a polar solvent is used to wash said precipitate.
Claim 12
Dependent Claim
30 words
The method as claimed in claim 1, in which said ferromagnetic powder is one of magnetite, manganese ferrite, nickel ferrite, copper ferrite, cobalt ferrite, manganese-zinc ferrite and nickel zinc ferrite.
Claim 13
Dependent Claim
22 words
The method as claimed in claim 1, in which said ferromagnetic powder has an average particle size of 150 A or less.
Claim 14
Dependent Claim
28 words
The method as claimed in claim 1, in which said acid solution is at least one acid selected from the group consisting of hydrochloric acid and sulfuric acid.
Claim 15
Dependent Claim
41 words
The method as claimed in claim 1, in which said acid solution is added into the dispersed solution in an amount so that the acidity of the dispersed solution is substantially equal to the value of pK of the first surfactant.
Claim 16
Dependent Claim
23 words
The method as claimed in claim 1, wherein said aqueous alkaline solution containing said first surfactant has a pH of above about 10.
Claim 17
Dependent Claim
34 words
The method as claimed in claim 1 wherein said aqueous colloidal solution of a ferromagnetic powder is produced by precipitation of a mixture of the metal oxides from an aqueous solution of their salts.
Claim 18
Dependent Claim
48 words
The method as claimed in claim 16 wherein said colloidal solution is prepared by preparing an aqueous acidic solution of salts of the metal ions and then adding an alkaline solution to form a mixture of the metal ions in oxide or hydrated oxide form and then maturing.
Claim 19
Dependent Claim
33 words
The method as claimed in claim 1 in which said acid solution which is added to adjust the pH to a value not in excess of 7 is an aqueous inorganic acid solution.
Claim 20
Dependent Claim
153 words
A stable aqueous magnetic fluid having a pH of above about 4 comprising water having stable dispersed therein ferromagnetic oxide particles of a particle size below about 300 A, each of said magnetic particles having a two layer surfactant coating comprising an inner layer and an outer layer, the inner layer being a monomolecular layer of an 18 carbon atoms unsaturated fatty acid or salt thereof which completely coats said magnetic particle, and the outer layer being an outer coating free of cationic surfactants and consisting essentially of (i) an anionic surfactant having 8 to 30 carbon atoms in its hydrophobic radical other than said first surfactant, or (ii) a non-ionic surfactant having 8 to 20 carbon atoms in it hydrophobic radical and having a hydrophile balance of at least 12 which completely covers said inner layer, said aqueous fluid containing between about 0.005 and 0.7 g/ml of said coated ferromagnetic oxide particles.
Claim 21
Dependent Claim
153 words
A stable aqueous magnetic fluid having a pH of above about 4 comprising water having stable dispersed therein ferromagnetic oxide particles of a particle size below about 300 A, each of said magnetic particles having a two layer surfactant coating comprising an inner layer and an outer layer, the inner layer being a monomolecular layer of an 18 carbon atoms unsaturated fatty acid or salt thereof which completely coats said magnetic particle, and the outer layer being an outer coating free of cationic surfactants and consisting essentially of (i) an anionic surfactant having 8 to 30 carbon atoms in its hydrophobic radical other than said first surfactant, or (ii) a non-ionic surfactant having 8 to 20 carbon atoms in it hydrophobic radical and having a hydrophile balance of at least 12 which completely covers said inner layer, said aqueous fluid containing between about 0.005 and 0.7 g/ml of said coated ferromagnetic oxide particles.
Claim 22
Dependent Claim
13 words
The fluid of claim 14 wherein said unsaturated fatty acid is oleic acid.
Claim 23
Dependent Claim
26 words
The fluid of claim 20 wherein said outer layer is one anionic surfactant selected from the group consisting of alkyl sulfate, alkylbenzene sulfate, and alkyl phosphate.
Claim 24
Dependent Claim
29 words
The fluid of claim 20 wherein said outer layer is one non-ionic surfactant selected from the group consisting of polyoxyethylene alkyl ether, polyoxyethylene alkyl ester, and polyoxyethylene alkylphenyl ether.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-12 | 1981-12-12 | 1982-06-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-12 | 1985-12-12 | 1986-06-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-12 | 1989-12-12 | 1990-06-13 | $7700.00 | Window Closed / Lapsed |