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US4093784A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithium primary cell

Assignee: United States Department of the Army
•
Filing: 1977-08-26
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Granted: 1978-06-06
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Expires: 1997-08-26
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Abstract

Abstract A lithium primary cell including lithium as the anode, a solution of an iganic salt in an inorganic solvent as the electrolyte, and a current collector as the cathode is improved in cell performance by coating the lithium anode with calcium.

Inventors

  • 👤 Joseph R. Driscoll

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:15
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/14

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 43 words
In a lithium primary cell including lithium as the anode, a solution of an inorganic salt in an inorganic solvent as the electrolyte, and a current collector as the cathode, the improvement in cell performance obtained by coating the lithium anode with calcium.
Claim 2
Dependent Claim 43 words
In a lithium primary cell including lithium as the anode, a solution of an inorganic salt in an inorganic solvent as the electrolyte, and a current collector as the cathode, the improvement in cell performance obtained by coating the lithium anode with calcium.
Claim 3
Dependent Claim 26 words
An improved lithium primary cell according to claim 1 wherein the inorganic salt is selected from the group consisting of LiAlCl 4 and LiSbCl 6 .
Claim 4
Dependent Claim 34 words
An improved lithium primary cell according to claim 1 wherein the inorganic solvent is a covalent inorganic oxychloride solvent selected from the group consisting of thionyl chloride, phosphorous oxychloride, monofluorophosphoryl dichloride, and sulfuryl chloride.
Claim 5
Dependent Claim 25 words
An improved lithium primary cell according to claim 1 wherein the electrolyte is a solution of about 1.5 molar LiAlCl 4 in SOCl 2 .
Claim 6
Dependent Claim 29 words
An improved lithium primary cell according to claim 4 wherein the lithium anode is coated with calcium by exchange from a solution containing dissolved calcium in SOCl 2 .
Claim 7
Dependent Claim 21 words
An improved lithium primary cell according to claim 1 wherein the current collector is a high surface area electronically conducting material.
Claim 8
Dependent Claim 27 words
An improved lithium primary cell according to claim 6 wherein the high surface area electronically conducting material is selected from the group consisting of carbon and graphite.
Claim 9
Dependent Claim 19 words
An improved lithium primary cell according to claim 7 wherein the high surface area electronically conducting material is carbon.
Claim 10
Dependent Claim 21 words
An improved lithium primary cell according to claim 4 wherein the current collector is a high surface area electronically conducting material.
Claim 11
Dependent Claim 27 words
An improved lithium primary cell according to claim 9 wherein the high surface area electronically conducting material is selected from the group consisting of carbon and graphite.
Claim 12
Dependent Claim 19 words
An improved lithium primary cell according to claim 10 wherein the high surface area electronically conducting material is carbon.
Claim 13
Dependent Claim 20 words
An improved lithium primary cell according to claim 1 wherein said inorganic solvent is also the depolarizer for the battery.

References Cited (Backward Citations)

US3716410A Cited
US4012564A Cited
US3993501A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-05 1981-12-05 1982-06-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-05 1985-12-05 1986-06-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-05 1989-12-05 1990-06-06 $7700.00 Window Closed / Lapsed

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