Photocurable composition comprising a copolymer of a maleic acid monoester with an α-olefine

Claim 2

A photocurable composition which comprises (A) a mixture of 20 to 90% by weight of a maleic acid monoester/αolefine copolymer of the formula: ##STR5## wherein R 1 is an alkyl group having 1 to 8 carbon atoms, aralkyl group, cyclo group and cycloalkyl group, R 2 is a hydrogen or alkyl group of 1 to 3 carbon atoms, R 3 is a hydrogen or alkyl group of 1 to 6 carbon atoms and n is an integer which provides a number average molecular weight of 55,000 to 200,000 and 10 to 80% by weight of a vinylurethane compound obtained by urethanation reaction of a polyisocyanate compound with a photopolymerizable ethylenically unsaturated alcohol having a number average molecular weight of less than 3,000 or by urethanation reaction of 1 mole of diisocyanate compound with about 1 mole of said photopolymerizable ethylenically unsaturated alcohol and about 1/m mole of m-valent alcohol (wherein m is an integer of 2 to 6) having a number average molecular weight of less than 3,000, and (B) a photosensitizer.

Claim 3

A photocurable composition according to claim 1, wherein said α-olefine compound is selected from the group consisting of ethylene, propylene, n-butene, isobutylene, n-pentene, isoprene, 2-methyl 1-butene, n-hexene, 2-methyl 1-pentene, 3-methyl 1-pentene, 4-methyl 1-pentene and 2-ethyl 1-butene.

Claim 4

A photocurable composition according to claim 2, wherein said α-olefine compound is isobutylene.

Claim 5

A photocurable composition according to claim 1, wherein said di- or polyisocyanate compound is selected from the group consisting of tolyene diisocyanates, xylylene diisocyanates, hexamethylene diisocyanate, lysine diisocyanate, isophorone diisocyanate, diphenyl methane-4-4'-diisocyanate, dicyclohexyl methane-4,4'-diisocyanate, triphenyl methane triisocyanate and compounds of the following formulae H 5 C 2 C(CH OCONHC 6 H 3 CH 3 NCO) 3 and OCN(CH 2 ) 6 N[CONH(CH 2 ) 6 NCO] 2 .

Claim 6

A photocurable composition according to claim 1, wherein said photopolymerizable ethylenically unsaturated alcohol is selected from the group consisting of monocrotonic acid esters of glycols, cinnamyl alcohol, oleyl alcohol, and monoacrylic acid and monomethacrylic acid esters of glycols.

Claim 7

A photocurable compsotion according to claim 5, wherein said photopolymerizable ethylenically unsaturated alcohol is monoacrylic acid or monomethyacrylic acid esters of glycols of the general formula ##STR6## wherein R 4 and R 5 are independently hydrogen or methyl group and p is 1 or more integer which provides a the number average molecular weight of less than 3,000.

Claim 8

A photocurable composition according to claim 1, wherein said m-valent alcohol is selected from the group consisting of ethylene glycol, 1,2-propanediol, 1,3-propanediol, neopentyl glycol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2-methylpentane-2,4-diol, polyethylene glycol with a number average molecular weight below 3,000, polypropylene glycol with a number average molecular weight below 3,000, glycerine, trimethylol ethane, trimethylol propane, pentaerythritol, pentavalent sugaralcohol consisting of D-and L-arabitols, adonitol and xylitol, hexavalent sugaralcohols consisting of D- and L-sorbitols D-and L-manitols, D- and L-iditols, D- and L-talitols, dalsitol and sllitol, a polyaddition product of ethylene oxide to glycerine with a number average molecular weight of less than 3,000, a polyaddition product of propylene oxide to glycerine with a number average molecular weight below 3,000, a polyaddition product of ethylene oxide to trimethylol ethane with a number average molecular weight below 3,000, a polyaddition product of ethylene oxide to D-sorbitol with a number average molecular weight below 3,000, dipentaerythritol, polybutadiene glycol with a number average molecular weight below 3,000 triricinoleic acid ester of glycerine and polyester glycol with a number average molecular weight below 3,000 and polytetramethylene glycol (with a number average molecular weight below 3,000).

Claim 9

A photocurable composition according to claim 1, wherein said photosensitizer is selected from the group consisting of α-carbonyl alcohols consisting of benzoin, butyroin, trioin, acetoin and acroin; acyloin ethers consisting of benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, pivaloin ethyl ether, and anisoin ethyl ether; α-substituted acyloins consisting of α-methylbenzoin, and α-phenylbenzoin; polynuclear quinones consisting of 9,10-anthraquinone, 2-chloroanthraquinone, 2-methylanthraquinone, 1,4-naphthoquinone, and 2,3-benzanthraquinone; neighboring polyketone compounds consisting of diacetyl, dibenzoyl, diphenyltriketone, phenylglyoxal, and pentadion-2,3; mercaptans consisting of 2-mercaptobenzothiazole, 2-mercaptobenzooxazole, 2-mercaptonaphthooxazole, and 2-mercaptobenzoimidazole; disulfides consisting of diphenyl disulfide, dibenzyl disulfide, di-n-butyl disulfide, dibenzoyl disulfide, diacetyl disulfide, and dibornyl disulfide; thiols consisting of thiophenol and o-aminothiophenol; thiuram derivatives consisting of tetramethylthiuram monosulfide, tetramethylthiuram disulfide and tetramethylthiuram tetrasulfide; a metal complex consisting of acetylacetone nickel complex; and peroxides consisting of benzoyl peroxide and di-tert-butyl peroxide; phenylketones consisting of benzophenone, Michler's ketone and ω-bromoacetophenone; an aromatic sulfonyl chloride consisting of 1-naphthalenesulfonyl chloride; and a metal mercaptide consisting of mercury phenylmercaptide.

Claim 10

A photocurable composition according to claim 8, wherein said photosensitizer is used in an amount of 0.01 to 5% by weight of said composition.

Claim 11

The photocurable composition according to claim 1 wherein said photosensitizer is 0.01 to 5 percent by weight of the composition.

Claim 12

A photocurable composition according to claim 10 wherein said mixture is of 30-80 weight perecent of said copolymer of 20-70 weight percent of said vinylurethane compound, wherein said copolymer has a number average molecular weight of 55,000-170,000, and wherein said photosensitizer is 0.1-2 weight percent.