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US4092171A Expired / Lapsed US ⏱️ 0.0 years remaining

Organophosphine chelates of platinum and palladium as sensitizers

Assignee: EIDP Inc
•
Filing: 1976-02-20
•
Granted: 1978-05-30
•
Expires: 1996-02-20
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Abstract

Abstract Photographic colloid-silver halide emulsions have their sensitivity increased by the addition of at least one organo-phosphine chelate of a palladium or platinum metal salt.

Inventors

  • 👤 John Howard Bigelow

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 10:21
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/09

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 47 words
A light-sensitive silver halide photographic element comprising a support coated with at least one silver halide emulsion containing as a chemical sensitizer a chelate of an organophosphine with a platinum or palladium salt, the latter being present in an amount sufficient to sensitize the silver halide emulsion.
Claim 2
Dependent Claim 47 words
A light-sensitive silver halide photographic element comprising a support coated with at least one silver halide emulsion containing as a chemical sensitizer a chelate of an organophosphine with a platinum or palladium salt, the latter being present in an amount sufficient to sensitize the silver halide emulsion.
Claim 3
Dependent Claim 15 words
The photographic element of claim 1 wherein the Pt or Pd salt is a halide.
Claim 4
Dependent Claim 15 words
The photographic element of claim 1 wherein the Pt or Pd salt is a chloride.
Claim 5
Dependent Claim 13 words
The photographic element of claim 1 wherein the chelate has the formula ##STR14##
Claim 6
Dependent Claim 24 words
The photographic element of claim 1 wherein the chelate has the formula [CH 3 P(OPh) 2 ] 2 PtCl 2 wherein Ph = phenyl.
Claim 7
Dependent Claim 24 words
The photographic element of claim 1 wherein the chelate has the formula (Ph 2 POCH 3 ) 2 PdCl 2 wherein Ph = phenyl.
Claim 8
Dependent Claim 24 words
The photographic element of claim 1 wherein the chelate has the formula [PhP(CH 3 ) 2 ] 2 PdCl 2 wherein Ph = phenyl.
Claim 9
Dependent Claim 13 words
The photographic element of claim 1 wherein the chelate has the formula ##STR15##
Claim 10
Dependent Claim 24 words
A photographic silver halide emulsion containing a sufficient amount of an organophosphine chelate of a Pt or Pd salt to chemically sensitize the emulsion.
Claim 11
Dependent Claim 24 words
A photographic silver halide emulsion containing a sufficient amount of an organophosphine chelate of a Pt or Pd salt to chemically sensitize the emulsion.

References Cited (Backward Citations)

US2540086A Cited
SU195872A1 Cited
GB1295463A Cited
US3804632A Cited
US3930867A Cited
US3904415A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-29 1981-11-28 1982-05-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-29 1985-11-28 1986-05-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-29 1989-11-28 1990-05-30 $7700.00 Window Closed / Lapsed

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