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US4090993A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating compositions containing a mixture of a tetrafluoroethylene polymer an aromatic polyethersulfone

Assignee: Imperial Chemical Industries Ltd
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Filing: 1976-07-22
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Granted: 1978-05-23
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Expires: 1996-07-22
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Abstract

Abstract A coating composition comprises a dispersion of a fluorocarbon polymer in an inert diluent having dissolved, or preferably dispersed, therein a low molecular weight (RV less than 0.25) polyethersulphone or precursor thereto.

Inventors

  • 👤 Terence Edwin Attwood
  • 👤 Ronald Peter Buckley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 09:08
CPC Classifications
C; C09; C09D; C09D127/00; C09D127/02; C09D127/12; C09D127/18; B; B05; B05D; B05D5/00; B05D5/08; B05D5/083; C09D181/00; C09D181/06; C08; C08L; C08L81/00; C08L81/06

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 200 words
A coating dispersion comprising a tetrafluoroethylene polymer selected from tetrafluoroethylene homopolymers, telomers, or copolymers with up to 5% by weight of a comonomer, such as ethylene, vinyl chloride, hexafluoropropene or perfluoropropyl perfluorovinyl ether said tetrafluoroethylene polymer having an average particle size of less than 20 μm, dispersed in an inert diluent, said diluent having a thermoplastic aromatic polyethersulphone of reduced viscosity below 0.25 (as measured at 25° C on a solution of the polymer in dimethyl formamide containing 1 g of polymer in 100 cm 3 of solution) dissolved or dispersed as particles of size below 25 μm (as measured by a Micromerograph) therein, or the precursor to such a polyethersulphone, said thermoplastic aromatic polyethersulphone having repeat units of the general formula --Ar--SO 2 -- in which Ar is a divalent aromatic radical, at least some of the --Ar-- units having the structure ##STR9## in which Y is oxygen or the divalent radical obtained by removal of the hydrogen atoms from the --OH groups of an aromatic diol and in which 0 to 50% of the --SO 2 -- groups are replaced by --CO-- groups, said dispersion having a tetrafluoroethylene polymer/polyethersulphone (or precursor thereto) weight ratio between 4:1 and 1:3.
Claim 2
Dependent Claim 200 words
A coating dispersion comprising a tetrafluoroethylene polymer selected from tetrafluoroethylene homopolymers, telomers, or copolymers with up to 5% by weight of a comonomer, such as ethylene, vinyl chloride, hexafluoropropene or perfluoropropyl perfluorovinyl ether said tetrafluoroethylene polymer having an average particle size of less than 20 μm, dispersed in an inert diluent, said diluent having a thermoplastic aromatic polyethersulphone of reduced viscosity below 0.25 (as measured at 25° C on a solution of the polymer in dimethyl formamide containing 1 g of polymer in 100 cm 3 of solution) dissolved or dispersed as particles of size below 25 μm (as measured by a Micromerograph) therein, or the precursor to such a polyethersulphone, said thermoplastic aromatic polyethersulphone having repeat units of the general formula --Ar--SO 2 -- in which Ar is a divalent aromatic radical, at least some of the --Ar-- units having the structure ##STR9## in which Y is oxygen or the divalent radical obtained by removal of the hydrogen atoms from the --OH groups of an aromatic diol and in which 0 to 50% of the --SO 2 -- groups are replaced by --CO-- groups, said dispersion having a tetrafluoroethylene polymer/polyethersulphone (or precursor thereto) weight ratio between 4:1 and 1:3.
Claim 3
Dependent Claim 13 words
A dispersion according to claim 1 wherein the polyethersulphone is a preformed polymer.
Claim 4
Dependent Claim 19 words
A dispersion according to claim 2 wherein the polyethersulphone has alkoxy end groups containing 1 to 4 carbon atoms.
Claim 5
Dependent Claim 15 words
A dispersion according to claim 2 in which the polyethersulphone has the repeat unit ##STR10##
Claim 6
Dependent Claim 15 words
A dispersion according to claim 2 in which the polyethersulphone has the repeat unit ##STR11##
Claim 7
Dependent Claim 20 words
A dispersion according to claim 2 in which the polyethersulphone has a reduced viscosity within the range 0.03 to 0.2.
Claim 8
Dependent Claim 22 words
A dispersion according to claim 1 wherein the dispersion has a tetrafluoroethylene polymer/polyethersulphone (or precursor thereto) weight ratio between 0.9:1 and 1.4:1.
Claim 9
Dependent Claim 12 words
A dispersion according to claim 1 wherein the inert diluent is water.
Claim 10
Dependent Claim 15 words
A dispersion according to claim 1 wherein the tetrafluoroethylene polymer is a lubricant grade polytetrafluoroethylene.
Claim 11
Dependent Claim 23 words
A dispersion according to claim 1 containing a combined content of tetrafluoroethylene and polyethersulphone of 20 to 50% by weight of the dispersion.
Claim 12
Dependent Claim 22 words
A dispersion according to claim 1 containing 1 to 10% by weight of titanium dioxide, based on the weight of the dispersion.

References Cited (Backward Citations)

US3993843A Cited
US3992347A Cited
US3981945A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-22 1981-11-21 1982-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-22 1985-11-21 1986-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-22 1989-11-21 1990-05-23 $7700.00 Window Closed / Lapsed

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