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US4090990A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing polyformals in the presence of an organic epoxide

Assignee: Wyeth Holdings LLC
•
Filing: 1976-12-20
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Granted: 1978-05-23
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Expires: 1996-12-20
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Abstract

Abstract An improved process for preparing polyformals is provided which comprises condensing an aliphatic diol, in which the hydroxyl groups are separated by at least four carbon atoms, with an essentially stoichiometric amount of formaldehyde in the presence of a Bronsted acid catalyst and contacting the condensation product with an organic epoxide in an amount sufficient to react with the residue of said catalyst.

Inventors

  • 👤 Ajaib Singh
  • 👤 Samuel Kaizerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 21:16
CPC Classifications
C; C08; C08G; C08G4/00; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/56

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 77 words
In a process for preparing a polyformal which comprises condensing an aliphatic diol, in which the hydroxyl groups are separated by at least four carbon atoms, with an essentially stoichiometric amount of formaldehyde in the presence of a Bronsted acid catalyst, the improvement which comprises contacting the condensation product thus formed with an organic epoxide in an amount sufficient to react with the residue of said acid catalyst, whereby said acid residue is removed from said polyformal.
Claim 2
Dependent Claim 77 words
In a process for preparing a polyformal which comprises condensing an aliphatic diol, in which the hydroxyl groups are separated by at least four carbon atoms, with an essentially stoichiometric amount of formaldehyde in the presence of a Bronsted acid catalyst, the improvement which comprises contacting the condensation product thus formed with an organic epoxide in an amount sufficient to react with the residue of said acid catalyst, whereby said acid residue is removed from said polyformal.
Claim 3
Dependent Claim 12 words
The process according to claim 1 wherein the aliphatic diol is 1,6-hexanediol.
Claim 4
Dependent Claim 13 words
The process according to claim 1 wherein the acid catalyst is p-toluenesulfonic acid.
Claim 5
Dependent Claim 12 words
The process according to claim 1 wherein the organic epoxide is 3,4-epoxycyclohexanecarboxylate.
Claim 6
Dependent Claim 14 words
The process according to claim 1 wherein the organic epoxide is epoxidized soybean oil.

References Cited (Backward Citations)

US2485160A Cited
US2786067A Cited
US3055871A Cited
US3183211A Cited
US3210318A Cited
US3271369A Cited
US3419531A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-22 1981-11-21 1982-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-22 1985-11-21 1986-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-22 1989-11-21 1990-05-23 $7700.00 Window Closed / Lapsed

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