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US4090969A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of oil recovery by flooding employing betaine solutions

Assignee: Henkel AG and Co KGaA
•
Filing: 1977-01-10
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Granted: 1978-05-23
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Expires: 1997-01-10
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Abstract

Abstract A method of extracting mineral oil from subterranean formation by flooding comprising the steps of forcing an aqueous liquid into a subterranean formation containing mineral oil and displacing the mineral oil through at least one bore hole in the subterranean formation, said aqueous liquid containing from 0.01% to 15% by weight of an amphoteric surface-active compound selected from the group consisting of (1) a betaine having the formula ##STR1## wherein R 1 and R 2 are members selected from the group consisting of hydrogen and alkyl having from 1 to 18 carbon atoms, with the proviso that the sum of the carbon atoms in R 1 + R 2 is from 9 to 18, R 3 and R 4 are members selected from the group consisting of lower alkyl and lower alkylol, x is an integer from 2 to 4, y is an integer from 0 to 1 and z is an integer from 1 to 4, and (2) mixtures of said betaine with up to 20% by weight of an acid having the formula ##STR2## wherein R 1 , R 2 , R 3 , R 4 , x and z have the above-assigned values.

Inventors

  • 👤 Karlheinz Koch
  • 👤 Horst Rutzen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:01
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/584; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 208 words
A method of extracting mineral oil from subterranean formation by flooding comprising the steps of forcing an aqueous liquid into a subterranean formation containing mineral oil and displacing the mineral oil through at least one bore hole in the subterranean formation, said aqueous liquid containing from 0.01% to 15% by weight of an amphoteric surface-active compound selected from the group consisting of (1) a betaine having the formula ##STR12## wherein R 1 and R 2 are members selected from the group consisting of hydrogen and alkyl having from 1 to 18 carbon atoms, with the proviso that at least one of R 1 and R 2 is hydrogen and the sum of the carbon atoms in R 1 + R 2 is from 9 to 18, R 3 and R 4 are members selected from the group consisting of lower alkyl and lower alkylol, x is an integer from 2 to 4, y is an integer from 0 to 1 and z is an integer from 1 to 4, and (2) mixtures of said betaine with up to 20% by weight of an acid having the formula ##STR13## wherein R 1 , R 2 , R 3 , R 4 , x and z have the above-assigned values.
Claim 2
Independent Claim 208 words
A method of extracting mineral oil from subterranean formation by flooding comprising the steps of forcing an aqueous liquid into a subterranean formation containing mineral oil and displacing the mineral oil through at least one bore hole in the subterranean formation, said aqueous liquid containing from 0.01% to 15% by weight of an amphoteric surface-active compound selected from the group consisting of (1) a betaine having the formula ##STR12## wherein R 1 and R 2 are members selected from the group consisting of hydrogen and alkyl having from 1 to 18 carbon atoms, with the proviso that at least one of R 1 and R 2 is hydrogen and the sum of the carbon atoms in R 1 + R 2 is from 9 to 18, R 3 and R 4 are members selected from the group consisting of lower alkyl and lower alkylol, x is an integer from 2 to 4, y is an integer from 0 to 1 and z is an integer from 1 to 4, and (2) mixtures of said betaine with up to 20% by weight of an acid having the formula ##STR13## wherein R 1 , R 2 , R 3 , R 4 , x and z have the above-assigned values.
Claim 3
Dependent Claim 21 words
The method of claim 1 wherein said aqueous liquid contains from 0.1% to 5% by weight of said amphoteric surface-active compound.
Claim 4
Dependent Claim 15 words
The method of claim 1 wherein one of R 1 and R 2 is hydrogen.
Claim 5
Dependent Claim 20 words
The method of claim 1 wherein said aqueous liquid has a dissolved salt content of up to 30% by weight.
Claim 6
Dependent Claim 17 words
The method of claim 4 wherein said dissolved salt content comprises water-soluble salts of sodium and calcium.

References Cited (Backward Citations)

US3360550A Cited
US3275552A Cited
US3888797A Cited
US3792731A Cited
US3811505A Cited
US3939911A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-22 1981-11-21 1982-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-22 1985-11-21 1986-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-22 1989-11-21 1990-05-23 $7700.00 Window Closed / Lapsed

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