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US4090951A Expired / Lapsed US ⏱️ 0.0 years remaining

Denitrogenation of syncrude

Assignee: Atlantic Richfield Co
•
Filing: 1977-06-06
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Granted: 1978-05-23
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Expires: 1997-06-06
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Abstract

Abstract A method for reducing the nitrogen content of a syncrude feed obtained from at least one of oil shale, tar sands, and coal wherein syncrude is mixed with an adsorbent which is effective for adsorbing nitrogen materials from the syncrude feed and also effective as a catalytic cracking catalyst for said syncrude feed. The mixture is settled into a first phase of low nitrogen syncrude material and a second phase of adsorbent and high nitrogen syncrude feed. The first phase can be subjected to additional light or mild hydrotreating, i.e. low temperature, high space velocity, etc. The second phase is stripped to separate low nitrogen syncrude material which is combined with the hydrotreated low nitrogen material to form a first low nitrogen syncrude product. The stripped second phase is catalytically cracked to produce a second low nitrogen syncrude product. The adsorbent from the cracking step is regenerated by heating to at least 1000° F in the presence of air or oxygen and the regenerated adsorbent is used either in the mixing step or the cracking step of the process.

Inventors

  • 👤 Robert H. Smith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 22:04
CPC Classifications
C; C10; C10G; C10G25/00; C10G25/02; C10G25/03; C10G25/05

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 219 words
A method for reducing the nitrogen content of a syncrude feed obtained from at least one of oil shale, tar sands, and coal, comprising mixing an adsorbent with said feed, said adsorbent being effective for and being employed in an amount effective to adsorb nitrogen materials from said syncrude feed and also to serve as a catalytic cracking catalyst for said syncrude feed, settling said mixture to form a first phase composed essentially of a low nitrogen syncrude material, and a second phase composed of said adsorbent and high nitrogen syncrude feed, separating said first and second phases from one another, hydrotreating said first phase to reduce the nitrogen content of said low nitrogen material, stripping low nitrogen syncrude material from said second phase, combining said material stripped from said second phase with said hydrotreated low nitrogen material to form a first low nitrogen syncrude product catalytically cracking said stripped second phase to produce a second low nitrogen syncrude product, recovering adsorbent from said cracking step, regenerating said recovered adsorbent by heating same at a temperature of at least 1000° F in the presence of air or oxygen to drive off nitrogen compounds and burn off at least part of the carbon previously deposited on said adsorbent, and reusing at least part of said regenerated adsorbent in the process.
Claim 2
Independent Claim 219 words
A method for reducing the nitrogen content of a syncrude feed obtained from at least one of oil shale, tar sands, and coal, comprising mixing an adsorbent with said feed, said adsorbent being effective for and being employed in an amount effective to adsorb nitrogen materials from said syncrude feed and also to serve as a catalytic cracking catalyst for said syncrude feed, settling said mixture to form a first phase composed essentially of a low nitrogen syncrude material, and a second phase composed of said adsorbent and high nitrogen syncrude feed, separating said first and second phases from one another, hydrotreating said first phase to reduce the nitrogen content of said low nitrogen material, stripping low nitrogen syncrude material from said second phase, combining said material stripped from said second phase with said hydrotreated low nitrogen material to form a first low nitrogen syncrude product catalytically cracking said stripped second phase to produce a second low nitrogen syncrude product, recovering adsorbent from said cracking step, regenerating said recovered adsorbent by heating same at a temperature of at least 1000° F in the presence of air or oxygen to drive off nitrogen compounds and burn off at least part of the carbon previously deposited on said adsorbent, and reusing at least part of said regenerated adsorbent in the process.
Claim 3
Dependent Claim 23 words
The method according to claim 1 wherein said adsorbent is selected from the group consisting of silica, alumina, silica alumina and mixtures thereof.
Claim 4
Dependent Claim 29 words
the method according to claim 1 wherein said adsorbent is employed in an amount of at least 5 weight percent based on the total weight of said syncrude feed.
Claim 5
Dependent Claim 24 words
The method according to claim 1 wherein said catalytic cracking is carried out at a temperature of from about 650° to about 1000° F.
Claim 6
Dependent Claim 12 words
The method according to claim 1 wherein said adsorbent is an aluminosilicate.

References Cited (Backward Citations)

US2744053A Cited
US2962435A Cited
US2984620A Cited
US3189539A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-22 1981-11-21 1982-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-22 1985-11-21 1986-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-22 1989-11-21 1990-05-23 $7700.00 Window Closed / Lapsed

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