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US4090884A Expired / Lapsed US ⏱️ 0.0 years remaining

Inhibitors for alkali-glass reactions in glass fiber reinforced cement products

Assignee: W R Bonsal Co
•
Filing: 1976-07-16
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Granted: 1978-05-23
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Expires: 1996-07-16
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Abstract

Abstract A glass reinforced cement composition containing a scavenger material as an inhibitor to prevent or greatly reduce attack and degradation of the glass reinforcement by the alkali content of the inorganic alkaline cement binder. The scavenger is a finely divided alkali-reactive material which contains silica as the major constituent thereof, and which has a reactivity with the alkali content of the binder substantially greater than the reactivity of the glass reinforcement therewith whereby the alkali content of the binder reacts with the scavenger in preference to reacting with the glass reinforcement.

Inventors

  • 👤 Friedrich Goeman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 03:17
CPC Classifications
C; C04; C04B; C04B28/00; C04B28/02; Y; Y10; Y10T; Y10T428/00; Y10T428/18; Y10T428/183

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 142 words
A glass reinforced cement mix suitable for high tensile strength applications such as surface bonding of cement blocks or the like or in the formation of concrete articles and characterized by a resistance to alkali-glass reaction resulting in loss of tensile strength, said cement mix comprising: ______________________________________ Parts by weight ______________________________________ Portland cement 100 Hydrated lime 0-30 Alkali susceptible E-glass reinforcement elements 2-15 Aggregate filler 0-300 Inhibitor for alkali- aggregate expansion reaction, ASTM-C-441 0-15 Finely divided alkali reactive scavenger material containing at least 65% SiO.sub.2 and comprising 30-325 mesh powdered soda lime glass 1-7 ______________________________________ said scavenger material having a reactivity with the alkali content of said Portland cement which is substantially greater than the reactivity of said glass reinforcement elements therewith whereby the alkali content of said Portland cement reacts with said scavenger material in preference to said glass reinforcement element.
Claim 2
Dependent Claim 142 words
A glass reinforced cement mix suitable for high tensile strength applications such as surface bonding of cement blocks or the like or in the formation of concrete articles and characterized by a resistance to alkali-glass reaction resulting in loss of tensile strength, said cement mix comprising: ______________________________________ Parts by weight ______________________________________ Portland cement 100 Hydrated lime 0-30 Alkali susceptible E-glass reinforcement elements 2-15 Aggregate filler 0-300 Inhibitor for alkali- aggregate expansion reaction, ASTM-C-441 0-15 Finely divided alkali reactive scavenger material containing at least 65% SiO.sub.2 and comprising 30-325 mesh powdered soda lime glass 1-7 ______________________________________ said scavenger material having a reactivity with the alkali content of said Portland cement which is substantially greater than the reactivity of said glass reinforcement elements therewith whereby the alkali content of said Portland cement reacts with said scavenger material in preference to said glass reinforcement element.
Claim 3
Dependent Claim 92 words
A glass reinforced cement mix suitable for high tensile strength applications such as surface bonding of cement blocks or the like or in the formation of concrete articles and characterized by a resistance to alkali glass reaction resulting in loss of tensile strength, said cement mix comprising: ______________________________________ Parts by weight ______________________________________ Portland cement 100 Hydrated lime 13-22 Fine sand aggregate 100-160 1/2" chopped glass fiber reinforcement 4-7 30-325 mesh soda-lime glass scavenger inhibitor .4-2 BaCl.sub.2 expansion inhibitor .5-3 Set accelerating admixture 1-3 Water retaining admixture .1-.4 Mineral oxide pigments 0-12 ______________________________________
Claim 4
Dependent Claim 92 words
A glass reinforced cement mix suitable for high tensile strength applications such as surface bonding of cement blocks or the like or in the formation of concrete articles and characterized by a resistance to alkali glass reaction resulting in loss of tensile strength, said cement mix comprising: ______________________________________ Parts by weight ______________________________________ Portland cement 100 Hydrated lime 13-22 Fine sand aggregate 100-160 1/2" chopped glass fiber reinforcement 4-7 30-325 mesh soda-lime glass scavenger inhibitor .4-2 BaCl.sub.2 expansion inhibitor .5-3 Set accelerating admixture 1-3 Water retaining admixture .1-.4 Mineral oxide pigments 0-12 ______________________________________
Claim 5
Dependent Claim 185 words
A surface bonded wall comprising an assembly of stacked concrete blocks and a glass reinforced surface bonding cement coating applied over at least one surface of the assembly of stacked concrete blocks and serving to bond the blocks together without the necessity of mortar between the blocks, said surface bonding cement coating being characterized by a resistance to alkali degradation of the glass reinforcement resulting in loss of tensile strength, and said cement coating comprising an inorganic cementitious binder containing at least one reactive alkali compound, glass reinforcement, and a finely-divided alkali-reactive scavenger material, said scavenger material containing silica as the major constituent thereof and having a reactivity with the alkali content of said binder which is substantially greater than the reactivity of said glass reinforcement therewith whereby the alkali content of said binder reacts with said scavenger material in preference to the glass reinforcement to protect the glass reinforcement from degradation from the alkali content of the binder, and the amount of said scavenger material, based upon the silica content thereof, being at least in stochiometric proportion to the alkali content of said binder.
Claim 6
Dependent Claim 185 words
A surface bonded wall comprising an assembly of stacked concrete blocks and a glass reinforced surface bonding cement coating applied over at least one surface of the assembly of stacked concrete blocks and serving to bond the blocks together without the necessity of mortar between the blocks, said surface bonding cement coating being characterized by a resistance to alkali degradation of the glass reinforcement resulting in loss of tensile strength, and said cement coating comprising an inorganic cementitious binder containing at least one reactive alkali compound, glass reinforcement, and a finely-divided alkali-reactive scavenger material, said scavenger material containing silica as the major constituent thereof and having a reactivity with the alkali content of said binder which is substantially greater than the reactivity of said glass reinforcement therewith whereby the alkali content of said binder reacts with said scavenger material in preference to the glass reinforcement to protect the glass reinforcement from degradation from the alkali content of the binder, and the amount of said scavenger material, based upon the silica content thereof, being at least in stochiometric proportion to the alkali content of said binder.

References Cited (Backward Citations)

US3969567A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-22 1981-11-21 1982-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-22 1985-11-21 1986-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-22 1989-11-21 1990-05-23 $7700.00 Window Closed / Lapsed

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