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US4090562A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and solvent composition for stimulating the production of oil from a producing well

Assignee: Union Oil Company of California
•
Filing: 1976-07-29
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Granted: 1978-05-23
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Expires: 1996-07-29
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Abstract

Abstract A method and solvent composition for removing viscous crude oil, waxes, asphaltenes and resin precipitates of petroleum origin from oil wells, flow lines and pore spaces of oil-bearing formations. The solvent composition is a mixture of about 45 to about 85 volume percent of a nornally liquid aliphatic hydrocarbon boiling in the range of about 120° F. to about 550° F., between about 5 to 45 volume percent of a normally liquid aromatic hydrocarbon, between about 0.5 to about 6 volume percent of an ether of an aliphatic polyhydric alcohol, and between about 1 to about 15 volume percent of a lower alkyl monohydric alcohol.

Inventors

  • 👤 George P. Maly
  • 👤 John A. Landess
  • 👤 Thomas Foral

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:11
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/52; C09K8/524; Y; Y10; Y10S; Y10S507/00; Y10S507/927; Y10S507/929; Y10S507/93; Y10S507/931

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 188 words
The method for removing viscous crude oil, waxes, asphaltenes and resin precipitates of petroleum origin from pore spaces of oil-bearing formations, wells and flow lines comprising contacting said waxes, asphaltenes and resin precipitates of petroleum origin with a solvent composition consisting essentially of between about 45 to 85 volume percent of a normally liquid aliphatic hydrocarbon boiling in the range of about 120° to about 550° F. selected from the group consisting of kerosene and aviation turbine fuels; about 5 to 45 volume percent of a normally liquid aromatic hydrocarbon having a boiling point above about 175° F. selected from the group consisting of benzene, toluene, ethylbenzene, cumene, mesitylene and propylbenzene; about 0.5 to 6 volume percent of an aliphatic ether of an aliphatic polyhydric alcohol containing at least one free hydroxyl group, having a boiling point above 212° F. and containing less than about 20 carbon atoms selected from the group consisting of ethylene glycol monobutyl ether and monomethyl ether diethylene glycol; and about 1 to 15 volume percent of a lower alkyl monohydric alcohol selected from the group consisting of methanol, ethanol, propanol, isopropanol and butanol.
Claim 2
Independent Claim 188 words
The method for removing viscous crude oil, waxes, asphaltenes and resin precipitates of petroleum origin from pore spaces of oil-bearing formations, wells and flow lines comprising contacting said waxes, asphaltenes and resin precipitates of petroleum origin with a solvent composition consisting essentially of between about 45 to 85 volume percent of a normally liquid aliphatic hydrocarbon boiling in the range of about 120° to about 550° F. selected from the group consisting of kerosene and aviation turbine fuels; about 5 to 45 volume percent of a normally liquid aromatic hydrocarbon having a boiling point above about 175° F. selected from the group consisting of benzene, toluene, ethylbenzene, cumene, mesitylene and propylbenzene; about 0.5 to 6 volume percent of an aliphatic ether of an aliphatic polyhydric alcohol containing at least one free hydroxyl group, having a boiling point above 212° F. and containing less than about 20 carbon atoms selected from the group consisting of ethylene glycol monobutyl ether and monomethyl ether diethylene glycol; and about 1 to 15 volume percent of a lower alkyl monohydric alcohol selected from the group consisting of methanol, ethanol, propanol, isopropanol and butanol.
Claim 3
Dependent Claim 24 words
The method defined in claim 1 wherein said solvent composition is an admixture of aviation turbine fuel, toluene, ethylene glycol monobutyl ether and isopropanol.
Claim 4
Independent Claim 182 words
The method of treating an oil-bearing formation which comprises introducing into a well penetrating said formation a solvent consisting essentially of about 45 to 85 volume percent of a normally liquid aliphatic hydrocarbon boiling in the range of about 120° to about 550° F. selected from the group consisting of kerosene and aviation turbine fuels, about 5 to 45 volume percent of a normally liquid aromatic hydrocarbon having a boiling point above about 175° F. selected from the group consisting of benzene, toluene, ethylbenzene, cumene, mesitylene and propylbenzene, about 0.5 to 6 volume percent of an aliphatic ether of an aliphatic polyhydric alcohol containing at least one free hydroxyl group, having a boiling point above 212° F. and containing less than about 20 carbon atoms selected from the group consisting of ethylene glycol monobutyl ether and monomethyl ether diethylene glycol, and about 1 to 15 volume percent of a lower alkyl monohydric alcohol selected from the group consisting of methanol, ethanol, propanol, isopropanol and butanol; and thereafter applying fluid pressure to said solvent to force it into the interstices of said formation.
Claim 5
Independent Claim 182 words
The method of treating an oil-bearing formation which comprises introducing into a well penetrating said formation a solvent consisting essentially of about 45 to 85 volume percent of a normally liquid aliphatic hydrocarbon boiling in the range of about 120° to about 550° F. selected from the group consisting of kerosene and aviation turbine fuels, about 5 to 45 volume percent of a normally liquid aromatic hydrocarbon having a boiling point above about 175° F. selected from the group consisting of benzene, toluene, ethylbenzene, cumene, mesitylene and propylbenzene, about 0.5 to 6 volume percent of an aliphatic ether of an aliphatic polyhydric alcohol containing at least one free hydroxyl group, having a boiling point above 212° F. and containing less than about 20 carbon atoms selected from the group consisting of ethylene glycol monobutyl ether and monomethyl ether diethylene glycol, and about 1 to 15 volume percent of a lower alkyl monohydric alcohol selected from the group consisting of methanol, ethanol, propanol, isopropanol and butanol; and thereafter applying fluid pressure to said solvent to force it into the interstices of said formation.
Claim 6
Independent Claim 80 words
The method for removing waxes, asphaltenes and resin precipitates of petroleum origin from pore spaces of oil-bearing formations, wells and flow lines comprising placing in contact with said waxes, asphaltenes and resin precipitates of petroleum origin a solvent composition comprising about 50 to 80 volume percent of Jet A aviation turbine fuel, about 10 to 30 volume percent of toluene, about 1 to 5 volume percent of ethylene glycol monobutyl ether, and about 1 to 10 volume percent of isopropanol.
Claim 7
Independent Claim 80 words
The method for removing waxes, asphaltenes and resin precipitates of petroleum origin from pore spaces of oil-bearing formations, wells and flow lines comprising placing in contact with said waxes, asphaltenes and resin precipitates of petroleum origin a solvent composition comprising about 50 to 80 volume percent of Jet A aviation turbine fuel, about 10 to 30 volume percent of toluene, about 1 to 5 volume percent of ethylene glycol monobutyl ether, and about 1 to 10 volume percent of isopropanol.

References Cited (Backward Citations)

US2356205A Cited
US2753939A Cited
US3241614A Cited
US3402770A Cited
US3279541A Cited
US3756319A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-22 1981-11-21 1982-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-22 1985-11-21 1986-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-22 1989-11-21 1990-05-23 $7700.00 Window Closed / Lapsed

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