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US4089837A Expired / Lapsed US ⏱️ 0.0 years remaining

Shell molding process and composition

Assignee: Hexion Inc
•
Filing: 1977-03-07
•
Granted: 1978-05-16
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Expires: 1997-03-07
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Abstract

Abstract Shell cores and molds are prepared more rapidly by the shell process using resin coated sands wherein the resin is a phenol-formaldehyde novalak resin but having a small amount, e.g. about 1 to about 10 percent by weight, of resorcinol incorporated therein whereby a significant reduction in the cycle time required to produce the cores or molds is achieved.

Inventors

  • 👤 Manfred Luttinger
  • 👤 George E. Cremeans
  • 👤 Louis J. Nowacki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 16:10
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08K3/36; B; B22; B22C; B22C1/00; B22C1/16; B22C1/20; B22C1/22; B22C1/2233; B22C1/2246; B22C1/2253; C08K5/00; C08K5/04; C08K5/13

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 39 words
A composition for the shell process comprising an admixture of sand, a phenol-formaldehyde novalak resin, a curing agent for the resin and a small but effective amount of resorcinol sufficient to reduce the cycle time of the shell process.
Claim 2
Dependent Claim 39 words
A composition for the shell process comprising an admixture of sand, a phenol-formaldehyde novalak resin, a curing agent for the resin and a small but effective amount of resorcinol sufficient to reduce the cycle time of the shell process.
Claim 3
Dependent Claim 31 words
The composition of claim 1, wherein the phenol-formaldehyde novalak resin is present in the composition at about 1 to about 8 percent by weight based on the weight of the sand.
Claim 4
Dependent Claim 30 words
The composition of claim 2, wherein the curing agent is present in the composition at about 5 to about 22 percent by weight based on the weight of the resin.
Claim 5
Dependent Claim 11 words
The composition of claim 1, wherein the curing agent is hexamethylenetetramine.
Claim 6
Dependent Claim 29 words
The composition of claim 3, wherein resorcinol is present in the composition at about 1 to about 10 percent by weight based on the solids weight of the resin.
Claim 7
Dependent Claim 29 words
The composition of claim 1, wherein resorcinol is present in the composition at about 1 to about 10 percent by weight based on the solids weight of the resin.
Claim 8
Dependent Claim 30 words
The composition of claim 1, wherein the resorcinol is present in the composition at about 2 1/2 to about 8% by weight based on the solids weight of the resin.
Claim 9
Dependent Claim 70 words
A process for forming a shell component comprising mixing a major proportion of sand, a minor proportion of a phenol-formaldehyde novalak resin, a curing agent which makes the resin thermosetting and a small but effective amount of resorcinol, which decreases the cycle time of forming the shell component, and thereafter, placing the mixture in contact with a heated pattern to bond the sand particles together into a hardened shell component.
Claim 10
Dependent Claim 70 words
A process for forming a shell component comprising mixing a major proportion of sand, a minor proportion of a phenol-formaldehyde novalak resin, a curing agent which makes the resin thermosetting and a small but effective amount of resorcinol, which decreases the cycle time of forming the shell component, and thereafter, placing the mixture in contact with a heated pattern to bond the sand particles together into a hardened shell component.
Claim 11
Dependent Claim 32 words
The process of claim 8, wherein the curing agent is hexamethylenetetramine, and the curing agent is present at a concentration of about 5 to about 22 percent by weight of the resin.
Claim 12
Dependent Claim 32 words
The process of claim 8, wherein the resin is present in the mixture at a concentration of about 1 to about 8 percent by weight based on the weight of the sand.
Claim 13
Dependent Claim 29 words
The process of claim 8, wherein resorcinol is present at a concentration of about 1 to about 10 percent by weight based on the solids weight of the resin.
Claim 14
Dependent Claim 29 words
The process of claim 8, wherein resorcinol is present at a concentration of about 2 1/2 to about 8% by weight based on the solids weight of the resin.

References Cited (Backward Citations)

US2414416A Cited
US2599870A Cited
US2806832A Cited
US3118850A Cited
US3422068A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-15 1981-11-14 1982-05-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-15 1985-11-14 1986-05-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-15 1989-11-14 1990-05-16 $7700.00 Window Closed / Lapsed

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