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US4089694A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass composition

Assignee: General Electric Co
•
Filing: 1976-08-04
•
Granted: 1978-05-16
•
Expires: 1996-08-04
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Abstract

Abstract A CaO containing silicate glass composition which can further contain small amounts of lead oxide and barium oxide is generally useful for hermetically sealing the electrical in-leads of various electrical devices. The present glass has a composition range in percentages by weight of: ______________________________________ Constituents Weight Percent ______________________________________ SiO 2 65-75 Na 2 O 9-13 K 2 O 3-6 Al 2 O 3 1-4 CaO 4-8 BaO 0-4 PbO 0-6 Li 2 O 0-2 ______________________________________ along with minor amounts of incidental impurities, residual fluxes and refining agents.

Inventors

  • 👤 George L. Thomas
  • 👤 Edward L. Woodall, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 05:35
CPC Classifications
C; C03; C03C; C03C8/00; C03C8/24; C03C3/00; C03C3/04; C03C3/076; C03C3/083; C03C3/085; C03C3/087; C03C3/102; C03C3/105

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 198 words
A seal glass composition for electric devices which consists essentially of in approximate percent by weight 65-75 SiO 2 , 9-13 Na 2 O, 3-6 K 2 O, 1-4 Al 2 O 3 , 4-8 CaO, 0-4 BaO, 0-6 PbO, 0-1F, and 0-2 Li 2 O along with minor amounts of incidental impurities, residual fluxes, and refining agents, and wherein the Na 2 O to K 2 O ratio lies between about 1.5 to about 4.5 with a high Na 2 O/K 2 O ratio when the CaO is high whereas the Na 2 O/K 2 O ratio is low when the CaO is low, said glass composition having a softening point in the approximate range 625°-670° C, a sealing point in the approximate range 820°-870° C, a working point in the approximate range 950°-990° C, a working range of at least 300° C, an average coefficient of linear thermal expansion in the 0°-300° C temperature range between about 87 × 10 -7 cm/cm/° C to about 97 × 10-7 cm/cm/° C, and electrical resistivity greater than 10 7 .1 ohm-cm at 250° C together with an electrical resistivity greater than 10 5 .5 ohm-cm at 350° C.
Claim 2
Dependent Claim 198 words
A seal glass composition for electric devices which consists essentially of in approximate percent by weight 65-75 SiO 2 , 9-13 Na 2 O, 3-6 K 2 O, 1-4 Al 2 O 3 , 4-8 CaO, 0-4 BaO, 0-6 PbO, 0-1F, and 0-2 Li 2 O along with minor amounts of incidental impurities, residual fluxes, and refining agents, and wherein the Na 2 O to K 2 O ratio lies between about 1.5 to about 4.5 with a high Na 2 O/K 2 O ratio when the CaO is high whereas the Na 2 O/K 2 O ratio is low when the CaO is low, said glass composition having a softening point in the approximate range 625°-670° C, a sealing point in the approximate range 820°-870° C, a working point in the approximate range 950°-990° C, a working range of at least 300° C, an average coefficient of linear thermal expansion in the 0°-300° C temperature range between about 87 × 10 -7 cm/cm/° C to about 97 × 10-7 cm/cm/° C, and electrical resistivity greater than 10 7 .1 ohm-cm at 250° C together with an electrical resistivity greater than 10 5 .5 ohm-cm at 350° C.
Claim 3
Dependent Claim 37 words
A glass composition as in claim 1 having an average coefficient of linear thermal expansion in the 0°-300° C temperature range between about 89 × 10 -7 cm/cm/° C to about 93 × 10 -7 cm/cm/° C.

References Cited (Backward Citations)

US2527693A Cited
US3445255A Cited
US3837831A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-15 1981-11-14 1982-05-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-15 1985-11-14 1986-05-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-15 1989-11-14 1990-05-16 $7700.00 Window Closed / Lapsed

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