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US4088627A Expired / Lapsed US ⏱️ 0.0 years remaining

Multicomponent polyurethane-block copolymer blends

Assignee: Shell USA Inc
•
Filing: 1977-05-05
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Granted: 1978-05-09
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Expires: 1997-05-05
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Abstract

Abstract A multicomponent polymer blend composition is prepared by intimately mixing a polyurethane, a selectively hydrogenated monoalkenyl arene-diene block copolymer, and at least one dissimilar engineering thermoplastic resin under such conditions that at least two of the polymers form at least partial continuous network phases which interlock with the other polymer networks and therefore results in a desirable balance of properties.

Inventors

  • 👤 William P. Gergen
  • 👤 Sol Davison

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:38
CPC Classifications
C; C08; C08L; C08L75/00; C08L75/04; C08L101/00; C08L53/00; C08L53/02; C08L53/025; C08L67/00; C08L69/00; C08L77/00; C08L2205/00; C08L2205/04; C08L59/00; C08L71/00

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 202 words
A composition comprising the admixture obtained by intimately mixing about 4 to about 40 parts by weight of a block copolymer, about 5 to about 48 parts by weight of at least one dissimilar engineering thermoplastic, and a thermoplastic polyurethane in a weight ratio of polyurethane to dissimilar engineering thermoplastic of greater than 1:1, so as to form a polyblend wherein at least two of the polymers have at least partial continuous interlocked networks with each other and wherein: (a) said block copolymer comprises at least two monoalkenyl arene polymer end blocks A and at least one substantially completely hydrogenated conjugated diene polymer mid block B, said block copolymer having an 8 to 55 percent by weight monoalkenyl arene polymer block content, each polymer block A having an average molecular weight of between about 5,000 and about 125,000, and each polymer block B having an average molecular weight of between about 10,000 and about 300,000; (b) said thermoplastic polyurethane has a generally crystalline structure and a melting point over about 120° C; and (c) said dissimilar engineering thermoplastic resin is capable of forming a continuous structure and is selected from the group consisting of poly(aryl ethers), poly(aryl sulfones) polycarbonates and acetal resins.
Claim 2
Dependent Claim 202 words
A composition comprising the admixture obtained by intimately mixing about 4 to about 40 parts by weight of a block copolymer, about 5 to about 48 parts by weight of at least one dissimilar engineering thermoplastic, and a thermoplastic polyurethane in a weight ratio of polyurethane to dissimilar engineering thermoplastic of greater than 1:1, so as to form a polyblend wherein at least two of the polymers have at least partial continuous interlocked networks with each other and wherein: (a) said block copolymer comprises at least two monoalkenyl arene polymer end blocks A and at least one substantially completely hydrogenated conjugated diene polymer mid block B, said block copolymer having an 8 to 55 percent by weight monoalkenyl arene polymer block content, each polymer block A having an average molecular weight of between about 5,000 and about 125,000, and each polymer block B having an average molecular weight of between about 10,000 and about 300,000; (b) said thermoplastic polyurethane has a generally crystalline structure and a melting point over about 120° C; and (c) said dissimilar engineering thermoplastic resin is capable of forming a continuous structure and is selected from the group consisting of poly(aryl ethers), poly(aryl sulfones) polycarbonates and acetal resins.
Claim 3
Dependent Claim 26 words
A composition according to claim 1 wherein said block copolymer monoalkenyl arene is styrene and said block copolymer conjugated diene is selected from isoprene and butadiene.
Claim 4
Dependent Claim 15 words
A composition according to claim 1 wherein said block copolymer has an ABA linear structure.
Claim 5
Dependent Claim 14 words
A composition according to claim 1 wherein said block copolymer has a branched structure.
Claim 6
Dependent Claim 32 words
A composition according to claim 3 wherein said block copolymer is a selectively hydrogenated block copolymer of styrene and butadiene, said butadiene having a 1,2 content of between about 35% and 55%.
Claim 7
Dependent Claim 20 words
A composition according to claim 1 wherein said thermoplastic polyurethane has an apparent crystalline melting point of about 165° C.
Claim 8
Dependent Claim 14 words
A composition according to claim 1 wherein said dissimilar engineering thermoplastic is a polycarbonate.
Claim 9
Dependent Claim 18 words
A composition according to claim 1 which contains about 2 to about 80 percent by weight glass fibers.
Claim 10
Dependent Claim 23 words
A composition according to claim 1 wherein the block copolymer, polyurethane, and dissimilar engineering thermoplastic are melt blended under essentially isoviscous blending conditions.
Claim 11
Dependent Claim 41 words
A composition according to claim 9 wherein the viscosity ratio of the viscosity of the block copolymer divided by the viscosity of the polyurethane, dissimilar engineering thermoplastic, or mixture thereof is between about 0.2 and 4.0 at the processing temperature Tp.
Claim 12
Dependent Claim 17 words
A composition according to claim 10 wherein said viscosity ratio is between about 0.8 and about 1.2.
Claim 13
Dependent Claim 20 words
A composition according to claim 10 wherein said processing temperature Tp is between about 150° C and about 400° C.

References Cited (Backward Citations)

US3562355A Cited
US3646162A Cited
US3975460A Cited
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US4006116A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-08 1981-11-07 1982-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-08 1985-11-07 1986-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-08 1989-11-07 1990-05-09 $7700.00 Window Closed / Lapsed

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