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US4088595A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent composition comprising a system producing superoxide ions

Assignee: Bpifrance Financement SA
•
Filing: 1976-08-06
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Granted: 1978-05-09
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Expires: 1996-08-06
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Abstract

Abstract The invention relates to an improved detergent composition. This composition comprises at least one hydrosoluble salt of a metal selected from the group consisting of divalent iron, divalent cobalt and divalent nickel, associated with at least one hydrosoluble ligand which is a hydrogen donor and has at least two sites available for fixing to the said metal. Application to all cleaning, and preferably to laundry and dishwashing.

Inventors

  • 👤 Adolf M. Michelson
  • 👤 Philippe Rotter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:20
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3942; C11D3/02; C11D3/04; C11D3/046; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086; C11D3/2089

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 97 words
A detergent composition consisting essentially of soap or granular synthetic detergents, and an amount sufficient to produce superoxide ions of at least one water soluble salt of a metal selected from the group consisting of divalent iron, divalent cobalt and divalent nickel, and an amount in moles of from 1 to 10 times that of the divalent metal ions of at least one water soluble ligand which is a hydrogen donor and has at least two sites available for fixing to the said metal selected from the group consisting of --NH 2 and --COOH and mixtures thereof.
Claim 2
Dependent Claim 97 words
A detergent composition consisting essentially of soap or granular synthetic detergents, and an amount sufficient to produce superoxide ions of at least one water soluble salt of a metal selected from the group consisting of divalent iron, divalent cobalt and divalent nickel, and an amount in moles of from 1 to 10 times that of the divalent metal ions of at least one water soluble ligand which is a hydrogen donor and has at least two sites available for fixing to the said metal selected from the group consisting of --NH 2 and --COOH and mixtures thereof.
Claim 3
Dependent Claim 99 words
A detergent compositon of claim 1 free of per compounds consisting essentially of soap, an amount sufficient to produce superoxide ions of at least one water soluble salt of a metal selected from the group consisting of divalent iron, divalent nickel and divalent cobalt and an amount in moles of from 1 to 10 times that of the divalent metal ions of at least one water soluble ligand which is a hydrogen donor and has at least two sites available for fixing to the said metal selected from the group consisting of --NH 2 and --COOH and mixtures thereof.
Claim 4
Dependent Claim 26 words
A detergent composition according to claim 1 wherein said ligand is selected from the group consisting of tetraglycine fumaric acid and dihydroxyfumanic acid and salts thereof.
Claim 5
Dependent Claim 33 words
A detergent composition according to claim 1 wherein the metal salt is a Co 2+ salt and the ligand is selected from the group consisting of dihydroxyfumaric acid, tetraglycine and a mixture thereof.
Claim 6
Dependent Claim 38 words
A detergent composition according to claim 1 wherein the metal salt is a Ni 2+ salt and the ligand is selected from the group consisting of dihydroxyfumaric acid, a sodium or ammonium dihydroxyfumarate, tetraglycine and a mixture thereof.
Claim 7
Dependent Claim 34 words
A process for cleaning and removing said from any material consisting in washing said material to be cleaned in an aqueous bath of about 0.5% by weight of a detergent composition of claim 1.
Claim 8
Dependent Claim 27 words
A detergent composition of claim 1 wherein the amount of said metal and ligand is capable of releasing 10 -5 to 2×10 -3 m of superoxide ions.
Claim 9
Dependent Claim 12 words
A detergent composition of claim 1 which is free of per compounds.
Claim 10
Dependent Claim 8 words
A detergent composition of claim 8 containing soap.

References Cited (Backward Citations)

US3969387A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-08 1981-11-07 1982-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-08 1985-11-07 1986-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-08 1989-11-07 1990-05-09 $7700.00 Window Closed / Lapsed

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