US4088497A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Acutance agents for use in thermally-developable photosensitive compositions
Assignee: 3M Co
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Filing: 1977-03-25
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Granted: 1978-05-09
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Expires: 1997-03-25
Abstract
Abstract Certain members of the class of odd-numbered methine arylidene dye bases are found to be of use in thermally-developable photosensitive compositions and thermally-developable photosensitive elements containing such agents. These compounds are acutance agents which are relatively stable against photo-bleaching but undergo thermochemical bleaching on heating in silver salt-containing thermally-developable photosensitive compositions.
Inventors
- 👤 Harvey A. Brown
- 👤 Jack E. Reece
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 19:34
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/825; G03C1/83; G03C1/832; C; C07; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/24; C07D213/54; C07D213/57; C07D215/00; C07D215/02; C07D215/12; C07D277/00; C07D277/60; C07D277/62; C07D277/64; C09; C09K; C09K19/00; C09K19/52; C09K19/60; C09K19/605
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
168 words
In a photosensitive, heat-developable, dry silver sheet material containing an image forming system including in one layer a photosensitive silver halide catalyst-forming means and, as heat image-forming means, an organic silver compound, said image-forming system further including toner and a reducing agent the oxidation-reduction reaction of which latter with said organic silver compound being catalyzed by silver halide catalyst; the improvement characterized by the inclusion in said layer with said organic silver compound of an acutance agent represented by the formula ##STR10## wherein: Z represents the atoms necessary to complete a mono-or polycyclic dihydroheterocyclic nucleus having 5 to 6 atoms in the ring including the N of the formula; R 1 is an alkyl, substituted alkyl, alkenyl or aryl group; m = 0 or 1; k = 0, 1 or 2; T is an aprotic electron-withdrawing group having a σ para value of 0.45 to 0.63 selected from CF 3 or CN and R 2 and R 3 are hydrogen or together constitute a condensed carbocyclic aromatic ring.
Claim 2
Dependent Claim
168 words
In a photosensitive, heat-developable, dry silver sheet material containing an image forming system including in one layer a photosensitive silver halide catalyst-forming means and, as heat image-forming means, an organic silver compound, said image-forming system further including toner and a reducing agent the oxidation-reduction reaction of which latter with said organic silver compound being catalyzed by silver halide catalyst; the improvement characterized by the inclusion in said layer with said organic silver compound of an acutance agent represented by the formula ##STR10## wherein: Z represents the atoms necessary to complete a mono-or polycyclic dihydroheterocyclic nucleus having 5 to 6 atoms in the ring including the N of the formula; R 1 is an alkyl, substituted alkyl, alkenyl or aryl group; m = 0 or 1; k = 0, 1 or 2; T is an aprotic electron-withdrawing group having a σ para value of 0.45 to 0.63 selected from CF 3 or CN and R 2 and R 3 are hydrogen or together constitute a condensed carbocyclic aromatic ring.
Claim 3
Dependent Claim
38 words
The dry silver sheet material of claim 1 wherein, in the acutance agent, Z is a member of the group: --CH═CH--, --CH═CH--CH═CH--, ##STR11## where R.sup.4 is H, alkyl of 1-2 carbon atoms or alkoxy of 1-2 carbon atoms.
Claim 4
Dependent Claim
23 words
The dry silver sheet material of claim 1 wherein, in the acutance agent, R 1 is alkyl of 1 to 4 carbon atoms.
Claim 5
Dependent Claim
22 words
The dry silver sheet material of claim 1 wherein the reducing agent is in the same layer as the organic silver compound.
Claim 6
Dependent Claim
23 words
The dry silver sheet material of claim 1 wherein the image forming system includes the reducing agent and toner in a separate layer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-05-08 | 1981-11-07 | 1982-05-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-05-08 | 1985-11-07 | 1986-05-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-05-08 | 1989-11-07 | 1990-05-09 | $7700.00 | Window Closed / Lapsed |