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US4088497A Expired / Lapsed US ⏱️ 0.0 years remaining

Acutance agents for use in thermally-developable photosensitive compositions

Assignee: 3M Co
•
Filing: 1977-03-25
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Granted: 1978-05-09
•
Expires: 1997-03-25
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Abstract

Abstract Certain members of the class of odd-numbered methine arylidene dye bases are found to be of use in thermally-developable photosensitive compositions and thermally-developable photosensitive elements containing such agents. These compounds are acutance agents which are relatively stable against photo-bleaching but undergo thermochemical bleaching on heating in silver salt-containing thermally-developable photosensitive compositions.

Inventors

  • 👤 Harvey A. Brown
  • 👤 Jack E. Reece

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 19:34
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/825; G03C1/83; G03C1/832; C; C07; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/24; C07D213/54; C07D213/57; C07D215/00; C07D215/02; C07D215/12; C07D277/00; C07D277/60; C07D277/62; C07D277/64; C09; C09K; C09K19/00; C09K19/52; C09K19/60; C09K19/605

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 168 words
In a photosensitive, heat-developable, dry silver sheet material containing an image forming system including in one layer a photosensitive silver halide catalyst-forming means and, as heat image-forming means, an organic silver compound, said image-forming system further including toner and a reducing agent the oxidation-reduction reaction of which latter with said organic silver compound being catalyzed by silver halide catalyst; the improvement characterized by the inclusion in said layer with said organic silver compound of an acutance agent represented by the formula ##STR10## wherein: Z represents the atoms necessary to complete a mono-or polycyclic dihydroheterocyclic nucleus having 5 to 6 atoms in the ring including the N of the formula; R 1 is an alkyl, substituted alkyl, alkenyl or aryl group; m = 0 or 1; k = 0, 1 or 2; T is an aprotic electron-withdrawing group having a σ para value of 0.45 to 0.63 selected from CF 3 or CN and R 2 and R 3 are hydrogen or together constitute a condensed carbocyclic aromatic ring.
Claim 2
Dependent Claim 168 words
In a photosensitive, heat-developable, dry silver sheet material containing an image forming system including in one layer a photosensitive silver halide catalyst-forming means and, as heat image-forming means, an organic silver compound, said image-forming system further including toner and a reducing agent the oxidation-reduction reaction of which latter with said organic silver compound being catalyzed by silver halide catalyst; the improvement characterized by the inclusion in said layer with said organic silver compound of an acutance agent represented by the formula ##STR10## wherein: Z represents the atoms necessary to complete a mono-or polycyclic dihydroheterocyclic nucleus having 5 to 6 atoms in the ring including the N of the formula; R 1 is an alkyl, substituted alkyl, alkenyl or aryl group; m = 0 or 1; k = 0, 1 or 2; T is an aprotic electron-withdrawing group having a σ para value of 0.45 to 0.63 selected from CF 3 or CN and R 2 and R 3 are hydrogen or together constitute a condensed carbocyclic aromatic ring.
Claim 3
Dependent Claim 38 words
The dry silver sheet material of claim 1 wherein, in the acutance agent, Z is a member of the group: --CH═CH--, --CH═CH--CH═CH--, ##STR11## where R.sup.4 is H, alkyl of 1-2 carbon atoms or alkoxy of 1-2 carbon atoms.
Claim 4
Dependent Claim 23 words
The dry silver sheet material of claim 1 wherein, in the acutance agent, R 1 is alkyl of 1 to 4 carbon atoms.
Claim 5
Dependent Claim 22 words
The dry silver sheet material of claim 1 wherein the reducing agent is in the same layer as the organic silver compound.
Claim 6
Dependent Claim 23 words
The dry silver sheet material of claim 1 wherein the image forming system includes the reducing agent and toner in a separate layer.

References Cited (Backward Citations)

US3457075A Cited
US3647433A Cited
US3988156A Cited
US4033948A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-08 1981-11-07 1982-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-08 1985-11-07 1986-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-08 1989-11-07 1990-05-09 $7700.00 Window Closed / Lapsed

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