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Organo-titanate chelates and their uses
Assignee: Kenrich Petrochemicals Inc
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Filing: 1976-04-19
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Granted: 1978-05-02
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Expires: 1996-04-19
Abstract
Abstract New chelate compounds which are alpha,omega-alkylene titanates having two non-hydrolyzable groups. The compounds may be represented by the formula: ##STR1## where A represents a non-hydrolyzable group, B is an R 2 C group or a carbonyl group, R may be hydrogen or alkyl groups having 1 to 6 carbon atoms and n may be 1 or 2. Preferably R is hydrogen. The R in a particular molecule may be the same or different. The compounds are particularly useful for treating inorganic fillers which are used to extend or modify the properties of polymeric materials. The compounds maintain high activity even when applied to filler containing free water.
Inventors
- 👤 Salvatore J. Monte
- 👤 Gerald Sugerman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 20:59
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F7/00; C07F7/003; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/30; C08G59/68; C08G59/70; C08K; C08K9/00; C08K9/04; C09; C09C; C09C3/00; C09C3/08; C01; C01P; C01P2004/00; C01P2004/80; C01P2004/82; C01P2004/84
Claims Analysis
Total Claims: 34
Claim 1
Independent Claim
94 words
An organo alpha, omega-alkylene titanate having the formula: ##STR6## wherein A represents a non-hydrolyzable aroxy, thioaroxy, --OCOR', --OSO 2 R", --OSOR", (R"O) 2 P(O)OP(OH)(O)--, or (R"O) 2 P(O)O-group; B is an R 2 C group or a carbonyl group; R is hydrogen or an alkyl group having from 1 to 6 carbon atoms; R' and R" are hydrogen or an alkyl, alkenyl, aryl, aralkyl or alkaryl group, or an alkyl, alkenyl, aryl, aralkyl, alkaryl, halo, amino, epoxy, ether, thioether, ester, cyano, carbonyl or aromatic nitro substituted derivative thereof; and n is 1 or 2.
Claim 2
Dependent Claim
94 words
An organo alpha, omega-alkylene titanate having the formula: ##STR6## wherein A represents a non-hydrolyzable aroxy, thioaroxy, --OCOR', --OSO 2 R", --OSOR", (R"O) 2 P(O)OP(OH)(O)--, or (R"O) 2 P(O)O-group; B is an R 2 C group or a carbonyl group; R is hydrogen or an alkyl group having from 1 to 6 carbon atoms; R' and R" are hydrogen or an alkyl, alkenyl, aryl, aralkyl or alkaryl group, or an alkyl, alkenyl, aryl, aralkyl, alkaryl, halo, amino, epoxy, ether, thioether, ester, cyano, carbonyl or aromatic nitro substituted derivative thereof; and n is 1 or 2.
Claim 3
Dependent Claim
37 words
The compound of claim 1 wherein A is --OSO 2 R" or a --OSOR" group and R" is phenyl, a substituted phenyl or an aralkyl group having from 5 to 24 carbon atoms in the alkyl chain.
Claim 4
Dependent Claim
22 words
The compound of claim 1 wherein A is a (R"O) 2 P(O)O-- group and R" has from 6 to 24 carbon atoms.
Claim 5
Dependent Claim
25 words
The compound of claim 1 wherein A is a (R"O) 2 P(O)OP(OH)(O)-- group and R" is an alkyl group having up to 12 carbon atoms.
Claim 6
Dependent Claim
16 words
The compound of claim 1 wherein R' is a long chain group having 18 carbon atoms.
Claim 7
Dependent Claim
19 words
The compound of claim 1 wherein the aryl portion of the aroxy and thioaroxy groups is phenyl or naphthyl.
Claim 8
Dependent Claim
18 words
The compound of claim 1 wherein the non-hydrolyzable groups are OCOR' having from 1 to 18 carbon atoms.
Claim 9
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR7## wherein R' is an isostearyl group.
Claim 10
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR7## wherein R' is an isostearyl group.
Claim 11
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR8## wherein R" is an octyl group.
Claim 12
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR8## wherein R" is an octyl group.
Claim 13
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR9## wherein R" is an octyl group.
Claim 14
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR9## wherein R" is an octyl group.
Claim 15
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR10## wherein R" is a dodecyl group.
Claim 16
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR10## wherein R" is a dodecyl group.
Claim 17
Dependent Claim
20 words
An organo-titanate compound having the formula: ##STR11## wherein R is an --CH═CH 2 group and R' is an isostearyl group.
Claim 18
Dependent Claim
20 words
An organo-titanate compound having the formula: ##STR11## wherein R is an --CH═CH 2 group and R' is an isostearyl group.
Claim 19
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR12## wherein R' is a methacryl group.
Claim 20
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR12## wherein R' is a methacryl group.
Claim 21
Dependent Claim
19 words
An organo-titanate compound having the formula: ##STR13## wherein R is an isostearyl group and R' is a 4-aminophenyl group.
Claim 22
Dependent Claim
19 words
An organo-titanate compound having the formula: ##STR13## wherein R is an isostearyl group and R' is a 4-aminophenyl group.
Claim 23
Dependent Claim
19 words
An organo-titanate compound having the formula: ##STR14## wherein R is a 4-aminophenyl group and R' is a dodecylphenyl group.
Claim 24
Dependent Claim
19 words
An organo-titanate compound having the formula: ##STR14## wherein R is a 4-aminophenyl group and R' is a dodecylphenyl group.
Claim 25
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR15## wherein Ar is a cumylphenyl group.
Claim 26
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR15## wherein Ar is a cumylphenyl group.
Claim 27
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR16## wherein R' is an octyl group.
Claim 28
Dependent Claim
13 words
An organo-titanate compound having the formula: ##STR16## wherein R' is an octyl group.
Claim 29
Dependent Claim
19 words
An organo-titanate compound having the formula: ##STR17## wherein R is a 4-aminophenyl group and R' is a dodecylphenyl group.
Claim 30
Dependent Claim
19 words
An organo-titanate compound having the formula: ##STR17## wherein R is a 4-aminophenyl group and R' is a dodecylphenyl group.
Claim 31
Dependent Claim
104 words
The composition of matter comprising comminuted inorganic material reacted with an alpha, omega-alkylene titanate having the formula: ##STR18## wherein A represents a non-hydrolyzable aroxy, thioaroxy, --OCOR', --OSO 2 R", --OSOR", (R"O) 2 P(O)OP(OH)(O)--, or (R"O) 2 P(O)O-- group; B is an R 2 C group or a carbonyl group; R is hydrogen or an alkyl group having from 1 to 6 carbon atoms; R' and R" are hydrogen or an alkyl, alkenyl, aryl, aralkyl or alkaryl group, or an alkyl, alkenyl, aryl, aralkyl, alkaryl, halo, amino, epoxy, ether, thioether, ester, cyano, carbonyl, or aromatic nitro substituted derivative thereof; and n is 1 or 2.
Claim 32
Dependent Claim
104 words
The composition of matter comprising comminuted inorganic material reacted with an alpha, omega-alkylene titanate having the formula: ##STR18## wherein A represents a non-hydrolyzable aroxy, thioaroxy, --OCOR', --OSO 2 R", --OSOR", (R"O) 2 P(O)OP(OH)(O)--, or (R"O) 2 P(O)O-- group; B is an R 2 C group or a carbonyl group; R is hydrogen or an alkyl group having from 1 to 6 carbon atoms; R' and R" are hydrogen or an alkyl, alkenyl, aryl, aralkyl or alkaryl group, or an alkyl, alkenyl, aryl, aralkyl, alkaryl, halo, amino, epoxy, ether, thioether, ester, cyano, carbonyl, or aromatic nitro substituted derivative thereof; and n is 1 or 2.
Claim 33
Dependent Claim
112 words
A filled polymeric composition which comprises a polymeric material admixed with a comminuted inorganic material reacted with an organic alpha, omega-alkylene titanate having the formula: ##STR19## wherein A represents a non-hydrolyzable aroxy, thioaroxy, --OCOR', --OSO 2 R", --OSOR", (R"O) 2 P(O)OP(OH)(O)--, or (R"O) 2 P(O)O-- group; B is an R 2 C group or a carbonyl group; R is hydrogen or an alkyl group having from 1 to 6 carbon atoms; R' and R" are hydrogen or an alkyl, alkenyl, aryl, aralkyl, or alkaryl group, or an alkyl, alkenyl, aryl, aralkyl, alkaryl, halo, amino, epoxy, ether, thioether, ester, cyano, carbonyl or aromatic nitro substituted derivative thereof; and n is 1 or 2.
Claim 34
Dependent Claim
112 words
A filled polymeric composition which comprises a polymeric material admixed with a comminuted inorganic material reacted with an organic alpha, omega-alkylene titanate having the formula: ##STR19## wherein A represents a non-hydrolyzable aroxy, thioaroxy, --OCOR', --OSO 2 R", --OSOR", (R"O) 2 P(O)OP(OH)(O)--, or (R"O) 2 P(O)O-- group; B is an R 2 C group or a carbonyl group; R is hydrogen or an alkyl group having from 1 to 6 carbon atoms; R' and R" are hydrogen or an alkyl, alkenyl, aryl, aralkyl, or alkaryl group, or an alkyl, alkenyl, aryl, aralkyl, alkaryl, halo, amino, epoxy, ether, thioether, ester, cyano, carbonyl or aromatic nitro substituted derivative thereof; and n is 1 or 2.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-05-01 | 1981-10-31 | 1982-05-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-05-01 | 1985-10-31 | 1986-05-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-05-01 | 1989-10-31 | 1990-05-02 | $7700.00 | Window Closed / Lapsed |