US4087393A
Expired / Lapsed
US
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Non-aqueous resin dispersion and method of manufacturing thereof
Assignee: Ricoh Co Ltd
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Filing: 1976-11-08
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Granted: 1978-05-02
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Expires: 1996-11-08
Abstract
Abstract A non-aqueous resin dispersion is obtained by dissolving a resin, which is substantially insoluble in non-aqueous solvents, in at least one monomer which can dissolve said resin, subjecting the resulting solution to polymerization reaction in the presence or in the absence of non-aqueous solvent, and if necessary, adding a non-aqueous solvent to the reaction product. The non-aqueous resin dispersion is useful as a coating material or as a liquid developer for use in electrophotography.
Inventors
- 👤 Kazuo Tsubuko
- 👤 Kenichi Matsubayashi
- 👤 Tsuneo Kurotori
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 21:02
CPC Classifications
C; C08; C08F; C08F291/00
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
129 words
A non-aqueous resin dispersion comprising a non-aqueous solvent selected from the group consisting of aliphatic hydrocarbons and halogen derivatives thereof, at least one resin which is substantially insoluble in said solvent, said resin being selected from the group consisting of natural resins and natural resin-modified thermosetting resins, and a polymer obtained by polymerizing at least one monomer A, wherein said monomer A has the formula ##STR2## wherein R is hydrogen or CH 3 , D is --COOC n H 2n+1 or --OC n H 2n+1 or and n is an integer ranging from 6 to 20, and which monomer A is capable of dissolving said resin, the weight ratio of said resin: said polymer being in the range of from about 5-50:50-95, said polymer being solvated with said solvent.
Claim 2
Dependent Claim
129 words
A non-aqueous resin dispersion comprising a non-aqueous solvent selected from the group consisting of aliphatic hydrocarbons and halogen derivatives thereof, at least one resin which is substantially insoluble in said solvent, said resin being selected from the group consisting of natural resins and natural resin-modified thermosetting resins, and a polymer obtained by polymerizing at least one monomer A, wherein said monomer A has the formula ##STR2## wherein R is hydrogen or CH 3 , D is --COOC n H 2n+1 or --OC n H 2n+1 or and n is an integer ranging from 6 to 20, and which monomer A is capable of dissolving said resin, the weight ratio of said resin: said polymer being in the range of from about 5-50:50-95, said polymer being solvated with said solvent.
Claim 3
Dependent Claim
60 words
A dispersion according to claim 1, which further comprises at least one dispersant selected from the group consisting of waxlike substances and polyolefins having a softening temperature in the range of 60° - 130° C, wherein the amount of said dispersant is in the range of 10 - 50 parts by weight per 100 parts by weight of said polymer.
Claim 4
Dependent Claim
61 words
A dispersion according to claim 1, wherein said polymer is a copolymer of monomer A and at least one monomer B selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, propylene glycol monoacrylate, propylene glycol methacrylate, hydroxyethyl methacrylate, acrylonitrile and methacrylonitrile, wherein the weight ratio of said monomer A to said monomer B is in the range of about 70-99:30-1.
Claim 5
Dependent Claim
73 words
A dispersion according to claim 1, wherein said polymer is a copolymer of monomer A and at least one monomer C selected from the group consisting of acrylic acid, methacrylic acid, lower alkyl esters of acrylic acid and methacrylic acid in which said alkyl has 1 - 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, wherein the weight ratio of monomer A:monomer C is in the range of about 50-90:50-10.
Claim 6
Dependent Claim
111 words
A dispersion according to claim 1 wherein said polymer is a terpolymer of monomer A, monomer B and monomer C, wherein monomer B is at least one monomer selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, propylene glycol monoacrylate, propylene glycol methacrylate, hydroxyethyl methacrylate, acrylonitrile and methacrylonitrile, wherein monomer C is at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, lower alkyl esters of acrylic acid and methacrylic acid in which said alkyl has 1 - 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, and wherein the weight ratio of monomer A:monomer B:monomer C is in the range of about 60-90:20-1:20-1.
Claim 7
Independent Claim
148 words
A method of manufacturing a non-aqueous resin dispersion, which comprises dissolving a resin selected from the group consisting of natural resins and natural resin-modified thermosetting resins in at least one monomer A, wherein said monomer A has the formula ##STR3## wherein R is hydrogen or CH 3 , D is --COOC n H 2n+1 or --OC n H 2n+1 or and n is an integer ranging from 6 to 20, and which can dissolve said resin, and effecting polymerization reaction of the resulting solution in the presence of a non-aqueous solvent, whereby to form a polymer of said monomer A, said non-aqueous solvent being selected from the group consisting of aliphatic hydrocarbons and halogen derivatives thereof, said resin being substantially insoluble in said non-aqueous solvent, the weight ratio of said resin: said polymer being in the range of 5-50:50-95, and said polymer being solvated in said non-aqueous solvent.
Claim 8
Independent Claim
148 words
A method of manufacturing a non-aqueous resin dispersion, which comprises dissolving a resin selected from the group consisting of natural resins and natural resin-modified thermosetting resins in at least one monomer A, wherein said monomer A has the formula ##STR3## wherein R is hydrogen or CH 3 , D is --COOC n H 2n+1 or --OC n H 2n+1 or and n is an integer ranging from 6 to 20, and which can dissolve said resin, and effecting polymerization reaction of the resulting solution in the presence of a non-aqueous solvent, whereby to form a polymer of said monomer A, said non-aqueous solvent being selected from the group consisting of aliphatic hydrocarbons and halogen derivatives thereof, said resin being substantially insoluble in said non-aqueous solvent, the weight ratio of said resin: said polymer being in the range of 5-50:50-95, and said polymer being solvated in said non-aqueous solvent.
Claim 9
Dependent Claim
80 words
A method according to claim 6, which comprises adding to said solution during the course of the polymerization reaction at least one dispersant selected from the group consisting of waxlike substances and polyolefins having a softening temperature in the range of 60° - 130° C, wherein the amount of said dispersant added is in the range of 10 - 50 parts by weight per 100 parts by weight of said polymer and quenching said solution after finishing the polymerization reaction.
Claim 10
Dependent Claim
56 words
A method according to claim 6, wherein said monomer A is polymerized with at least one monomer B selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, propylene glycol monoacrylate, propylene glycol methacrylate, hydroxyethyl methacrylate, acrylonitrile and methacrylonitrile, wherein the weight ratio of monomer A to monomer B is in the range of about 70-99:30-1.
Claim 11
Dependent Claim
70 words
A method according to claim 6, wherein said monomer A is polymerized with at least one monomer C selected from the group consisting of acrylic acid, methacrylic acid, lower alkyl esters of acrylic acid and methacrylic acid wherein said alkyl has 1 - 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, wherein the weight ratio of the monomer A:monomer C is in the range of about 50-90:50-10.
Claim 12
Dependent Claim
109 words
A method according to claim 6, wherein said monomer A is polymerized with monomer B and monomer C, wherein monomer B is at least one monomer selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, propylene glycol monoacrylate propylene glycol methacrylate, hydroxyethyl methacrylate, acrylonitrile and methacrylonitrile, wherein monomer C is at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, lower alkyl esters of acrylic acid and methacrylic acid in which said alkyl has 1 - 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, and wherein the weight ratio of monomer A:monomer B:monomer C is in the range of about 60-90:20-1:20-1.
Claim 13
Dependent Claim
21 words
A method according to claim 6, wherein the polymerization reaction is effected by heating in the presence of a polymerization initiator.
Claim 14
Dependent Claim
23 words
A method according to claim 11, wherein the temperature for the polymerization reaction is in the range of about 70° - 110° C.
Claim 15
Independent Claim
147 words
A method of manufacturing a non-aqueous resin dispersion, which comprises dissolving a resin selected from the group consisting of natural resins and natural resin-modified thermosetting resins in at least one monomer A, wherein said monomer A has the formula ##STR4## wherein R is hydrogen or CH 3 , D is --COOC n H 2n+1 or --OC n H 2n+1 or and n is an integer ranging from 6 to 20, and which can dissolve said resin, effecting polymerization reaction of the resulting solution whereby to form a polymer of said monomer A, and adding a non-aqueous solvent to the resulting polymer, said non-aqueous solvent being selected from the group consisting of aliphatic hydrocarbons and halogen derivatives thereof, said resin being substantially insoluble in said non-aqueous solvent, the weight ratio of said resin:said polymer being in the range of 5-50:50-95, said polymer being solvated in said non-aqueous solvent.
Claim 16
Independent Claim
147 words
A method of manufacturing a non-aqueous resin dispersion, which comprises dissolving a resin selected from the group consisting of natural resins and natural resin-modified thermosetting resins in at least one monomer A, wherein said monomer A has the formula ##STR4## wherein R is hydrogen or CH 3 , D is --COOC n H 2n+1 or --OC n H 2n+1 or and n is an integer ranging from 6 to 20, and which can dissolve said resin, effecting polymerization reaction of the resulting solution whereby to form a polymer of said monomer A, and adding a non-aqueous solvent to the resulting polymer, said non-aqueous solvent being selected from the group consisting of aliphatic hydrocarbons and halogen derivatives thereof, said resin being substantially insoluble in said non-aqueous solvent, the weight ratio of said resin:said polymer being in the range of 5-50:50-95, said polymer being solvated in said non-aqueous solvent.
Claim 17
Dependent Claim
80 words
A method according to claim 13, which comprises adding to said solution during the course of the polymerization reaction at least one dispersant selected from the group consisting of waxlike substances and polyolefins having a softening temperature in the range of 60° - 130° C, wherein the amount of said dispersant added is in the range of 10 - 50 parts by weight per 100 parts by weight of said polymer, and quenching said solution after finishing the polymerization reaction.
Claim 18
Dependent Claim
56 words
A method according to claim 13, wherein said monomer A is polymerized with at least one monomer B selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, propylene glycol monoacrylate, propylene glycol methacrylate, hydroxyethyl methacrylate, acrylonitrile and methacrylonitrile, wherein the weight ratio of monomer A to monomer B is in the range of about 70-99:30-1.
Claim 19
Dependent Claim
68 words
A method according to claim 13, wherein said monomer A is polymerized with at least one monomer C selected from the group consisting of acrylic acid, methacrylic acid, lower alkyl esters of acrylic acid and methacrylic acid wherein said alkyl has 1 - 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, wherein the weight ratio of monomer A:monomer C is in the range of 50-90:50-10.
Claim 20
Dependent Claim
109 words
A method according to claim 13, wherein said monomer A is polymerized with monomer B and monomer C, wherein monomer B is at least one monomer selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, propylene glycol monoacrylate, propylene glycol methacrylate, hydroxyethyl methacrylate, acrylonitrile and methacrylonitrile, wherein monomer C is at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, lower alkyl esters of acrylic acid and methacrylic acid in which said alkyl has 1 - 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, and wherein the weight ratio of monomer A:monomer B:monomer C is in the range of about 60-90:20-1:20-1.
Claim 21
Dependent Claim
21 words
A method according to claim 13, wherein the polymerization reaction is effected by heating in the presence of a polymerization initiator.
Claim 22
Dependent Claim
23 words
A method according to claim 18, wherein the temperature for the polymerization reaction is in the range of about 70° - 110° C.
Claim 23
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 6.
Claim 24
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 7.
Claim 25
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 8.
Claim 26
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 9.
Claim 27
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 10.
Claim 28
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 13.
Claim 29
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 14.
Claim 30
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 15.
Claim 31
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 16.
Claim 32
Dependent Claim
11 words
A non-aqueous resin dispersion prepared by the method of claim 17.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-05-01 | 1981-10-31 | 1982-05-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-05-01 | 1985-10-31 | 1986-05-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-05-01 | 1989-10-31 | 1990-05-02 | $7700.00 | Window Closed / Lapsed |