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US4087347A Expired / Lapsed US ⏱️ 0.0 years remaining

Shale retorting process

Assignee: Chevron USA Inc
•
Filing: 1976-09-20
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Granted: 1978-05-02
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Expires: 1996-09-20
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Abstract

Abstract Disclosed is a process for the retorting of shale and other similar hydrocarbon-containing solids in which the solids to be retorted are mixed with a solid heat transfer material to rapidly heat the hydrocarbon-containing solids to a high temperature. The shale and heat-transfer material are entrained in a high-velocity gaseous stream and conveyed upward in a vertical dilute phase lift pipe retorting vessel whereby the hydrocarbon-containing solids are rapidly heated to an elevated temperature vaporizing a minor portion of the hydrocarbons in the solid. The hydrocarbon-containing solids then pass into a disengaging zone wherein the gas and solids are separated. The partially retorted solids then pass into a gravitating bed retort and flow downward countercurrent to the flow of a stripping gas. The process is characterized by a high liquid yield and a minimum gas yield along with minimal amounts of volatile components being left in the retorted solids.

Inventors

  • 👤 Gordon E. Langlois
  • 👤 Paul W. Tamm

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:59
CPC Classifications
C; C10; C10B; C10B53/00; C10B53/06; C10B49/00; C10B49/16; C10B55/00; C10B55/02; C10B55/04; C10B55/08; C10B55/10; C10G; C10G1/00; C10G1/008; C10G1/02

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 321 words
A continuous process for retorting oil shale which comprises: (a) introducing a solid heat-transfer material at an elevated temperature in the range 1000° to 2000° F and oil shale into a lower portion of a first vertically elongated vessel at a weight ratio of said heat-transfer material to said oil shale of greater than 0.1 and less than 5; (b) passing a lift gas containing less than 1 volume percent free oxygen upwardly through said first vessel at a linear velocity of 20 to 200 feet per second and sufficient to entrain and convey said oil shale and said heat-transfer material upwardly through said vessel, whereby said oil shale and said heat-transfer material are intermixed and said oil shale is rapidly heated to an elevated temperature between 700° F and 1200° F, vaporizing a first portion comprising less than 30 weight percent of the hydrocarbons in said oil shale, said oil shale having a residence time in said first vessel of less than 5 seconds; (c) separating from said lift gas a solid fraction comprising said heat-transfer material and oil shale; (d) introducing said solid fraction into the upper portion of a second vertically elongated vessel forming a downwardly moving bed of solids wherein additional heat is transferred from said heat-transfer material to said oil shale, vaporizing a second portion of the hydrocarbons in said oil shale; (e) withdrawing retorted solids and said heat-transfer material from a lower portion of said second vessel; (f) passing a stripping gas upwardly through said second vessel which entrains said vaporous second portion of hydrocarbons; (g) separating condensable hydrocarbons from said lift gas and said stripping gas; and (h) introducing retorted solids into a lift pipe combustor and combusting residual carbon in said retorted shale, forming spent shale at an elevated temperature in the range from 1000° F to 1600° F, and introducing said spent shale into said first vessel to provide said heat-exchange material.
Claim 2
Dependent Claim 321 words
A continuous process for retorting oil shale which comprises: (a) introducing a solid heat-transfer material at an elevated temperature in the range 1000° to 2000° F and oil shale into a lower portion of a first vertically elongated vessel at a weight ratio of said heat-transfer material to said oil shale of greater than 0.1 and less than 5; (b) passing a lift gas containing less than 1 volume percent free oxygen upwardly through said first vessel at a linear velocity of 20 to 200 feet per second and sufficient to entrain and convey said oil shale and said heat-transfer material upwardly through said vessel, whereby said oil shale and said heat-transfer material are intermixed and said oil shale is rapidly heated to an elevated temperature between 700° F and 1200° F, vaporizing a first portion comprising less than 30 weight percent of the hydrocarbons in said oil shale, said oil shale having a residence time in said first vessel of less than 5 seconds; (c) separating from said lift gas a solid fraction comprising said heat-transfer material and oil shale; (d) introducing said solid fraction into the upper portion of a second vertically elongated vessel forming a downwardly moving bed of solids wherein additional heat is transferred from said heat-transfer material to said oil shale, vaporizing a second portion of the hydrocarbons in said oil shale; (e) withdrawing retorted solids and said heat-transfer material from a lower portion of said second vessel; (f) passing a stripping gas upwardly through said second vessel which entrains said vaporous second portion of hydrocarbons; (g) separating condensable hydrocarbons from said lift gas and said stripping gas; and (h) introducing retorted solids into a lift pipe combustor and combusting residual carbon in said retorted shale, forming spent shale at an elevated temperature in the range from 1000° F to 1600° F, and introducing said spent shale into said first vessel to provide said heat-exchange material.
Claim 3
Dependent Claim 25 words
The process of claim 1 wherein said lift gas and said stripping gas are essentially free of molecular oxygen and comprise recycled light product gas.

References Cited (Backward Citations)

US2582712A Cited
US2634198A Cited
US3281349A Cited
US3501394A Cited
US3655518A Cited
US3784462A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-01 1981-10-31 1982-05-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-01 1985-10-31 1986-05-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-01 1989-10-31 1990-05-02 $7700.00 Window Closed / Lapsed

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