← Back to Patent Explorer
US4086157A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrode for electrochemical processes

Assignee: De Nora Deutschland GmbH
•
Filing: 1976-04-15
•
Granted: 1978-04-25
•
Expires: 1996-04-15
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A coated valve metal electrode for electrochemical processes, which has (a) an electrode base body of valve metal; (b) a base layer on said valve metal, said base layer comprising an electrically conducting element without valve effect, and (c) a cover layer comprising titanium dioxide and/or tantalum oxide with certain doping and stable oxides.

Inventors

  • 👤 Konrad Koziol
  • 👤 Karl-Heinz Sieberer
  • 👤 Hans-Carl Rathjen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:50
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/04; C25B11/051; C25B11/073; C25B11/091; C25B11/093

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 204 words
In an electrode for electrode processes and comprising a valve metal as a base member the improvement which comprises: a. a base layer coated on said base member and comprising an electrically conductive chemical element having no substantial valve effect; and b. a gas-tight and liquid-tight cover layer on said base layer and comprising: 1. a valve metal oxide selected from the group consisting of titanium dioxide and tantalum oxide; 2. a doping material to increase the electrical conductivity of said valve metal oxide and comprising, when titanium oxide is said valve metal oxide, an oxide selected from the oxides of niobium, tungsten, molybdenum, antimony, and tin and comprising, when tantalum oxide is said valve metal oxide, an oxide selected from the oxides of tungsten, molybdenum, antimony, and tin; 3. at least one of the oxides stable in an electrolysis medium selected from the oxides of barium, gallium, germanium, lead, bismuth, selenium, tellurium, copper, cadmium, the rare earth elements, manganese, iron, cobalt, and nickel; wherein the proportion of said doping material in said valve metal oxides is less than about 28 mol percent of the mixture and the proportion of said stable oxides in said cover layer is greater than about 50 mol percent.
Claim 2
Dependent Claim 204 words
In an electrode for electrode processes and comprising a valve metal as a base member the improvement which comprises: a. a base layer coated on said base member and comprising an electrically conductive chemical element having no substantial valve effect; and b. a gas-tight and liquid-tight cover layer on said base layer and comprising: 1. a valve metal oxide selected from the group consisting of titanium dioxide and tantalum oxide; 2. a doping material to increase the electrical conductivity of said valve metal oxide and comprising, when titanium oxide is said valve metal oxide, an oxide selected from the oxides of niobium, tungsten, molybdenum, antimony, and tin and comprising, when tantalum oxide is said valve metal oxide, an oxide selected from the oxides of tungsten, molybdenum, antimony, and tin; 3. at least one of the oxides stable in an electrolysis medium selected from the oxides of barium, gallium, germanium, lead, bismuth, selenium, tellurium, copper, cadmium, the rare earth elements, manganese, iron, cobalt, and nickel; wherein the proportion of said doping material in said valve metal oxides is less than about 28 mol percent of the mixture and the proportion of said stable oxides in said cover layer is greater than about 50 mol percent.
Claim 3
Dependent Claim 29 words
The electrode as defined in claim 1 wherein said valve metal forming said base member is selected from the group consisting of titanium, tantalum, niobium, zirconium, and alloys thereof.
Claim 4
Dependent Claim 28 words
The electrode as defined in claim 1 wherein said electrically conductive chemical element is selected from the group consisting of cadmium, silver, gold, platinum, ruthenium, palladium, and carbon.
Claim 5
Dependent Claim 15 words
The electrode as defined in claim 1 wherein said valve metal oxide is titanium dioxide.
Claim 6
Dependent Claim 14 words
The electrode as defined in claim 1 wherein said valve metal is tantalum oxide.
Claim 7
Dependent Claim 15 words
The electrode as defined in claim 3 wherein said electrically conductive chemical element is carbon.
Claim 8
Dependent Claim 57 words
The electrode as defined in claim 1 wherein said valve metal forming said base member is selected from the group consisting of titanium, tantalum, niobium, zirconium, and alloys thereof; said valve metal oxide is titanium dioxide; and said electrically conductive chemical element is selected from the group consisting of cadmium, silver, gold, platinum, ruthenium, palladium, and carbon.
Claim 9
Dependent Claim 28 words
The electrode as defined in claim 1 wherein said valve metal is titanium, said valve metal oxide is titanium dioxide, and said electrically conducting chemical element is carbon.
Claim 10
Dependent Claim 28 words
The electrode as defined in claim 1 wherein said valve metal is titanium, said valve metal oxide is tantalum oxide, and said electrically conducting chemical element is carbon.
Claim 11
Dependent Claim 46 words
The electrode as defined in claim 1 comprising interruptions in said base layer in a manner to divide said base layer into a number of fields to in part expose said base member to and to in part separate said base member from said cover layer.
Claim 12
Dependent Claim 46 words
The electrode as defined in claim 4 comprising interruptions in said base layer in a manner to divide said base layer into a number of fields to in part expose said base member to and to in part separate said base member from said cover layer.
Claim 13
Dependent Claim 46 words
The electrode as defined in claim 7 comprising interruptions in said base layer in a manner to divide said base layer into a number of fields to in part expose said base member to and to in part separate said base member from said cover layer.
Claim 14
Dependent Claim 14 words
The electrode as defined in claim 1 wherein said stable oxides comprise a spinel.
Claim 15
Dependent Claim 14 words
The electrode as defined in claim 4 wherein said stable oxides comprise a spinel.
Claim 16
Dependent Claim 14 words
The electrode as defined in claim 7 wherein said stable oxides comprise a spinel.

References Cited (Backward Citations)

US1302959A Cited
US2305539A Cited
US2882213A Cited
US3632497A Cited
US3706644A Cited
US3677917A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-04-24 1981-10-24 1982-04-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-04-24 1985-10-24 1986-04-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-04-24 1989-10-24 1990-04-25 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag