US4086156A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Pitch bonded carbon electrode
Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1977-04-18
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Granted: 1978-04-25
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Expires: 1997-04-18
Abstract
Abstract This invention relates to the production of chemical pitch by stripping under reduced pressure steam cracker tar to obtain a pitch having an initial boiling point of between 350 DEG C and 400 DEG C at atmospheric pressure, heat soaking the pitch at 360 DEG to 420 DEG C in the absence of air or oxygen at sub-atmospheric to 4 atmospheres absolute and stripping under reduced pressure the soaked pitch to obtain a product having a minimum softening point (R and B) of 75 DEG C. This pitch can be mixed with coke to make electrodes especially suitable for aluminium production.
Inventors
- 👤 Ghazi Mourad Dickakian
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 14:01
CPC Classifications
C; C25; C25C; C25C3/00; C25C3/06; C25C3/08; C25C3/12; C25C3/125; C10; C10C; C10C3/00; C10C3/002
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
87 words
A process for preparing chemical pitch which comprises stripping under reduced pressure steam cracker tar to obtain a pitch having an initial boiling point of between 350° C and 400° C at atmospheric pressure, heat soaking the pitch at 360° C to 420° C in the absence of air or oxygen at a pressure in the range of from sub-atmospheric to 4 atmospheres absolute and stripping under reduced pressure the soaked pitch to obtain a product having a minimum softening point (R and B) of 75° C.
Claim 2
Dependent Claim
87 words
A process for preparing chemical pitch which comprises stripping under reduced pressure steam cracker tar to obtain a pitch having an initial boiling point of between 350° C and 400° C at atmospheric pressure, heat soaking the pitch at 360° C to 420° C in the absence of air or oxygen at a pressure in the range of from sub-atmospheric to 4 atmospheres absolute and stripping under reduced pressure the soaked pitch to obtain a product having a minimum softening point (R and B) of 75° C.
Claim 3
Dependent Claim
81 words
A process according to claim 1 wherein the steam cracker tar has the following characteristics: ______________________________________
Sp. gr. at 20° C 1.10 - 1.15
Toluene insolubles (wt.%)
0.020-0.200
Ash content (wt.%) 0.010-0.004
Viscosity (cps) at 210° F
20 - 200
n-heptane insoluble 10 - 25
Coking value of n-heptane insoluble wt.%
50 - 65
Aromatic carbon atom % 71 - 72
Aliphatic/aromatic proton ratio
1.3 - 1.6
Number average molecular weight
250 - 310
Sulphur content (wt.%) 1.0 - 5.0
______________________________________
Claim 4
Dependent Claim
16 words
A process according to claim 1 wherein the steam cracker tar is stripped by vacuum stripping.
Claim 5
Dependent Claim
30 words
A process according to claim 1 wherein the steam cracker is stripped at a temperature between 200° C and 400° C at a pressure of 10 to 100 mm Hg.
Claim 6
Dependent Claim
29 words
A process according to claim 1 wherein the pitch obtained after stripping the steam cracker tar has a softening point of between 60° and 95° C (R and B).
Claim 7
Dependent Claim
26 words
A process according to claim 5 wherein the pitch is heat soaked at a temperature of 380° C to 390° C and at about atmospheric pressure.
Claim 8
Dependent Claim
27 words
A process according to claim 1 wherein the pitch obtained from the heat soaking step has a softening point of 60° to 90° C (R and B).
Claim 9
Dependent Claim
26 words
A process according to claim 7 wherein the final product obtained after stripping has a softening point (R and B) of 100° C to 130° C.
Claim 10
Dependent Claim
30 words
A process according to claim 7 wherein the final product obtained after stripping has an aromatic carbon content of 73% to 80% and a coking value of 50% to 58%.
Claim 11
Dependent Claim
31 words
A process according to claim 7 wherein the final product obtained after stripping has a C:H atomic ratio of 1.35 to 1.50 and a benzene insolubles (wt.%) of 15 to 32.
Claim 12
Dependent Claim
11 words
Chemical pitch whenever prepared by a process claimed in claim 1.
Claim 13
Dependent Claim
23 words
An electrode comprising coke and 14 to 17 wt.% based on the weight of coke of chemical pitch as claimed in claim 11.
Claim 14
Dependent Claim
23 words
An electrode comprising coke and 26 to 32 wt.% based on the weight of coke of chemical pitch as claimed in claim 11.
References Cited (Backward Citations)
US2848424A
Cited
US3324029A
Cited
US3238116A
Cited
US3725240A
Cited
US3970542A
Cited
US4017378A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-04-24 | 1981-10-24 | 1982-04-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-04-24 | 1985-10-24 | 1986-04-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-04-24 | 1989-10-24 | 1990-04-25 | $7700.00 | Window Closed / Lapsed |