US4082551A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electrophotographic element containing a multilayer interlayer
Assignee: Eastman Kodak Co
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Filing: 1977-05-26
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Granted: 1978-04-04
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Expires: 1997-05-26
Abstract
Abstract A unitary photoconductive element having an electrically conducting layer, a photoconductive layer thereover, and a multilayer interlayer composition interposed between the conducting layer and the photoconductive layer. The multilayer interlayer composition comprises a layer containing an acidic polymer material, a layer containing a basic polymer material, and an acid-base reaction product zone formed at the interface of the acidic polymer-containing layer and the basic polymer-containing layer. The multilayer interlayer composition provides good adhesion between the conducting and photoconductive layers of the resultant unitary element and can function as an electrical barrier blocking positive charge carriers which might otherwise be injected into the photoconductive layer from the underlying conducting layer.
Inventors
- 👤 David J. Steklenski
- 👤 Evelio A. Perez Albuerne
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 15:03
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/14; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31536
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
78 words
In a unitary photoconductive element comprising an electrically conducting layer, a photoconductive layer overlying said conducting layer, and a multilayer interlayer composition interposed between said conducting layer and said photoconductive layer, the improvement wherein said multilayer interlayer composition comprises a first layer containing an acidic polymer material, a second layer containing a basic polymer material, and at the interface of said first and second layers an acid-base reaction product zone formed by said acidic and basic polymer materials.
Claim 2
Dependent Claim
78 words
In a unitary photoconductive element comprising an electrically conducting layer, a photoconductive layer overlying said conducting layer, and a multilayer interlayer composition interposed between said conducting layer and said photoconductive layer, the improvement wherein said multilayer interlayer composition comprises a first layer containing an acidic polymer material, a second layer containing a basic polymer material, and at the interface of said first and second layers an acid-base reaction product zone formed by said acidic and basic polymer materials.
Claim 3
Dependent Claim
54 words
A unitary photoconductive element as defined in claim 1 wherein said electrically conducting layer is a hole injecting electrode, wherein said photoconductive layer comprises a p-type photoconductive material, and wherein said multilayer interlayer composition provides an electrical barrier which blocks the injection of positive charge carriers from said conducting layer into said photoconductive layer.
Claim 4
Dependent Claim
55 words
A unitary photoconductive element as defined in claim 1 wherein said acidic polymer material contains at least one repeating unit containing an acidic group selected from the class consisting of carboxyl, sulfonic, and phosphonic groups and wherein said basic polymer material contains at least one repeating unit containing as the basic group an amine group.
Claim 5
Dependent Claim
40 words
A unitary photoconductive element as defined in claim 1 wherein said acidic polymer material contains at least one repeating unit containing a carboxyl group and wherein said basic polymer material contains at least one repeating unit containing an amine group.
Claim 6
Dependent Claim
118 words
In a unitary photoconductive element comprising as an electrically conducting layer a layer containing a positive hole injecting material, a p-type organic photoconductive layer overlying said conducting layer, and a multilayer interlayer composition interposed between said conducting layer and said photoconductive layer to provide an electrical barrier which blocks the injection of positive charge carriers from said conducting layer into said photoconductive layer, the improvement wherein said multilayer interlayer composition comprises a first layer containing an acidic polymer material adjacent said conducting layer, a second layer containing a basic polymer material adjacent said photoconductive layer, and at the interface of said first and second layers an acid-base reaction product zone formed by said acidic and basic polymer materials.
Claim 7
Dependent Claim
118 words
In a unitary photoconductive element comprising as an electrically conducting layer a layer containing a positive hole injecting material, a p-type organic photoconductive layer overlying said conducting layer, and a multilayer interlayer composition interposed between said conducting layer and said photoconductive layer to provide an electrical barrier which blocks the injection of positive charge carriers from said conducting layer into said photoconductive layer, the improvement wherein said multilayer interlayer composition comprises a first layer containing an acidic polymer material adjacent said conducting layer, a second layer containing a basic polymer material adjacent said photoconductive layer, and at the interface of said first and second layers an acid-base reaction product zone formed by said acidic and basic polymer materials.
Claim 8
Dependent Claim
28 words
A unitary photoconductive element as defined in claim 5 wherein said photoconductive layer comprises a solid solution of a p-type organic photoconductive and an electrically insulating polymer binder.
Claim 9
Dependent Claim
18 words
A unitary photoconductive element as defined in claim 5 wherein said photoconductive layer comprises an aggregate photoconductive composition.
Claim 10
Dependent Claim
32 words
A unitary photoconductive element as defined in claim 5 wherein said photoconductive layer comprises a multi-active photoconductive composition having an aggregate charge generation layer in electrical contact with a charge transport layer.
Claim 11
Dependent Claim
55 words
A unitary photoconductive element as defined in claim 5 wherein said acidic polymer material contains at least one repeating unit containing an acidic group selected from the class consisting of carboxyl, sulfonic, and phosphonic groups and wherein said basic polymer material contains at least one repeating unit containing as the basic group an amine group.
Claim 12
Dependent Claim
40 words
A unitary photoconductive element as defined in claim 5 wherein said acidic polymer material contains at least one repeating unit containing a carboxyl group and wherein said basic polymer material contains at least one repeating unit containing an amine group.
Claim 13
Dependent Claim
148 words
In a unitary photoconductive element comprising as an electrically conducting layer a layer containing a positive hole injecting material, a p-type organic photoconductive layer overlying said conducting layer, and a multilayer interlayer composition interposed between said conducting layer and said photoconductive layer to provide an electrical barrier which blocks the injection of positive charge carriers from said conducting layer into said photoconductive layer, the improvement wherein said multilayer interlayer composition comprises a first layer containing an organic solvent soluble, acidic polymer material adjacent said conducting layer, a second layer containing an organic solvent soluble basic polymer adjacent said photoconductive layer, and at the interface of said first and second layers an acid-base reaction product zone formed by said acidic and basic polymer materials, said acidic polymer material having at least one repeating; carboxyl group-containing unit and said basic polymer material having at least one repeating, amine group-containing unit.
Claim 14
Dependent Claim
148 words
In a unitary photoconductive element comprising as an electrically conducting layer a layer containing a positive hole injecting material, a p-type organic photoconductive layer overlying said conducting layer, and a multilayer interlayer composition interposed between said conducting layer and said photoconductive layer to provide an electrical barrier which blocks the injection of positive charge carriers from said conducting layer into said photoconductive layer, the improvement wherein said multilayer interlayer composition comprises a first layer containing an organic solvent soluble, acidic polymer material adjacent said conducting layer, a second layer containing an organic solvent soluble basic polymer adjacent said photoconductive layer, and at the interface of said first and second layers an acid-base reaction product zone formed by said acidic and basic polymer materials, said acidic polymer material having at least one repeating; carboxyl group-containing unit and said basic polymer material having at least one repeating, amine group-containing unit.
Claim 15
Dependent Claim
62 words
A unitary photoconductive element as defined in claim 11 wherein said first layer of said multilayer interlayer composition comprises a copolymer of at least one carboxyl group-containing monomer and at least one compatible, non-interfering monomer and wherein said second layer of said multilayer interlayer composition comprises a copolymer of at least one amine group-containing monomer and at least one compatible, non-interfering monomer.
Claim 16
Dependent Claim
57 words
A unitary photoconductive element as defined in claim 11 wherein said acidic polymer is selected from the group consisting of poly(methyl methacrylate-co-methacrylic acid); poly(methacrylic acid), poly(ethylene-co-maleic acid), poly(vinyl hydrogen phthalate); poly(styrenesulfonic acid); and poly(acrylic acid); and wherein said basic polymer is selected from the group consisting of poly{N-[3-(N,N-dimethylaminopropyl)]acrylamide}, poly(4-vinylpyridine), poly[2-(N,N-dimethylamino)ethyl methacrylate-co-methyl methacrylate]; poly[styrene-co-N-(γ-dimethylaminopropyl)maleimide]; poly(styrene-co-vinylbenzyldimethylamine); and poly(2-vinylpyridine-co-methyl methacrylate).
Claim 17
Dependent Claim
24 words
A unitary photoconductive element as defined in claim 11 wherein said acidic polymer is poly(methyl methacrylate-co-methacrylic acid) and wherein said basic polymer is poly(2-vinylpyridine-co-methylmethacrylate).
Claim 18
Dependent Claim
17 words
A unitary photoconductive element as defined in claim 11 wherein said electrically conducting layer contains copper iodide.
Claim 19
Dependent Claim
18 words
A unitary photoconductive element as defined in claim 11 wherein said photoconductive layer contains an aggregate photoconductive composition.
Claim 20
Dependent Claim
30 words
A unitary photoconductive element as defined in claim 11 wherein the dry thickness of said multilayer interlayer compositions is within the range of from about 0.04 to about 2.0 microns.
Claim 21
Dependent Claim
44 words
In an electrophotographic imaging process wherein a photoconductive layer of a unitary photoconductive element is uniformly charged and exposed to produce a charge pattern on said element, the improvement which comprises using as said unitary photoconductive element an element as defined in claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-04-03 | 1981-10-03 | 1982-04-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-04-03 | 1985-10-03 | 1986-04-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-04-03 | 1989-10-03 | 1990-04-04 | $7700.00 | Window Closed / Lapsed |