US4082550A
Expired / Lapsed
US
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Hexachlorocyclopentene chemical sensitizers for heterogeneous organic photoconductive compositions
Assignee: Eastman Kodak Co
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Filing: 1977-05-25
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Granted: 1978-04-04
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Expires: 1997-05-25
Abstract
Abstract Photoconductive insulating compositions in the form of organic photoconductive dispersions are described. Particles of organic photoconductor such as p-terphenyl are dispersed in cellulose nitrate and chemically sensitized with monomeric hexachlorocyclopentenes to provide useful heterogeneous photoconductive insulating dispersions. Such dispersions can be applied to an electrically conducting support to prepare electrophotographic elements.
Inventors
- 👤 William E. Yoerger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 01:52
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0601; G03G5/0605; G03G5/0607; G03G5/0609; G03G5/0618; G03G5/062; G03G5/0622; G03G5/0624; G03G5/0627; G03G5/0629; G03G5/0631
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
24 words
A heterogeneous photoconductive insulating composition comprising particles of an organic photoconductor chemically sensitized with a monomeric hexachlorocyclopentene and dispersed in a cellulose nitrate binder.
Claim 2
Dependent Claim
24 words
A heterogeneous photoconductive insulating composition comprising particles of an organic photoconductor chemically sensitized with a monomeric hexachlorocyclopentene and dispersed in a cellulose nitrate binder.
Claim 3
Dependent Claim
126 words
The composition of claim 1 wherein said photoconductor is a compound selected from the group consisting of (a) fused carbocyclic ring compounds, (b) polyphenyl compounds having the structure ##STR13## wherein n is an integer from 1 to about 6; and (c) nitrogen-free, polyarylated compounds having the structure ##STR14## wherein n is 0, 1, or 2 Ar is aryl; and R 1 , r 2 , r 3 , and R 4 individually represent hydrogen, Ar, alkyl having 1 to about 10 carbon atoms, or alkoxy having 1 to about 10 carbon atoms, with the proviso that when n is 0, both R 1 and R 4 are Ar, and when both R 1 and R 4 are hydrogen, both R 2 and R 3 are Ar.
Claim 4
Dependent Claim
79 words
The composition of claim 2 wherein said monomeric hexachlorocyclopentene has the structure: ##STR15## wherein B is ##STR16## ##STR17## ##STR18## wherein R is hydrogen or alkyl having one to four carbon atoms; R 1 is lower alkyl having one to four carbon atoms, hydrogen, NO 2 , halogen or carboxyl; R 2 is --SO 3 H or a metal salt of --SO 3 H, NO 2 , halogen, or carboxyl; and R 1 and R 2 taken together are ##STR19##
Claim 5
Dependent Claim
42 words
The composition of claim 3 wherein B is: ##STR20## and R 1 is methyl or hydrogen, or carboxyl; R 2 is --SO 3 H or a metal salt of --SO 3 H; and R 1 and R 2 taken together are ##STR21##
Claim 6
Dependent Claim
14 words
The composition of claim 2 wherein said hexachlorocyclopentene is chlorendic anhydride or chlorendic acid.
Claim 7
Dependent Claim
27 words
A heterogeneous photoconductive insulating composition comprising particles of anthracene, p-terphenyl, p-quaterphenyl, or a tetraphenylbutadiene chemically sensitized with chlorendic anhydride or chlorendic acid, and dispersed in cellulose nitrate.
Claim 8
Dependent Claim
27 words
A heterogeneous photoconductive insulating composition comprising particles of anthracene, p-terphenyl, p-quaterphenyl, or a tetraphenylbutadiene chemically sensitized with chlorendic anhydride or chlorendic acid, and dispersed in cellulose nitrate.
Claim 9
Dependent Claim
21 words
The composition of claim 6 wherein the nitrogen content of said cellulose nitrate is from about 11.5 to about 13 percent.
Claim 10
Dependent Claim
83 words
A heterogeneous photoconductive insulating composition comprising particles of anthracene, p-terphenyl, p-quaterphenyl or a tetraphenylbutadiene dispersed in a cellulose nitrate binder and chemically sensitized with a compound having the structure ##STR22## wherein B is ##STR23## and R 1 is lower alkyl having one to four carbon atoms, hydrogen, NO 2 , carboxyl or halogen; R 2 is --SO 3 H or a metal salt of --SO 3 H, NO 2 , halogen, or carboxyl; and R 1 and R 2 taken together are ##STR24##
Claim 11
Dependent Claim
83 words
A heterogeneous photoconductive insulating composition comprising particles of anthracene, p-terphenyl, p-quaterphenyl or a tetraphenylbutadiene dispersed in a cellulose nitrate binder and chemically sensitized with a compound having the structure ##STR22## wherein B is ##STR23## and R 1 is lower alkyl having one to four carbon atoms, hydrogen, NO 2 , carboxyl or halogen; R 2 is --SO 3 H or a metal salt of --SO 3 H, NO 2 , halogen, or carboxyl; and R 1 and R 2 taken together are ##STR24##
Claim 12
Dependent Claim
21 words
The composition of claim 8 wherein the nitrogen content of said cellulose nitrate is from about 11.5 to about 13 percent.
Claim 13
Dependent Claim
20 words
The composition of claim 9 additionally comprising a matte agent and at least one cyanine or benzopyrylium spectral sensitizing dye.
Claim 14
Dependent Claim
36 words
An electrophotographic element comprising an electrically conducting support bearing a layer thereon of a photoconductive insulating composition comprising particles of an organic photoconductor chemically sensitized with a monomeric hexachlorocyclopentene and dispersed in a cellulose nitrate binder.
Claim 15
Dependent Claim
36 words
An electrophotographic element comprising an electrically conducting support bearing a layer thereon of a photoconductive insulating composition comprising particles of an organic photoconductor chemically sensitized with a monomeric hexachlorocyclopentene and dispersed in a cellulose nitrate binder.
Claim 16
Dependent Claim
66 words
An electrophotographic element as described in claim 11 wherein said organic photoconductor is p-terphenyl and said hexachlorocyclopentene is chlorendic anhydride, chlorendic acid, or a compound having the structure: ##STR25## wherein B is ##STR26## and R 1 is methyl or hydrogen, or carboxyl; R 2 is --SO 3 H or a metal salt of --SO 3 H; and R 1 and R 2 taken together are ##STR27##
Claim 17
Dependent Claim
40 words
An electrophotographic element as described in claim 12 wherein said support is an electrically conducting paper support, the nitrogen content of said cellulose nitrate is from about 11.5 to about 13 percent, and said composition additionally comprises a matte agent.
Claim 18
Dependent Claim
50 words
An electrophotographic process comprising applying a uniform charge to the surface of an electrophotographic element, imagewise exposing said charged surface to actinic radiation to form an electrostatic latent image, and developing said latent image to form a visible image, said electrophotographic element being an element as defined in claim 11.
Claim 19
Dependent Claim
50 words
An electrophotographic process comprising applying a uniform charge to the surface of an electrophotographic element, imagewise exposing said charged surface to actinic radiation to form an electrostatic latent image, and developing said latent image to form a visible image, said electrophotographic element being an element as defined in claim 13.
Claim 20
Dependent Claim
22 words
An electrophotographic copy comprising an element as defined in claim 13 and a visible image pattern on said photoconductive insulating composition layer.
References Cited (Backward Citations)
US3349064A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-04-03 | 1981-10-03 | 1982-04-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-04-03 | 1985-10-03 | 1986-04-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-04-03 | 1989-10-03 | 1990-04-04 | $7700.00 | Window Closed / Lapsed |