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Process for the catalytic oxidation of hydrocarbons with the oxides of nitrogen

Assignee: University of Southern California
•
Filing: 1976-08-05
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Granted: 1978-03-21
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Expires: 1996-08-05
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Abstract

Abstract A process for the oxidation of hydrocarbons with the oxides of nitrogen which comprises combining a hydrocarbon with a predetermined amount of the oxides of nitrogen to produce carbon dioxide, nitrogen gas and water and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a predetermined elevated temperature above about 200 DEG C.:

Inventors

  • 👤 James M. Whelan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 01:41
CPC Classifications
F; F23; F23C; F23C13/00; B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8603; B01D53/92; B01D53/94; B01D53/9445; B01D53/945; B01J; B01J23/00; B01J23/10; B01J23/70; B01J23/76; B01J23/78; C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/0473; C01B17/0486; C01B17/48; C01B17/50; C01B17/508; C01B17/69; C01B17/74; C01B17/76; C01B17/78; C01B21/00; C01B21/02; C01B21/20; C01B21/24; C01B21/26; C01B21/265; C01B32/00; C01B32/50; C01C; C01C3/00; C01C3/02; C04; C04B; C04B35/00; C04B35/50; F23C13/08; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 188 words
A process for the oxidation of hydrocarbons with the oxides of nitrogen which comprises: combining a hydrocarbon with a predetermined amount of the oxides of nitrogen to produce carbon dioxide, nitrogen gas and water; and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a predetermined elevated temperature above about 200° C.: w.sub.k X.sub.n J.sub.(1-k-n) ZO.sub.(3±m') wherein: W is zirconium, tin or thorium or mixture thereof; X is an alkaline earth metal or mixture thereof; J is scandium, yttrium, a rare-earth element or mixture thereof; Z is a metal of the first transition series or a mixture thereof, at least 0.01% of said metal having an oxidation state other than +3; k is a number having a value of between 0 and about 1.0; m' is a number having a value of from 0 to about 0.26, provided m' has a value other than 0 when n has a value of 0; and N is a number having a value from 0 to about 0.51, provided when n has a value of 0, k has a value of between 0 and about 0.05.
Claim 2
Dependent Claim 188 words
A process for the oxidation of hydrocarbons with the oxides of nitrogen which comprises: combining a hydrocarbon with a predetermined amount of the oxides of nitrogen to produce carbon dioxide, nitrogen gas and water; and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a predetermined elevated temperature above about 200° C.: w.sub.k X.sub.n J.sub.(1-k-n) ZO.sub.(3±m') wherein: W is zirconium, tin or thorium or mixture thereof; X is an alkaline earth metal or mixture thereof; J is scandium, yttrium, a rare-earth element or mixture thereof; Z is a metal of the first transition series or a mixture thereof, at least 0.01% of said metal having an oxidation state other than +3; k is a number having a value of between 0 and about 1.0; m' is a number having a value of from 0 to about 0.26, provided m' has a value other than 0 when n has a value of 0; and N is a number having a value from 0 to about 0.51, provided when n has a value of 0, k has a value of between 0 and about 0.05.

References Cited (Backward Citations)

US3316057A Cited
US3926854A Cited
US3885020A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-20 1981-09-19 1982-03-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-20 1985-09-19 1986-03-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-20 1989-09-19 1990-03-21 $7700.00 Window Closed / Lapsed

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