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US4080353A Expired / Lapsed US ⏱️ 0.0 years remaining

Titanate phosphite adducts and their use

Assignee: Kenrich Petrochemicals Inc
•
Filing: 1976-01-30
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Granted: 1978-03-21
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Expires: 1996-01-30
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Abstract

Abstract This invention relates to adducts of tetra-substituted titanates and di-substituted hydrogen phosphites; the use of such adducts for treating particular fillers, including pigments; the compositions of fillers and the aforesaid adducts with epoxy resins and other casting resins; the reaction product of said adducts with aromatic polyamines; the use of said reaction products for curing epoxide and urethane resins; and compositions of certain of the adducts and casting resins. The titanate-phosphite adducts serve to reduce the viscosity of filled epoxy resins, thereby permitting higher filler loading, to enhance the tinctorial power of pigments, and to render casting resins water-extendible. The titanate-phosphite adducts are the reaction products of one mole of a compound having the formula (RO) 4 Ti and two moles of di-substituted hydrogen phosphite, (R'O) 2 P(O)H, where R and R' are monovalent alkyl, alkenyl, aryl, aralkyl or alkaryl. Both R and R' may be alkoxy, aroxy, bromo or chloro-substituted derivatives of the aforesaid groups. R may have from 1 to 18 carbon atoms, preferably 3 to 12, except where the titanates are used for water-extension, where R is preferably 6 to 12. R' may be from 3 to 18, preferably from 6 to 14.

Inventors

  • 👤 Salvatore J. Monte
  • 👤 Gerald Sugerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:55
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/08; C07F9/141; C08; C08F; C08F299/00; C08F299/02; C08F299/04; C08F299/0442; C08F299/0464; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/16; C08G18/22; C08G18/222; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4092; C08G63/00; C08G63/91; C08G63/914; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/52; C08K5/524

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 104 words
A filled resin composition useful for coating and casting which comprises a resin containing a filler and an organic titanate compound which is an adduct of one mole of a tetra-substituted titanate having the formula (RO) 4 Ti and two moles of a di-substituted hydrogen phosphite having the formula (R'O) 2 P(O)H wherein R and R' are monovalent alkyl, alkenyl, aryl, aralkyl, alkaryl, alkoxy or aryloxy groups and wherein R has from 1 to 18 carbon atoms and R' from 3 to 18 carbon atoms; said organic titanate compound being present in an amount sufficient to reduce the viscosity of said filled resin composition.
Claim 2
Dependent Claim 104 words
A filled resin composition useful for coating and casting which comprises a resin containing a filler and an organic titanate compound which is an adduct of one mole of a tetra-substituted titanate having the formula (RO) 4 Ti and two moles of a di-substituted hydrogen phosphite having the formula (R'O) 2 P(O)H wherein R and R' are monovalent alkyl, alkenyl, aryl, aralkyl, alkaryl, alkoxy or aryloxy groups and wherein R has from 1 to 18 carbon atoms and R' from 3 to 18 carbon atoms; said organic titanate compound being present in an amount sufficient to reduce the viscosity of said filled resin composition.
Claim 3
Dependent Claim 32 words
The resin composition of claim 1 wherein R is an alkyl group containing from 3 to 12 carbon atoms and R' is an alkyl group containing from 6 to 14 carbon atoms.
Claim 4
Dependent Claim 32 words
The resin composition of claim 1 wherein R is an alkoxy group containing from 3 to 12 carbon atoms and R' is an alkyl group containing from 3 to 18 carbon atoms.
Claim 5
Dependent Claim 24 words
The resin composition of claim 1 wherein the resin is an epoxy resin and the filler is slicon dioxide, aluminum hydrate, or a pigment.
Claim 6
Dependent Claim 19 words
The resin composition of claim 1 wherein the resin is a polyester resin and the filler is aluminum hydrate.
Claim 7
Dependent Claim 19 words
The resin composition of claim 1 wherein the resin is an alkyd resin and the filler is a pigment.
Claim 8
Dependent Claim 27 words
The filled resin composition of claim 1 wherein the composition contains from 0.1 to 5 weight percent of the adduct based on the weight of the filler.
Claim 9
Dependent Claim 26 words
The filled composition of claim 1 wherein the composition contains from 50 to 1200 parts by weight of filler for each 100 parts of the resin.
Claim 10
Dependent Claim 22 words
The composition of claim 1 wherein the resin is an epoxy resin, a polyester resin, a furan resin or a phenolic resin.

References Cited (Backward Citations)

US3385835A Cited
US3457195A Cited
US3488368A Cited
US3578615A Cited
US3655816A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-20 1981-09-19 1982-03-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-20 1985-09-19 1986-03-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-20 1989-09-19 1990-03-21 $7700.00 Window Closed / Lapsed

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