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US4080211A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymerization of monomeric color couplets

Assignee: Agfa Gevaert NV
•
Filing: 1975-07-23
•
Granted: 1978-03-21
•
Expires: 1995-07-23
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Abstract

Abstract A process of making a color photographic material comprising a support and a layer comprising gelatin and as a color-coupling agent a water-insoluble homopolymer of a solid water-insoluble ethylenically unsaturated color coupling monomer or a water-insoluble copolymer of said monomer with a water-insoluble ethylenically unsaturated monomer, wherein the color-coupling agent is made by:

Inventors

  • 👤 August Jean Van Paesschen
  • 👤 Jan Jozef Priem

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 21:31
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/12; C08F2/16; C08F2/22; C08F2/24; G; G03; G03C; G03C1/00; G03C1/76; G03C1/7614; G03C1/815; G03C1/8155; G03C1/825; G03C1/835; G03C7/00; G03C7/30; G03C7/32; G03C7/327; G03C7/3275; Y; Y10; Y10S; Y10S430/00; Y10S430/136

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 193 words
A process of making a color photographic material comprising a support and a layer comprising gelatin and as a color-coupling agent a water-insoluble homopolymer of a solid water-insoluble ethylenically unsaturated color coupling monomer or a water-insoluble copolymer of said monomer with a water-insoluble ethylenically unsaturated monomer, which process comprises the steps of: (1) forming an aqueous dispersion of up to 65% by weight of said polymeric color coupling agent by polymerizing an emulsion in water of a solution of a solid water-insoluble ethylenically unsaturated color coupling monomer capable of undergoing free radical addition polymerization at a temperature below the melting point of said monomer or a mixture thereof with a water-insoluble ethylenically unsaturated monomer, said solution being in a solvent for said monomer selected from the group consisting of organic solvents substantially inert with respect to said color coupling monomer and the free radical polymerization products thereof, liquid water-insoluble copolymerizable monomers and mixtures of such organic solvents and such liquid copolymerizable monomers; (2) mixing an aqueous gelatin solution with the said aqueous dispersion of said polymeric color coupling agent; and (3) applying to said support a layer comprising said mixture of step (2).
Claim 2
Dependent Claim 193 words
A process of making a color photographic material comprising a support and a layer comprising gelatin and as a color-coupling agent a water-insoluble homopolymer of a solid water-insoluble ethylenically unsaturated color coupling monomer or a water-insoluble copolymer of said monomer with a water-insoluble ethylenically unsaturated monomer, which process comprises the steps of: (1) forming an aqueous dispersion of up to 65% by weight of said polymeric color coupling agent by polymerizing an emulsion in water of a solution of a solid water-insoluble ethylenically unsaturated color coupling monomer capable of undergoing free radical addition polymerization at a temperature below the melting point of said monomer or a mixture thereof with a water-insoluble ethylenically unsaturated monomer, said solution being in a solvent for said monomer selected from the group consisting of organic solvents substantially inert with respect to said color coupling monomer and the free radical polymerization products thereof, liquid water-insoluble copolymerizable monomers and mixtures of such organic solvents and such liquid copolymerizable monomers; (2) mixing an aqueous gelatin solution with the said aqueous dispersion of said polymeric color coupling agent; and (3) applying to said support a layer comprising said mixture of step (2).
Claim 3
Dependent Claim 70 words
A process according to claim 1 wherein the aqueous dispersion of up to 65% by weight of the polymeric color coupling agent is formed by the steps of: (1) dispersing the solid-water-insoluble color coupling monomer and a solvent therefor in water containing at least one emulsifying agent; (2) adding to the aqueous dispersion a polymerization initiator; and (3) agitating the dispersion under free radical polymerization conditions until polymerization has occurred.
Claim 4
Dependent Claim 29 words
A process according to claim 1 wherein the aqueous dispersion of said polymeric color coupling agent formed by emulsion polymerization has a solid concentration of about 2-50% by weight.
Claim 5
Dependent Claim 39 words
A process according ot claim 2 wherein said solid water-insoluble color coupling monomer and the solvent therefor are dispersed in water by first forming a solution of the monomer in the solvent and dispersing the solution formed in water.
Claim 6
Dependent Claim 24 words
A process according to claim 2 wherein said solid water-insoluble color coupling monomer and the solvent therefor are dispersed in water simultaneously or separately.
Claim 7
Dependent Claim 11 words
A color photographic material prepared by the process of claim 1.
Claim 8
Dependent Claim 76 words
A process according to claim 1 wherein said solid water-insoluble color coupling monomer corresponds to one of the general formulae: ##STR27## wherein R is hydrogen or methyl, R' and R" (same or different) represent hydrogen, halogen, --SO 2 CH 3 , --SO 2 NH 2 , --O--alkyl, X represents halogen, --SO 2 CH 3 , --SO 2 NH 2 , --CN, --alkyl, --O--alkyl, Y represents --O--, or --CONH--, and n is 0, 1, 2 or 3.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-20 1981-09-19 1982-03-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-20 1985-09-19 1986-03-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-20 1989-09-19 1990-03-21 $7700.00 Window Closed / Lapsed

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