US4080211A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymerization of monomeric color couplets
Assignee: Agfa Gevaert NV
•
Filing: 1975-07-23
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Granted: 1978-03-21
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Expires: 1995-07-23
Abstract
Abstract A process of making a color photographic material comprising a support and a layer comprising gelatin and as a color-coupling agent a water-insoluble homopolymer of a solid water-insoluble ethylenically unsaturated color coupling monomer or a water-insoluble copolymer of said monomer with a water-insoluble ethylenically unsaturated monomer, wherein the color-coupling agent is made by:
Inventors
- 👤 August Jean Van Paesschen
- 👤 Jan Jozef Priem
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 21:31
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/12; C08F2/16; C08F2/22; C08F2/24; G; G03; G03C; G03C1/00; G03C1/76; G03C1/7614; G03C1/815; G03C1/8155; G03C1/825; G03C1/835; G03C7/00; G03C7/30; G03C7/32; G03C7/327; G03C7/3275; Y; Y10; Y10S; Y10S430/00; Y10S430/136
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
193 words
A process of making a color photographic material comprising a support and a layer comprising gelatin and as a color-coupling agent a water-insoluble homopolymer of a solid water-insoluble ethylenically unsaturated color coupling monomer or a water-insoluble copolymer of said monomer with a water-insoluble ethylenically unsaturated monomer, which process comprises the steps of: (1) forming an aqueous dispersion of up to 65% by weight of said polymeric color coupling agent by polymerizing an emulsion in water of a solution of a solid water-insoluble ethylenically unsaturated color coupling monomer capable of undergoing free radical addition polymerization at a temperature below the melting point of said monomer or a mixture thereof with a water-insoluble ethylenically unsaturated monomer, said solution being in a solvent for said monomer selected from the group consisting of organic solvents substantially inert with respect to said color coupling monomer and the free radical polymerization products thereof, liquid water-insoluble copolymerizable monomers and mixtures of such organic solvents and such liquid copolymerizable monomers; (2) mixing an aqueous gelatin solution with the said aqueous dispersion of said polymeric color coupling agent; and (3) applying to said support a layer comprising said mixture of step (2).
Claim 2
Dependent Claim
193 words
A process of making a color photographic material comprising a support and a layer comprising gelatin and as a color-coupling agent a water-insoluble homopolymer of a solid water-insoluble ethylenically unsaturated color coupling monomer or a water-insoluble copolymer of said monomer with a water-insoluble ethylenically unsaturated monomer, which process comprises the steps of: (1) forming an aqueous dispersion of up to 65% by weight of said polymeric color coupling agent by polymerizing an emulsion in water of a solution of a solid water-insoluble ethylenically unsaturated color coupling monomer capable of undergoing free radical addition polymerization at a temperature below the melting point of said monomer or a mixture thereof with a water-insoluble ethylenically unsaturated monomer, said solution being in a solvent for said monomer selected from the group consisting of organic solvents substantially inert with respect to said color coupling monomer and the free radical polymerization products thereof, liquid water-insoluble copolymerizable monomers and mixtures of such organic solvents and such liquid copolymerizable monomers; (2) mixing an aqueous gelatin solution with the said aqueous dispersion of said polymeric color coupling agent; and (3) applying to said support a layer comprising said mixture of step (2).
Claim 3
Dependent Claim
70 words
A process according to claim 1 wherein the aqueous dispersion of up to 65% by weight of the polymeric color coupling agent is formed by the steps of: (1) dispersing the solid-water-insoluble color coupling monomer and a solvent therefor in water containing at least one emulsifying agent; (2) adding to the aqueous dispersion a polymerization initiator; and (3) agitating the dispersion under free radical polymerization conditions until polymerization has occurred.
Claim 4
Dependent Claim
29 words
A process according to claim 1 wherein the aqueous dispersion of said polymeric color coupling agent formed by emulsion polymerization has a solid concentration of about 2-50% by weight.
Claim 5
Dependent Claim
39 words
A process according ot claim 2 wherein said solid water-insoluble color coupling monomer and the solvent therefor are dispersed in water by first forming a solution of the monomer in the solvent and dispersing the solution formed in water.
Claim 6
Dependent Claim
24 words
A process according to claim 2 wherein said solid water-insoluble color coupling monomer and the solvent therefor are dispersed in water simultaneously or separately.
Claim 7
Dependent Claim
11 words
A color photographic material prepared by the process of claim 1.
Claim 8
Dependent Claim
76 words
A process according to claim 1 wherein said solid water-insoluble color coupling monomer corresponds to one of the general formulae: ##STR27## wherein R is hydrogen or methyl, R' and R" (same or different) represent hydrogen, halogen, --SO 2 CH 3 , --SO 2 NH 2 , --O--alkyl, X represents halogen, --SO 2 CH 3 , --SO 2 NH 2 , --CN, --alkyl, --O--alkyl, Y represents --O--, or --CONH--, and n is 0, 1, 2 or 3.
References Cited (Backward Citations)
US2563524A
Cited
US2976294A
Cited
US3163625A
Cited
US3356686A
Cited
US3202642A
Cited
US3211552A
Cited
US3325286A
Cited
US3370952A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-20 | 1981-09-19 | 1982-03-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-20 | 1985-09-19 | 1986-03-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-20 | 1989-09-19 | 1990-03-21 | $7700.00 | Window Closed / Lapsed |