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US4078991A Expired / Lapsed US ⏱️ 0.0 years remaining

Treatment of clay materials to form super-active catalyst

Assignee: Mobil Oil AS
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Filing: 1976-03-15
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Granted: 1978-03-14
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Expires: 1996-03-15
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Abstract

Abstract This invention relates to an improved method for treating clay materials to prepare a super-active catalyst for use in catalytic conversion of organic materials such as, for example, hydrocarbon compounds, heavy crude petroleum stock and kerogen, wherein when a clay material is contacted with a solution containing cations selected from the group consisting of transition metal ions, aluminum ions, hydrogen ions, ions of metals from Group IIB of the Periodic Table of Elements and a combination thereof with each other, the clay material is in the raw state and maintained at a temperature not exceeding about 100 DEG C prior to and during the contacting with said solution and thereafter heating said exchanged clay material to a temperature of at least about 50 DEG C but not exceeding about 250 DEG C in the presence of air and/or organic material which is to be catalytically converted. Further, this invention relates to the clay material which is the product of the above improved method and to converting organic materials such as, for example, hydrocarbons, heavy crude petroleum stock and kerogen, by contact at low temperature, e.g. from about 50 DEG C to about 250 DEG C, with said clay material.

Inventors

  • 👤 Theodore P. Goldstein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 13:47
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; B; B01; B01J; B01J21/00; B01J21/16; B01J29/00; B01J29/04; B01J29/049; B01J2229/00; B01J2229/30; B01J2229/42; Y; Y10; Y10S; Y10S585/00; Y10S585/8995; Y10S585/906

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 167 words
In a method for catalytic cracking of organic material which comprises contacting said organic material with a clay material composed primarily of clay minerals selected from the group consisting of kaolinite, halloysite, attapulgite, montmorillonite, illite and combinations thereof, said clay material having been contacted with a solution containing cations selected from the group consisting of transition metal ions, hydrogen ions, aluminum ions, ions of metals from Group IIB of the Periodic Table of Elements and a combination thereof to effect ion exchange of said clay material with said ions, the improvement which comprises using conversion conditions including a low temperature of from about 50° C to about 250° C, said clay material prior to said contact with said solution being in the raw state as found in nature or synthesized and said clay material not being exposed to a temperature exceeding 100° C prior to and during said contact with said solution and not being exposed to a temperature above 250° C. after contact with said solution.
Claim 2
Dependent Claim 167 words
In a method for catalytic cracking of organic material which comprises contacting said organic material with a clay material composed primarily of clay minerals selected from the group consisting of kaolinite, halloysite, attapulgite, montmorillonite, illite and combinations thereof, said clay material having been contacted with a solution containing cations selected from the group consisting of transition metal ions, hydrogen ions, aluminum ions, ions of metals from Group IIB of the Periodic Table of Elements and a combination thereof to effect ion exchange of said clay material with said ions, the improvement which comprises using conversion conditions including a low temperature of from about 50° C to about 250° C, said clay material prior to said contact with said solution being in the raw state as found in nature or synthesized and said clay material not being exposed to a temperature exceeding 100° C prior to and during said contact with said solution and not being exposed to a temperature above 250° C. after contact with said solution.
Claim 3
Dependent Claim 45 words
The method of claim 1 wherein said cracking conditions include a temperature of from about 150° C to about 250° C, a pressure of from about 0 psig to about 500 psig and a weight hourly space velocity of from about 0.001 to about 20.
Claim 4
Dependent Claim 45 words
The method of claim 2 wherein said cracking conditions include a temperature of from about 180° C to about 220° C, a pressure of from about 0 psig to about 100 psig and a weight hourly space velocity of from about 0.01 to about 1.
Claim 5
Dependent Claim 15 words
The method of claim 2 wherein said organic material charge stock is a hydrocarbon compound.
Claim 6
Dependent Claim 47 words
The method of claim 1 wherein said catalytic cracking is reducing the viscosity of heavy crude petroleum stock and said cracking conditions include a pressure of from about 0 psig to about 20,000 psig and a weight hourly space velocity of from about 0.001 to about 50.
Claim 7
Dependent Claim 45 words
The method of claim 5 wherein said cracking conditions include a temperature of from about 150° C to about 200° C, a pressure of from about 0 psig to about 1000 psig and a weight hourly space velocity of from about 0.1 to about 5.
Claim 8
Dependent Claim 41 words
The method of claim 1 wherein said catalytic cracking is decomposing kerogen and said cracking conditions include a pressure of from about 0 psig to about 20,000 psig and a contact time of from about 5 minutes to about 10 years.
Claim 9
Dependent Claim 33 words
The method of claim 7 wherein said cracking conditions include a temperature of from about 150° C to about 200° C and a pressure of from about 0 psig to about 1000 psig.

References Cited (Backward Citations)

US2744057A Cited
US2862875A Cited
US2825699A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-13 1981-09-12 1982-03-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-13 1985-09-12 1986-03-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-13 1989-09-12 1990-03-14 $7700.00 Window Closed / Lapsed

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