US4078990A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Manufacture of lower aromatic compounds
Assignee: Mobil Oil AS
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Filing: 1977-03-04
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Granted: 1978-03-14
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Expires: 1997-03-04
Abstract
Abstract Certain acidic heterogeneous catalysts produce large yields of benzene, toluene and xylene from alkyl aromatics of at least nine carbon atoms by a mechanism different from the classical disproportionation reaction characteristic of acid catalysts. Typically, aromatic mixtures so derived from such stocks have unusually low content of ethyl benzene, thus greatly simplifying separation of xylene isomers.
Inventors
- 👤 James A. Brennan
- 👤 Roger A. Morrison
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 20:00
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/04; C10L1/06; C07; C07C; C07C6/00; C07C6/08; C07C6/12; C10G; C10G2400/00; C10G2400/30
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
192 words
In the manufacture of gasoline and concurrent production of chemical grade aromatic compounds of eight or less carbon atoms by catalytic reforming of naphtha and using part of the reformate for each purpose, the improvement resulting in higher quality gasoline of lower "heavy end" content, which comprises fractionating a catalytic reformate to provide a light reformate containing most of the C 8 and lighter components of the reformate and a heavy reformate which contains no more than 20 weight percent of xylenes, blending said light reformate with other motor fuel components to provide a finished gasoline, contacting said heavy reformate with a solid, porous, acid catalyst characterized by a constraint index not higher than 1 at about 550° to about 1000° F., about 100 to about 2000 pounds per square inch, admixed with 0.5 to 10 mols of hydrogen per mol of hydrocarbon and at a weight hourly space velocity between about 0.1 and about 200 unit weights of hydrocarbon per unit weight of said catalyst per hour, and recover at least one aromatic compound of eight or less carbon atoms from the product of contacting said heavy reformate with said catalyst.
Claim 2
Dependent Claim
192 words
In the manufacture of gasoline and concurrent production of chemical grade aromatic compounds of eight or less carbon atoms by catalytic reforming of naphtha and using part of the reformate for each purpose, the improvement resulting in higher quality gasoline of lower "heavy end" content, which comprises fractionating a catalytic reformate to provide a light reformate containing most of the C 8 and lighter components of the reformate and a heavy reformate which contains no more than 20 weight percent of xylenes, blending said light reformate with other motor fuel components to provide a finished gasoline, contacting said heavy reformate with a solid, porous, acid catalyst characterized by a constraint index not higher than 1 at about 550° to about 1000° F., about 100 to about 2000 pounds per square inch, admixed with 0.5 to 10 mols of hydrogen per mol of hydrocarbon and at a weight hourly space velocity between about 0.1 and about 200 unit weights of hydrocarbon per unit weight of said catalyst per hour, and recover at least one aromatic compound of eight or less carbon atoms from the product of contacting said heavy reformate with said catalyst.
Claim 3
Dependent Claim
31 words
The process of claim 1 wherein said heavy reformate charge includes a minor amount of eight carbon atom aromatics and is essentially free of aromatics having less than eight carbon atoms.
Claim 4
Dependent Claim
16 words
The process of claim 1 wherein the operating conditions range from about 0.5 to 10 WHSV.
Claim 5
Dependent Claim
12 words
The process of claim 1 wherein said catalyst includes a hydrogenation metal.
Claim 6
Dependent Claim
10 words
The process of claim 4 wherein said metal is nickel.
Claim 7
Dependent Claim
12 words
The process of claim 4 wherein said metal is nickel or cobalt.
Claim 8
Dependent Claim
138 words
A process for producing aromatic compounds of six to eight carbon atoms from an aromatic hydrocarbon charge predominantly higher in molecular weight than eight carbon atom aromatics, without substantial formation of heavier (350° F.+) aromatics through conventional disproportionation or transalkylation reactions, which process comprises contacting said charge with a porous solid acid catalyst characterized by a constraint index not higher than 1 at about 550 to about 1000° F., about 100 to about 2,000 pounds per square inch, admixed with 0.5 to 10 mols of hydrogen per mol of hydrocarbon and at a weight hourly space velocity between about 0.1 and about 200 unit weights of hydrocarbon per unit weight of said catalyst per hour and recovering at least one aromatic compound of eight or less carbon atoms from the product of contacting said charge with said catalyst.
Claim 9
Dependent Claim
138 words
A process for producing aromatic compounds of six to eight carbon atoms from an aromatic hydrocarbon charge predominantly higher in molecular weight than eight carbon atom aromatics, without substantial formation of heavier (350° F.+) aromatics through conventional disproportionation or transalkylation reactions, which process comprises contacting said charge with a porous solid acid catalyst characterized by a constraint index not higher than 1 at about 550 to about 1000° F., about 100 to about 2,000 pounds per square inch, admixed with 0.5 to 10 mols of hydrogen per mol of hydrocarbon and at a weight hourly space velocity between about 0.1 and about 200 unit weights of hydrocarbon per unit weight of said catalyst per hour and recovering at least one aromatic compound of eight or less carbon atoms from the product of contacting said charge with said catalyst.
Claim 10
Dependent Claim
29 words
The process of claim 7 wherein said charge includes a minor amount of eight carbon atom aromatics and is essentially free of aromatics having less than eight carbon atoms.
Claim 11
Dependent Claim
12 words
The process of claim 7 wherein said charge is a heavy reformate.
Claim 12
Dependent Claim
13 words
The process of claim 7 wherein said charge is a heavy pyrolysis gasoline.
Claim 13
Dependent Claim
16 words
The process of claim 7 wherein the operating condition range is from 0.5 to 10 WHSV.
Claim 14
Dependent Claim
12 words
The process of claim 7 wherein said catalyst includes a hydrogenation metal.
Claim 15
Dependent Claim
12 words
The process of claim 12 wherein said metal is nickel or cobalt.
Claim 16
Dependent Claim
26 words
The process of claim 1 wherein C 9 + aromatics are separated from said product and admixed with said heavy reformate for contact with such catalyst.
Claim 17
Dependent Claim
28 words
The process of claim 1 wherein C 9 + aromatics and toluene are separated from said product and admixed with said heavy reformate for contact with said catalyst.
Claim 18
Dependent Claim
18 words
The process of claim 1 wherein said heavy reformate contains no more than 10 weight percent of xylenes.
Claim 19
Dependent Claim
25 words
The process of claim 7 wherein C 9 + aromatics are separated from said product and admixed with said charge for contact with said catalyst.
Claim 20
Dependent Claim
27 words
The process of claim 7 wherein C 9 + aromatics and toluene are separated from said product and admixed with said charge for contact with said catalyst.
Claim 21
Dependent Claim
17 words
The process of claim 7 wherein said charge contains no more than 10 weight percent of xylenes.
Claim 22
Dependent Claim
47 words
The process of claim 1 wherein a xylene fraction is separated from said product, a desired xylene isomer is isolated from xylene fraction and the resultant mixture of xylenes lean in said desired isomer is recycled to contact with said catalyst in admixture with said heavy reformate.
Claim 23
Dependent Claim
47 words
The process of claim 7 wherein a xylene fraction is separated from said product, a desired xylene isomer is isolated from said xylene fraction, and the resultant mixture of xylenes lean in said desired isomer is recycled to contact with said catalyst in admixture with said charge.
Claim 24
Dependent Claim
37 words
The process of claim 1 wherein at least a portion of the said product after recovery therefrom of aromatics of eight or less carbon atoms is blended with other motor fuel components to make a motor gasoline.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-13 | 1981-09-12 | 1982-03-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-13 | 1985-09-12 | 1986-03-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-13 | 1989-09-12 | 1990-03-14 | $7700.00 | Window Closed / Lapsed |