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US4078973A Expired / Lapsed US ⏱️ 0.0 years remaining

Loop pyrolysis process for organic solid wastes

Assignee: Occidental Petroleum Corp
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Filing: 1976-08-31
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Granted: 1978-03-14
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Expires: 1996-08-31
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Abstract

Abstract Particulate organic solid waste is pyrolyzed in the presence of an inert particulate source of heat and a carrier gas in a pyrolysis reactor to form a carbon containing solid residue of pyrolysis, pyrolytic oils and gases. The particulate source of heat and carbon containing solid residue of pyrolysis are separated from the product stream. The particulate source of heat and carbon containing solid residue of pyrolysis are transported to a combustion zone where through partial or total combustion. The particulate source of heat is reheated to a temperature requisite for feed to the pyrolysis reactor with attendant generation of additional particulate source of heat.

Inventors

  • 👤 Charles K. Choi
  • 👤 Robert W. Frischmuth
  • 👤 Richard M. Gundzik
  • 👤 Joseph P. Tassoney

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 08:24
CPC Classifications
C; C10; C10B; C10B53/00; C10B53/02; C10B49/00; C10B49/16; C10B49/20; Y; Y02; Y02E; Y02E50/00; Y02E50/10

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 484 words
A loop process for pyrolysis of organic solid waste which comprises continuously: a. pyrolyzing particulate organic solid waste having a maximum particle dimension less than 1 inch by combining and passing the particulate organic solid waste and a hot particulate source of heat selected from the group consisting of a carbon containing solid residue of pyrolysis, an inorganic heat source formed from decarbonization of the carbon containing solid residue of pyrolysis and mixtures thereof, with a fluidizing transport carrier gas which is nondeleteriously reactive with respect to the products of pyrolysis through a transport flash pyrolysis zone under turbulent flow conditions for a time sufficient to pyrolyze the organic solid waste to the carbon containing solid residue of pyrolysis, pyrolytic oils and gases, said flash pyrolysis zone being maintained at an operating pressure above atmospheric and at an operating temperature between about 600° F and the introduction temperature of the particulate heat source to said pyrolysis zone; b. withdrawing a fluidized mixture of the carrier gas, particulate source of heat, the carbon containing solid residue of pyrolysis, pyrolytic oils and gas from the flash pyrolysis zone; c. separating the particulate source of heat and the carbon containing solid residue of pyrolysis from the fluidized mixture and collecting the separated particulate source of heat and carbon containing solid residue of pyrolysis in a first particles collection zone wherein the particles are maintained in a dense fluidized state; d. withdrawing from the first particles collection zone a dense fluidized mixture of the particulate source of heat and carbon containing solid residue of pyrolysis through a first vertically oriented fluidized leg coupled to a first solids transport conduit connected to a fluidized solids transport burner, the particles in said first fluidized leg providing at the base thereof, a static pressure greater than the operating pressure of the fluidized solids transport burner; e. transporting the withdrawn particulate mixture through said first solids transport conduit to said fluidized solids transport burner; f. decarbonizing at least a portion of the carbon containing solid residue of pyrolysis in said fluidizing char transport burner to form the particulate source of heat at a temperature at least sufficient for feed to said pyrolysis zone; g. removing the formed particulate source of heat from the fluidized solids transport burner and collecting a portion of the formed particulate source of heat in a second particles collection zone; and h. withdrawing from the second particles collection zone particulate source of heat to a second vertically oriented fluidized leg coupled to a second solids transport conduit connected to said transport flash pyrolysis zone and transporting under fluidized conditions the withdrawn particulate source of heat to said transport flash pyrolysis zone, the height of the particulate static source in said second fluidized leg being sufficient to maintain a static pressure at the base of said second fluidized leg greater than the operating pressure of the flash pyrolysis zone.
Claim 2
Dependent Claim 484 words
A loop process for pyrolysis of organic solid waste which comprises continuously: a. pyrolyzing particulate organic solid waste having a maximum particle dimension less than 1 inch by combining and passing the particulate organic solid waste and a hot particulate source of heat selected from the group consisting of a carbon containing solid residue of pyrolysis, an inorganic heat source formed from decarbonization of the carbon containing solid residue of pyrolysis and mixtures thereof, with a fluidizing transport carrier gas which is nondeleteriously reactive with respect to the products of pyrolysis through a transport flash pyrolysis zone under turbulent flow conditions for a time sufficient to pyrolyze the organic solid waste to the carbon containing solid residue of pyrolysis, pyrolytic oils and gases, said flash pyrolysis zone being maintained at an operating pressure above atmospheric and at an operating temperature between about 600° F and the introduction temperature of the particulate heat source to said pyrolysis zone; b. withdrawing a fluidized mixture of the carrier gas, particulate source of heat, the carbon containing solid residue of pyrolysis, pyrolytic oils and gas from the flash pyrolysis zone; c. separating the particulate source of heat and the carbon containing solid residue of pyrolysis from the fluidized mixture and collecting the separated particulate source of heat and carbon containing solid residue of pyrolysis in a first particles collection zone wherein the particles are maintained in a dense fluidized state; d. withdrawing from the first particles collection zone a dense fluidized mixture of the particulate source of heat and carbon containing solid residue of pyrolysis through a first vertically oriented fluidized leg coupled to a first solids transport conduit connected to a fluidized solids transport burner, the particles in said first fluidized leg providing at the base thereof, a static pressure greater than the operating pressure of the fluidized solids transport burner; e. transporting the withdrawn particulate mixture through said first solids transport conduit to said fluidized solids transport burner; f. decarbonizing at least a portion of the carbon containing solid residue of pyrolysis in said fluidizing char transport burner to form the particulate source of heat at a temperature at least sufficient for feed to said pyrolysis zone; g. removing the formed particulate source of heat from the fluidized solids transport burner and collecting a portion of the formed particulate source of heat in a second particles collection zone; and h. withdrawing from the second particles collection zone particulate source of heat to a second vertically oriented fluidized leg coupled to a second solids transport conduit connected to said transport flash pyrolysis zone and transporting under fluidized conditions the withdrawn particulate source of heat to said transport flash pyrolysis zone, the height of the particulate static source in said second fluidized leg being sufficient to maintain a static pressure at the base of said second fluidized leg greater than the operating pressure of the flash pyrolysis zone.
Claim 3
Dependent Claim 80 words
The process of claim 1 in which the particulate source of heat is the inorganic heat source formed from decarbonization of the carbon containing solid residue of pyrolysis and said pyrolysis zone is maintained at a temperature from about 600° F to about 1700° F and said inorganic heat source is formed by decarbonization of the carbon containing solid residue of pyrolysis in said fluidized solids transport burner at a temperature below the fusion temperature of said inorganic heat source.
Claim 4
Dependent Claim 26 words
The process of claim 2 in which at least 80% of the carbon containing solid residue of pyrolysis is decarbonized in said fluidized solids transport burner.
Claim 5
Dependent Claim 22 words
The process of claim 2 in which said pyrolysis zone is maintained at a temperature from about 800° to about 1400° F.
Claim 6
Dependent Claim 21 words
The process of claim 1 in which the carrier gas is the gas formed by pyrolysis of the solid organic waste.
Claim 7
Dependent Claim 48 words
The process of claim 2 in which the carbon containing solid residue of pyrolysis and char are withdrawn from said first particles collection zone at a composition approximate that of the composition of said carbon containing solid residue of pyrolysis and inorganic heat source exiting said pyrolysis zone.
Claim 8
Dependent Claim 36 words
the process of claim 1 in which the particulate source of heat is the carbon containing solid residue of pyrolysis and said pyrolysis zone is maintained at a temperature from about 600° to about 2000° F.
Claim 9
Dependent Claim 23 words
The process of claim 1 in which the particulate source of heat is of a particle size from about 10 and 2000 microns.
Claim 10
Dependent Claim 24 words
The process of claim 1 in which the particulate source of heat is of a particle size from about 20 to about 1000 microns.
Claim 11
Dependent Claim 37 words
The process of claim 1 in which the weight ratio of the particulate source of heat to the organic solid waste fed to said pyrolysis zone is from about 2 to 1 to about 10 to 1.
Claim 12
Dependent Claim 37 words
The process of claim 1 in which the weight ratio of the particulate source of heat to the organic solid waste fed to said pyrolysis zone is from about 4 to 1 to about 5 to 1.
Claim 13
Dependent Claim 22 words
The process of claim 1 in which residence time of particles in the pyrolysis zone is from 0.1 to about 2 seconds.
Claim 14
Dependent Claim 23 words
The process of claim 1 in which residence time of particles in the pyrolysis zone is from about 0.1 to about 1 second.
Claim 15
Dependent Claim 49 words
The process of claim 1 in which the pressure at the base of the first fluidized leg is greater than the pressure in said fluidized solids transport burner, and the pressure at the base of the second fluidized leg is greater than the pressure of said flash pyrolysis zone.
Claim 16
Dependent Claim 22 words
The process of claim 1 in which the particulate solid organic waste is of a particle size less than about 5 mesh.
Claim 17
Dependent Claim 22 words
The process of claim 1 in which the particulate solid organic waste is of a particle size less than about 8 mesh.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-13 1981-09-12 1982-03-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-13 1985-09-12 1986-03-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-13 1989-09-12 1990-03-14 $7700.00 Window Closed / Lapsed

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