US4077944A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Catalytic production of polyesters
Assignee: Union Carbide Corp
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Filing: 1977-02-28
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Granted: 1978-03-07
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Expires: 1997-02-28
Abstract
Abstract A process for producing polyesters and copolyesters, useful for making films and fibers, by the polycondensation of dicarboxylic acids and aliphatic glycols using certain silicon compounds as catalysts.
Inventors
- 👤 Kurt Weinberg
- 👤 Gordon Carlton Johnson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 19:50
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/78; C08G63/82; C08G63/87
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
204 words
In a process for the manufacture of solid fiber-forming polyesters and copolyesters of dicarboxylic acid compounds and aliphatic glycols in the presence of catalysts, the improvement of using as polycondensation catalyst a silicon compound selected from the group consisting of: ##STR5## (IV) QCH 2 CH 2 SiR 3 ** wherein W is CH 2 ═CX-- or ##STR6## X is hydrogen or methyl and is methyl only when m is one; R* is alkyl or haloalkyl having from 1 to 4 carbon atoms; R** is methyl, ethyl, butyl, acetoxy methoxy, ethoxy or butoxy; R is methyl, ethyl, butyl or trimethylsiloxy; R' is methyl, methoxy, ethoxy, butoxy or trimethylsiloxy; R" is methoxy, ethoxy, butoxy, trimethylsiloxy or vinyldimethylsiloxy; R'" is methyl, ethyl, butyl or trimethylsilyl; Me is methyl; Z is methyl or W; Q is an NH 2 CH 2 --, NH 2 CH 2 CH 2 NHCH 2 --, NC--, HS-- or HSCH 2 CH 2 S-- group; n is an integer having a value of from 2 to 5; m is an integer having a value of zero or one; x is an integer having a value of from 1 to 100; and y is an integer having a value of from 1 to 100.
Claim 2
Dependent Claim
204 words
In a process for the manufacture of solid fiber-forming polyesters and copolyesters of dicarboxylic acid compounds and aliphatic glycols in the presence of catalysts, the improvement of using as polycondensation catalyst a silicon compound selected from the group consisting of: ##STR5## (IV) QCH 2 CH 2 SiR 3 ** wherein W is CH 2 ═CX-- or ##STR6## X is hydrogen or methyl and is methyl only when m is one; R* is alkyl or haloalkyl having from 1 to 4 carbon atoms; R** is methyl, ethyl, butyl, acetoxy methoxy, ethoxy or butoxy; R is methyl, ethyl, butyl or trimethylsiloxy; R' is methyl, methoxy, ethoxy, butoxy or trimethylsiloxy; R" is methoxy, ethoxy, butoxy, trimethylsiloxy or vinyldimethylsiloxy; R'" is methyl, ethyl, butyl or trimethylsilyl; Me is methyl; Z is methyl or W; Q is an NH 2 CH 2 --, NH 2 CH 2 CH 2 NHCH 2 --, NC--, HS-- or HSCH 2 CH 2 S-- group; n is an integer having a value of from 2 to 5; m is an integer having a value of zero or one; x is an integer having a value of from 1 to 100; and y is an integer having a value of from 1 to 100.
Claim 3
Dependent Claim
33 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: ##STR7## wherein W, R, R', R", n and m are as defined in claim 1.
Claim 4
Dependent Claim
30 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: ##STR8## wherein Me, W and Z are as defined in claim 1.
Claim 5
Dependent Claim
32 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: ##STR9## wherein Me, W, R'", x and y are as defined in claim 1.
Claim 6
Dependent Claim
32 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: QCH.sub.2 CH.sub.2 SiR.sub.2 ** wherein Q and R** are as defined in claim 1.
Claim 7
Dependent Claim
15 words
A process as claimed in claim 1, wherein the silicon compound is beta-diethoxyphosphorylethyl methyl diethoxysilane.
Claim 8
Dependent Claim
14 words
A process as claimed in claim 1, wherein the silicon compound is 2-cyanoethyl triethoxysilane.
Claim 9
Dependent Claim
14 words
A process as claimed in claim 1, wherein the silicon compound is 3-aminopropyl triethoxysilane.
References Cited (Backward Citations)
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US3525709A
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US3451970A
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US3506618A
Cited
US3546179A
Cited
US3965071A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-06 | 1981-09-05 | 1982-03-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-06 | 1985-09-05 | 1986-03-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-06 | 1989-09-05 | 1990-03-07 | $7700.00 | Window Closed / Lapsed |