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US4077944A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalytic production of polyesters

Assignee: Union Carbide Corp
•
Filing: 1977-02-28
•
Granted: 1978-03-07
•
Expires: 1997-02-28
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Abstract

Abstract A process for producing polyesters and copolyesters, useful for making films and fibers, by the polycondensation of dicarboxylic acids and aliphatic glycols using certain silicon compounds as catalysts.

Inventors

  • 👤 Kurt Weinberg
  • 👤 Gordon Carlton Johnson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 19:50
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/78; C08G63/82; C08G63/87

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 204 words
In a process for the manufacture of solid fiber-forming polyesters and copolyesters of dicarboxylic acid compounds and aliphatic glycols in the presence of catalysts, the improvement of using as polycondensation catalyst a silicon compound selected from the group consisting of: ##STR5## (IV) QCH 2 CH 2 SiR 3 ** wherein W is CH 2 ═CX-- or ##STR6## X is hydrogen or methyl and is methyl only when m is one; R* is alkyl or haloalkyl having from 1 to 4 carbon atoms; R** is methyl, ethyl, butyl, acetoxy methoxy, ethoxy or butoxy; R is methyl, ethyl, butyl or trimethylsiloxy; R' is methyl, methoxy, ethoxy, butoxy or trimethylsiloxy; R" is methoxy, ethoxy, butoxy, trimethylsiloxy or vinyldimethylsiloxy; R'" is methyl, ethyl, butyl or trimethylsilyl; Me is methyl; Z is methyl or W; Q is an NH 2 CH 2 --, NH 2 CH 2 CH 2 NHCH 2 --, NC--, HS-- or HSCH 2 CH 2 S-- group; n is an integer having a value of from 2 to 5; m is an integer having a value of zero or one; x is an integer having a value of from 1 to 100; and y is an integer having a value of from 1 to 100.
Claim 2
Dependent Claim 204 words
In a process for the manufacture of solid fiber-forming polyesters and copolyesters of dicarboxylic acid compounds and aliphatic glycols in the presence of catalysts, the improvement of using as polycondensation catalyst a silicon compound selected from the group consisting of: ##STR5## (IV) QCH 2 CH 2 SiR 3 ** wherein W is CH 2 ═CX-- or ##STR6## X is hydrogen or methyl and is methyl only when m is one; R* is alkyl or haloalkyl having from 1 to 4 carbon atoms; R** is methyl, ethyl, butyl, acetoxy methoxy, ethoxy or butoxy; R is methyl, ethyl, butyl or trimethylsiloxy; R' is methyl, methoxy, ethoxy, butoxy or trimethylsiloxy; R" is methoxy, ethoxy, butoxy, trimethylsiloxy or vinyldimethylsiloxy; R'" is methyl, ethyl, butyl or trimethylsilyl; Me is methyl; Z is methyl or W; Q is an NH 2 CH 2 --, NH 2 CH 2 CH 2 NHCH 2 --, NC--, HS-- or HSCH 2 CH 2 S-- group; n is an integer having a value of from 2 to 5; m is an integer having a value of zero or one; x is an integer having a value of from 1 to 100; and y is an integer having a value of from 1 to 100.
Claim 3
Dependent Claim 33 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: ##STR7## wherein W, R, R', R", n and m are as defined in claim 1.
Claim 4
Dependent Claim 30 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: ##STR8## wherein Me, W and Z are as defined in claim 1.
Claim 5
Dependent Claim 32 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: ##STR9## wherein Me, W, R'", x and y are as defined in claim 1.
Claim 6
Dependent Claim 32 words
A process as claimed in claim 1, wherein the silicon compound is a compound of the general formula: QCH.sub.2 CH.sub.2 SiR.sub.2 ** wherein Q and R** are as defined in claim 1.
Claim 7
Dependent Claim 15 words
A process as claimed in claim 1, wherein the silicon compound is beta-diethoxyphosphorylethyl methyl diethoxysilane.
Claim 8
Dependent Claim 14 words
A process as claimed in claim 1, wherein the silicon compound is 2-cyanoethyl triethoxysilane.
Claim 9
Dependent Claim 14 words
A process as claimed in claim 1, wherein the silicon compound is 3-aminopropyl triethoxysilane.

References Cited (Backward Citations)

US2465319A Cited
US3525709A Cited
US3451970A Cited
US3506618A Cited
US3546179A Cited
US3965071A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-06 1981-09-05 1982-03-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-06 1985-09-05 1986-03-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-06 1989-09-05 1990-03-07 $7700.00 Window Closed / Lapsed

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