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US4075285A Expired / Lapsed US ⏱️ 0.0 years remaining

Rubber-modified polystyrene resin composition

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1975-03-03
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Granted: 1978-02-21
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Expires: 1995-03-03
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Abstract

Abstract A rubber-modified polystyrene resin composition consisting essentially of a rubber-modified polystyrene and a transparent, resinous styrene-butadiene block copolymer containing 65 to 95% by weight of styrene and 5 to 35% by weight of butadiene. This resin composition is excellent in impact strength, elongation, flexural stress clouding, hinging endurance, and surface gloss.

Inventors

  • 👤 Minoru Tabana
  • 👤 Shizuo Narisawa
  • 👤 Tatsuyuki Mitsuno
  • 👤 Hiroshi Maki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 05:58
CPC Classifications
C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/06; C08L51/00; C08L51/04; C08L53/00; C08L53/02

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 86 words
A resin composition consisting essentially of a rubber modified polystyrene which is obtained by mechanically mixing a rubbery substance selected from the group consisting of polybutadiene, and styrene-butadiene with polystyrene or by graft-copolymerizing styrene with said rubbery substance and a transparent styrene-butadiene block copolymer containing 65 to 95% by weight of styrene and 5 to 35% by weight of butadiene, wherein the ratio of said rubber-modified polystyrene to said styrene-butadiene block copolymer is in the range from 0.5 : 99.5 to 15 : 85 by weight.
Claim 2
Dependent Claim 86 words
A resin composition consisting essentially of a rubber modified polystyrene which is obtained by mechanically mixing a rubbery substance selected from the group consisting of polybutadiene, and styrene-butadiene with polystyrene or by graft-copolymerizing styrene with said rubbery substance and a transparent styrene-butadiene block copolymer containing 65 to 95% by weight of styrene and 5 to 35% by weight of butadiene, wherein the ratio of said rubber-modified polystyrene to said styrene-butadiene block copolymer is in the range from 0.5 : 99.5 to 15 : 85 by weight.
Claim 3
Dependent Claim 209 words
A resin composition according to claim 1, wherein the structure of the styrene-butadiene block copolymer is 1. (S-B) n , (S-B) n -S, or B-(S-B) n , 2. [S-(S/B)] n , [S-(S/B)] n -S, or (S-B)-[S-(S/B)] n , 3. [(B→S)] n -S, S-[(B→S)] n , S-[(B→S)] n -S, or S-[(S←B→S)] n -S, or 4. S-[(S/B)→ (S/B)]-S, or S-[(S/B) ← (S/B) → (S/B)]-S wherein S represents a block chain composed of polymerized styrene, B represents an elastomeric block chain composed of polymerized butadiene, (S/B) represents an elastomeric block chain comprising copolymerized styrene and butadiene, in which chain styrene and butadiene are bound to each other in a fixed ratio [the ratio of S to B in (S/B) can be any of the ratios including the case where S is absent], (B→S) or (S←B→S) represents an elastomeric block chain comprising copolymerized styrene and butadiene, in which chain in the direction denoted by an arrow butadiene content gradually decreases while styrene content increases, [(S/B) → (S/B)] or [(S/B) ← (S/B) → (S/B)] represents an elastomeric block chain comprising a styrene-butadiene copolymer chain in which styrene and butadiene are bound in a random ratio and the ratio vaires within the chain intermittently or continuously, and n is an integer of 1 to 3.
Claim 4
Dependent Claim 25 words
A resin composition according to claim 2, wherein the elastomeric block chain in the styrene-butadiene block copolymer is a polymeric chain comprising styrene-butadiene copolymer chain.
Claim 5
Dependent Claim 16 words
A resin composition according to claim 1, which is incorporated with a stabilizer, colorant, and lubricant.

References Cited (Backward Citations)

FR1471458A Cited
GB1145923A Cited
FR1493846A Cited
US3562204A Cited
FR2037432A5 Cited
US3906057A Cited
US3853978A Cited
US3873645A Cited
US3835200A Cited
US3907930A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-20 1981-08-22 1982-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-20 1985-08-22 1986-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-20 1989-08-22 1990-02-21 $7700.00 Window Closed / Lapsed

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