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US4075160A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-carcinogenic carbon black

Assignee: Phillips Petroleum Co
•
Filing: 1976-04-30
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Granted: 1978-02-21
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Expires: 1996-04-30
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Abstract

Abstract A non-carcinogenic carbon black is produced by severely aftertreatng a carbon black-containing smoke inside of the carbon black reactor to result in a carbon black with a photelometer of 100% and a pitting degree (nitrogen surface area minus CTAB surface area) of about 7 square meters per gram or more, oxidizing this carbon black and thereafter high temperature drying wet pellets made from this carbon black at a temperature between about 500° and 600° F.

Inventors

  • 👤 King L. Mills
  • 👤 Paul H. Johnson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 04:49
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/44; C09C1/48; C09C1/56; C09C1/565; C08; C08K; C08K3/00; C08K3/02; C08K3/04; C09C1/58; C01; C01P; C01P2006/00; C01P2006/12

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 151 words
A process for the production of a non-carcinogenic carbon black comprising a. pyrolytically in a carbon black furnace decomposing a hydrocarbon feedstock having a low carbon residue of less than about 0.2 weight % such as to form a smoke containing a carbon black having a CTAB surface area of about 80 m 2 /g or more, b. aftertreating said smoke by subjecting it to at least one of the steps of late quenching and secondary air injecting such as to produce a smoke containing a carbon black having a photelometer of about 100% and a pitting degree defined as the difference between the nitrogen surface area and the CTAB surface area of 7 m 2 /g or more, c. oxidizing the carbon black and pelleting the carbon black with an aqueous pelleting agent, and d. drying the wet carbon black pellets at a temperature of about 500° to 600° F.
Claim 2
Dependent Claim 151 words
A process for the production of a non-carcinogenic carbon black comprising a. pyrolytically in a carbon black furnace decomposing a hydrocarbon feedstock having a low carbon residue of less than about 0.2 weight % such as to form a smoke containing a carbon black having a CTAB surface area of about 80 m 2 /g or more, b. aftertreating said smoke by subjecting it to at least one of the steps of late quenching and secondary air injecting such as to produce a smoke containing a carbon black having a photelometer of about 100% and a pitting degree defined as the difference between the nitrogen surface area and the CTAB surface area of 7 m 2 /g or more, c. oxidizing the carbon black and pelleting the carbon black with an aqueous pelleting agent, and d. drying the wet carbon black pellets at a temperature of about 500° to 600° F.
Claim 3
Dependent Claim 23 words
A process in accordance with claim 1 wherein said feedstock is selected from the group consisting of toluene and SO 2 extract oil.
Claim 4
Dependent Claim 53 words
A process in accordance with claim 1 wherein said carbon black is oxidized by contacting the carbon black with an aqueous solution of HNO 3 so that the mixture of carbon black and aqueous pelleting agent contains about 2 to 10 wt. % of HNO 3 based on the carbon black as 100%.
Claim 5
Dependent Claim 43 words
A process in accordance with claim 1 wherein said aftertreating of said carbon black containing smoke is carried out by a late quench step and/or by the introduction of secondary air between the main carbon black forming reaction zone and a quench location.
Claim 6
Dependent Claim 153 words
A non-carcinogenic carbon black obtained by a pyrolytic decomposition in a carbon black furnace of a hydrocarbon feedstock having a carbon residue of less than about 0.2 weight percent into a carbon black containing smoke, aftertreating said carbon black containing smoke by subjecting it to at least one of the steps of late quenching and secondary air injecting, oxidizing the so-produced carbon black and pelleting the carbon black with an aqueous pelleting agent and drying the wet carbon black pellets at a temperature of about 500° to 600° F., said carbon black being further characterized by having a CTAB surface area of 80 m 2 /g or more a pitting degree of 7 m 2 /g or more, said pitting degree being defined as the difference between the nitrogen surface area in the CTAB surface area, a photelometer of 100 percent, and a content of benzene extractables of less than 0.05 weight percent.
Claim 7
Dependent Claim 153 words
A non-carcinogenic carbon black obtained by a pyrolytic decomposition in a carbon black furnace of a hydrocarbon feedstock having a carbon residue of less than about 0.2 weight percent into a carbon black containing smoke, aftertreating said carbon black containing smoke by subjecting it to at least one of the steps of late quenching and secondary air injecting, oxidizing the so-produced carbon black and pelleting the carbon black with an aqueous pelleting agent and drying the wet carbon black pellets at a temperature of about 500° to 600° F., said carbon black being further characterized by having a CTAB surface area of 80 m 2 /g or more a pitting degree of 7 m 2 /g or more, said pitting degree being defined as the difference between the nitrogen surface area in the CTAB surface area, a photelometer of 100 percent, and a content of benzene extractables of less than 0.05 weight percent.
Claim 8
Dependent Claim 65 words
A polymer composition consisting essentially of 100 parts by weight of a polymer selected from the group of rubbers and thermoplastic polymers and about 1 to about 200 parts by weight of carbon black of claim 5 per 100 parts by weight of rubber and 0.1 to 50 parts by weight of carbon black of claim 5 per 100 parts by weight of thermoplastic polymer.
Claim 9
Dependent Claim 27 words
A polymer composition in accordance with claim 5 containing about 20 to 80 parts by weight of said carbon black per 100 parts by weight of rubber.
Claim 10
Dependent Claim 36 words
A polymer composition in accordance with claim 6 consisting essentially of 100 parts by weight of a thermoplastic polymer and 0.1 to 10 parts by weight of a carbon black produced in accordance with claim 1.

References Cited (Backward Citations)

US3009784A Cited
US3290791A Cited
US3523812A Cited
US3761577A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-20 1981-08-22 1982-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-20 1985-08-22 1986-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-20 1989-08-22 1990-02-21 $7700.00 Window Closed / Lapsed

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