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US4073988A Expired / Lapsed US ⏱️ 0.0 years remaining

Suede-like artificial leathers and a method for manufacturing same

Assignee: Kanebo Ltd
•
Filing: 1976-11-29
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Granted: 1978-02-14
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Expires: 1996-11-29
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Abstract

Abstract Natural suede-like artificial leathers are manufactured by subjecting pile fibrous structures wherein at least the pile portion is composed of separatable composite filaments made by bonding different polymers having mutual low adhesive affinity with each other, the cross-section of which is constituted of a radial segment (A) and segments (B) complementing the radial segment or a radial segment (A), segments (B') corresponding to said radial segment and having wedge-shaped concave portions directing to the center and wedge-shaped segments (C) complementing said concave portions, to at least one of a heat treatment and a swelling treatment to shrink said fibrous structure at least 10% in the area, impregnating or coating said fibrous structures with a synthetic polymer solution or emulsion, coagulating said polymer solution or emulsion, drying the thus treated pile fibrous structure and then buffing said piles to raise naps.

Inventors

  • 👤 Takeshi Nishida
  • 👤 Masao Morioka
  • 👤 Tetsuro Ohta
  • 👤 Yukio Yamakawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:32
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/244; D01; D01D; D01D5/00; D01D5/28; D01D5/30; D06M15/263; D06M15/37; D06M15/564; D06M15/59; D06M15/693; D06N; D06N3/00; D06N3/0002; D06N3/0004; Y; Y10; Y10S; Y10S428/00; Y10S428/904; Y10T; Y10T428/00; Y10T428/23907; Y10T428/2395; Y10T428/23986; Y10T428/23993; Y10T428/29; Y10T428/2913; Y10T428/2929; Y10T428/2931; Y10T428/2973

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 285 words
An artificial leather having a suede-like texture, consisting of a shrunk fabric selected from the group consisting of pile woven fabrics, raised woven fabrics, pile knitted fabrics and raised knitted fabrics, said fabric consisting of a substrate having napped piles projecting therefrom and uniformly distributed over the entire surface of the substrate at a high nap density, said piles having a length of 0.5 to 4.0 mm, said piles consisting essentially of fibrillated composite filaments consisting of synthetic polymers having mutually low adhesive affinity to each other, said fibrillated composite filaments having been obtained by filbrillating composite filaments which in transverse cross-section consist of at least three integral layers (A) of one polymer wherein said layers diverge from each other substantially radially in the outward direction and extend to the perimeter of the filament and the spaces between said layers are filled with either segments (B) of another polymer or concave segments (B') of said another polymer the concavities of which are filled with segments (C) of a different polymer, wherein all of the polymers extend to the perimeter of the filament, so that the polymers are separated from each other, said fabric having been shrunk from 10 to 40% of its original area and then having been impregnated with from 3 to 40 percent by weight, based on the weight of said fabric, of a substantially microporous synthetic polymer, the piles having been buffed after impregnation with said polymer to transform same to napped piles consisting of uniformly dispersed separate very fine fibrils of (A) and (B) or (A), (B') and (C) having a nap fibril denier of from 0.05 to 1 denier and a nap fibril length of from 0.2 to 3.0 mm.
Claim 2
Dependent Claim 285 words
An artificial leather having a suede-like texture, consisting of a shrunk fabric selected from the group consisting of pile woven fabrics, raised woven fabrics, pile knitted fabrics and raised knitted fabrics, said fabric consisting of a substrate having napped piles projecting therefrom and uniformly distributed over the entire surface of the substrate at a high nap density, said piles having a length of 0.5 to 4.0 mm, said piles consisting essentially of fibrillated composite filaments consisting of synthetic polymers having mutually low adhesive affinity to each other, said fibrillated composite filaments having been obtained by filbrillating composite filaments which in transverse cross-section consist of at least three integral layers (A) of one polymer wherein said layers diverge from each other substantially radially in the outward direction and extend to the perimeter of the filament and the spaces between said layers are filled with either segments (B) of another polymer or concave segments (B') of said another polymer the concavities of which are filled with segments (C) of a different polymer, wherein all of the polymers extend to the perimeter of the filament, so that the polymers are separated from each other, said fabric having been shrunk from 10 to 40% of its original area and then having been impregnated with from 3 to 40 percent by weight, based on the weight of said fabric, of a substantially microporous synthetic polymer, the piles having been buffed after impregnation with said polymer to transform same to napped piles consisting of uniformly dispersed separate very fine fibrils of (A) and (B) or (A), (B') and (C) having a nap fibril denier of from 0.05 to 1 denier and a nap fibril length of from 0.2 to 3.0 mm.
Claim 3
Dependent Claim 31 words
An artificial leather as claimed in claim 1, in which said filaments consist of (A) and (B), and wherein (A) is 10 to 50% of the cross-sectional area of the filaments.
Claim 4
Dependent Claim 31 words
An artificial leather as claimed in claim 1 in which the nap fibril denier is from 0.5 to 0.05 denier and the nap fibril length is from 0.5 to 2.0 mm.
Claim 5
Dependent Claim 33 words
An artificial leather as claimed in claim 1 in which said substrate contains from more than 30 to 100% of said fibrillated composite filaments, and the remainder of said substrate is another filament.
Claim 6
Dependent Claim 17 words
An artificial leather as claimed in claim 1 in which said fabric is a raised tricot fabric.
Claim 7
Dependent Claim 40 words
An artificial leather as claimed in claim 4 in which said fabric is comprised of front yarns of from 30 to 80 denier and back yarns of 15 to 50 denier and smaller than the denier of the front yarns.
Claim 8
Dependent Claim 38 words
An artificial leather as claimed in claim 1 in which said microporous synthetic polymer is at least one polymer selected from the group consisting of polyurethane, polyamide polymers, vinyl chloride polymers, acrylic polymers, acrylonitrile-butadiene rubber, and styrene-butadiene rubber.
Claim 9
Dependent Claim 31 words
An artificial leather as claimed in claim 1, in which the cross-section of the fibrils constituting the naps have one of the shapes shown in FIGS. 10-18 of the attached drawings.
Claim 10
Dependent Claim 32 words
An artificial leather as claimed in claim 1, in which fine spaces are formed between said microporous synthetic polymer and the filaments constituting the substrate and the fibrils of the napped piles.
Claim 11
Dependent Claim 63 words
An artificial leather as claimed in claim 9 in which before said fabric has been impregnated with said microporous synthetic polymer, said shrunk fabric has been impregnated with from 3 to 30 percent by weight of a watersoluble substance selected from the group consisting of polyvinyl alcohol, carboxymethyl cellulose, gelatin, starch and methyl cellulose, and after said fabric has been impregnated with said
Claim 12
Dependent Claim 44 words
An artificial leather as claimed in claim 1, in which said filaments consist of (A), (B') and (C) and wherein (A) is from 10 to 30%, (C) is from 5 to 40% and (B') is the balance of the cross-sectional area of the filaments.

References Cited (Backward Citations)

US3117362A Cited
US3282721A Cited
US3706613A Cited
US3705226A Cited
US3814561A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-13 1981-08-15 1982-02-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-13 1985-08-15 1986-02-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-13 1989-08-15 1990-02-14 $7700.00 Window Closed / Lapsed

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