US4073877A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Manufacture of titanium dioxide pigment seed from a titanium sulfate solution
Assignee: Kronos Titan GmbH
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Filing: 1975-05-27
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Granted: 1978-02-14
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Expires: 1995-05-27
Abstract
Abstract The application is concerned with a process for the manufacture of a titanium dioxide pigment from a titanium sulfate solution by hydrolysis in the presence of nuclei. The latter may be formed externally from any suitable source of titanium sulfate solution and preferably, but not exclusively, from a portion of the titanium sulfate solution used in forming the hydrous TiO 2 ; the nuclei being prepared by mixing the titanium sulfate solution, from whatever source, simultaneously with an alkaline reacting solution and subsequently curing the mixture at elevated temperature. In the present application "titanium sulfate solution" is understood to be a solution which may also contain other substances besides titanium sulfate; and may be obtained, for example, by digestion of titaniferous ores or slags using sulfuric acid, followed by dissolution of the resulting digestion cake.
Inventors
- 👤 Edgar Klein
- 👤 Reinhard Kracke
- 👤 Walter Nespital
- 👤 Rudiger Paul, deceased
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 03:39
CPC Classifications
C; C01; C01G; C01G23/00; C01G23/04; C01G23/047; C01G23/053; C01G23/0532; C01G23/0534; C09; C09C; C09C1/00; C09C1/36; C01P; C01P2006/00; C01P2006/80
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
189 words
In a process for preparing nuclei for use in the manufacture of titanium dioxide pigment by hydrolysis of a titanium sulfate solution wherein the nuclei is formed by mixing a titanium sulfate solution with an alkaline-reacting substance followed by curing the mix at elevated temperature, the improvement comprising the steps of: first adding titanium sulfate solution to water at temperatures between room temperature and 80° C. and in amount to form a dilute, aqueous sulfate solution having a maximum TiO 2 concentration of about 5 gpl, admixing an alkaline-reacting solution with said dilute aqueous solution in an amount to form an acid mixture having a pH from 2.5 to 3.0, thereafter adding additional titanium sulfate solution and additional alkaline-reacting solution to said acid mixture, said additional titanium sulfate solution and said additional alkaline-reacting solution being added simultaneously at temperatures between 50° C. and 80° C., at rates sufficient to maintain the pH of the resulting mixture substantially constant within the range of from 2.5 to 3.0, and in amounts to achieve TiO 2 concentration of from 10 to 100 gpl TiO 2 , and thereafter curing the concentrated mixture.
Claim 2
Dependent Claim
189 words
In a process for preparing nuclei for use in the manufacture of titanium dioxide pigment by hydrolysis of a titanium sulfate solution wherein the nuclei is formed by mixing a titanium sulfate solution with an alkaline-reacting substance followed by curing the mix at elevated temperature, the improvement comprising the steps of: first adding titanium sulfate solution to water at temperatures between room temperature and 80° C. and in amount to form a dilute, aqueous sulfate solution having a maximum TiO 2 concentration of about 5 gpl, admixing an alkaline-reacting solution with said dilute aqueous solution in an amount to form an acid mixture having a pH from 2.5 to 3.0, thereafter adding additional titanium sulfate solution and additional alkaline-reacting solution to said acid mixture, said additional titanium sulfate solution and said additional alkaline-reacting solution being added simultaneously at temperatures between 50° C. and 80° C., at rates sufficient to maintain the pH of the resulting mixture substantially constant within the range of from 2.5 to 3.0, and in amounts to achieve TiO 2 concentration of from 10 to 100 gpl TiO 2 , and thereafter curing the concentrated mixture.
Claim 3
Dependent Claim
20 words
Process according to claim 1, characterized in that the concentrated mixture is cured at temperatures between 50° and 80° C.
Claim 4
Dependent Claim
30 words
Process according to claim 1, characterized in that the simultaneous addition of both solutions is carried out at 60° C and the concentrated mixture produced is cured at 60° C.
Claim 5
Dependent Claim
34 words
Process according to claim 1 characterized in that the titanium sulfate solution used for preparation of the nuclei is derived from the titanium sulfate solution used in the manufacture of the hydrous titanium dioxide.
Claim 6
Dependent Claim
17 words
Process according to claim 1, characterized in that a potassium hydroxide solution is employed as alkaline-reacting solution.
Claim 7
Dependent Claim
44 words
Process according to claim 1, characterized in that a titanium sulfate solution is employed which has a weight ratio of H 2 SO 4 to TiO 2 between 1.6 and 2.0 and a weight ratio of Fe to TiO 2 between 0.25 and 0.5.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-02-13 | 1981-08-15 | 1982-02-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-02-13 | 1985-08-15 | 1986-02-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-02-13 | 1989-08-15 | 1990-02-14 | $7700.00 | Window Closed / Lapsed |