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US4073777A
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Radiation crosslinkable polyester and polyesteramide compositions containing sulfonate groups in the form of a metallic salt and unsaturated groups
Assignee: Eastman Chemical Co
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Filing: 1975-01-17
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Granted: 1978-02-14
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Expires: 1995-01-17
Abstract
Abstract Radiation crosslinkable, water-dispersable polyesters and polyesteramides derived from monomer components which include dicarboxylic acids, poly(ethylene glycol), monomer components substituted with a sulfonate metal salt group and α,β-unsaturated acids. A typical polyester is composed of 80 mole parts of isophthalic acid, 10 mole parts of 4-carboxycinnamic acid, 10 mole parts of 5-sodiosulfoisophthalate, and 100 mole parts diethylene glycol. The polyesters and polyesteramides may also include monomer components such as hydroxycarboxylic acid, aminocarboxylic acid, aminoalcohol, glycol, diamine or combinations of such components. Such polymers are useful as adhesives, coating materials, films, packaging materials and other products. The polymers can be dissolved, dispersed or otherwise dissipated in water or aqueous solutions, dried and subsequently cured by radiation.
Inventors
- 👤 George J. O'Neill
- 👤 James G. Pacifici
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 23:04
CPC Classifications
C; C08; C08F; C08F299/00; C08F299/02; C08F299/04; C08F299/0478; C08F299/0407; C08F299/0421; C08F299/0428; C08G; C08G63/00; C08G63/68; C08G63/688; C08G63/6884; C08G63/6888; C08G69/00; C08G69/44; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
110 words
A linear, radiation crosslinkable, water-dissipatable polymer having carbonyloxy interconnecting groups in the linear molecular structure and having an inherent viscosity of at least about 0.1 measured in a 60/40 parts by weight solution of phenol/tetrachloroethane at 25° C. and at a concentration of about 0.25 gram of polymer in 100 ml. of said solvent, said polymer being prepared from components comprising: a. at least one unsubstituted saturated aliphatic, unsubstituted saturated cycloaliphatic or unsubstituted aromatic dicarboxylic acid combining no ethylene unsaturation; b. at least one difunctional glycol containing two --CH 2 --OH groups of which at least 15 mole percent is a poly(ethylene glycol) having the structural formula: H(OCH.sub.2 -CH.sub.2).sub.n OH
Claim 2
Dependent Claim
110 words
A linear, radiation crosslinkable, water-dissipatable polymer having carbonyloxy interconnecting groups in the linear molecular structure and having an inherent viscosity of at least about 0.1 measured in a 60/40 parts by weight solution of phenol/tetrachloroethane at 25° C. and at a concentration of about 0.25 gram of polymer in 100 ml. of said solvent, said polymer being prepared from components comprising: a. at least one unsubstituted saturated aliphatic, unsubstituted saturated cycloaliphatic or unsubstituted aromatic dicarboxylic acid combining no ethylene unsaturation; b. at least one difunctional glycol containing two --CH 2 --OH groups of which at least 15 mole percent is a poly(ethylene glycol) having the structural formula: H(OCH.sub.2 -CH.sub.2).sub.n OH
Claim 3
Dependent Claim
74 words
n being an integer in the range between about 2 and about 20; c. an amount sufficient to provide said water-dissipatable characteristic of said polymer of at least one difunctional sulfomonomer containing at least one metal sulfonate group attached to an aromatic nucleus wherein the functional groups are hydroxy, carboxyl or amino; d. an α,β-unsaturated acid having the formula: R--CH═CH--R.sup.1 wherein R is H, alkyl or arylcarboxy and R 1 is carboxy or arylcarboxy.
Claim 4
Dependent Claim
74 words
n being an integer in the range between about 2 and about 20; c. an amount sufficient to provide said water-dissipatable characteristic of said polymer of at least one difunctional sulfomonomer containing at least one metal sulfonate group attached to an aromatic nucleus wherein the functional groups are hydroxy, carboxyl or amino; d. an α,β-unsaturated acid having the formula: R--CH═CH--R.sup.1 wherein R is H, alkyl or arylcarboxy and R 1 is carboxy or arylcarboxy.
Claim 5
Dependent Claim
72 words
A linear, radiation crosslinkable, water dispersible polymer according to claim 1 which also contains up to 80 mole percent of a difunctional hydroxycarboxylic acid having one --CH 2 --OH group, an aminocarboxylic acid having one --NRH group, an amino-alcohol having one --CH 2 --OH group and one --NRH group, a diamine having two --NRH groups, or a mixture thereof, wherein each R is an H atom or a 1-4 carbon alkyl group.
Claim 6
Dependent Claim
36 words
A linear, crosslinkable polymer according to claim 2 wherein said difunctional sulfo-monomer (c) is a dicarboxylic acid which constitutes about 8 mole percent to about 50 mole percent, based on the sum of all acid equivalents.
Claim 7
Dependent Claim
41 words
A linear, crosslinkable water-dissipatable polymer according to claim 2 wherein said difunctional sulfo-monomer (c) is a glycol which constitutes about 8 mole percent to about 50 mole percent based on the sum of all the hydroxy or hydroxy and amino equivalents.
Claim 8
Dependent Claim
23 words
A linear, crosslinkable, water-dissipatable polymer according to claim 3 wherein said difunctional sulfo-monomer (c) is present in from 10 to 50 mole percent.
Claim 9
Dependent Claim
23 words
A linear, crosslinkable, water-dissipatable polymer according to claim 4 wherein said difunctional sulfo-monomer (c) is present in from 10 to 50 mole percent.
Claim 10
Dependent Claim
31 words
A linear, crosslinkable, water-dispersible polymer according to claim 2 wherein said difunctional sulfo-monomer (c) is an aromatic dicarboxylic acid and the metal sulfonate group is attached to the aromatic nucleus thereof.
Claim 11
Dependent Claim
35 words
A linear, crosslinkable, water-dispersible polymer according to claim 7 wherein the metal of the sulfonate group is selected from the group consisting of Na, Li, K, Mg, Ca, Ba, Cu, Ni, Fe, and mixtures thereof.
Claim 12
Dependent Claim
27 words
A linear, crosslinkable, water-dispersible polymer according to claim 2 wherein said difunctional sulfo-monomer (c) is isophthalic acid containing a metal sulfonate group attached to the aromatic ring.
Claim 13
Dependent Claim
21 words
A linear, crosslinkable, water-dispersible polymer according to claim 9 wherein said difunctional sulfo-monomer (c) is isophthalic acid containing a sodiosulfonate group.
Claim 14
Dependent Claim
22 words
A linear, crosslinkable, water-dispersible polymer according to claim 10 wherein said sodiosulfonate group is attached to the isophthalic acid in the 5-position.
Claim 15
Dependent Claim
41 words
A linear, crosslinkable water-dispersible polymer according to claim 11 comprising the reaction product of: a. at least 80 mole percent isophthalic acid; b. diethylene glycol; c. about 10 mole percent 5-sodiosulfoisophthalic acid; and d. at least 5 mole percent acrylic acid.
Claim 16
Dependent Claim
41 words
A linear, crosslinkable, water-dispersible polymer according to claim 11 comprising the reaction product of: a. at least 80 mole percent isophthalic acid; b. diethylene glycol; c. about 10 mole percent 5-sodiosulfoisophthalic acid; and d. at least 5 mole percent methacrylic acid.
Claim 17
Dependent Claim
43 words
A linear, crosslinkable, water-dispersible polymer according to claim 11 comprising the reaction product of: a. about 80 mole percent isophthalic acid; b. about 100 mole percent diethylene glycol; c. about 10 mole percent 5-sodiosulfoisophthalic acid; and d. about 10 mole percent 4-carboxycinnamic acid.
Claim 18
Dependent Claim
43 words
A linear, crosslinkable, water-dispersible polymer according to claim 11 comprising the reaction product of: a. about 80 mole percent isophthalic acid; b. about 100 mole percent diethylene glycol; c. about 10 mole percent 5-sodiosulfoisophthalic acid; and d. about 10 mole percent 4,4'-stilbenedicarboxylic acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-02-13 | 1981-08-15 | 1982-02-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-02-13 | 1985-08-15 | 1986-02-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-02-13 | 1989-08-15 | 1990-02-14 | $7700.00 | Window Closed / Lapsed |