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US4073775A Expired / Lapsed US ⏱️ 0.0 years remaining

Powder coating composition

Assignee: Asahi Kasei Corp
•
Filing: 1976-06-08
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Granted: 1978-02-14
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Expires: 1996-06-08
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Abstract

Abstract A thermosetting powder coating composition having good handling characteristics and capable of being baked under relatively mild conditions and providing a coating having practically satisfactory properties. This coating composition is prepared by incorporating in 100 parts by weight of an epoxy group-containing acrylic or methacrylic copolymer having a glass transition point of 30° to 90° C. and a weight average molecular weight of 2,500 to 30,000, said copolymer consisting of 3 to 35% by weight of acrylate or methacrylate monomer units and 97 to 65% by weight of ethylenically unsaturated monomer units, 3 to 40 parts by weight of a specific diphenol having at its both terminals hydroxybenzoic acid ester structures as represented by the general formula: ##STR1## wherein R 3 stands for a hydrocarbon radical having 2 to 20 carbon atoms or a linking group containing, at least at its both terminals, hydrocarbon radicals and in its main chain at least one member selected from the group consisting of an ether linkage, ester linkage, urethane linkage and amide linkage, and having totally 4 to 20 carbon atoms. Especially good results are obtained when a specific phenol compound containing in the molecule one phenolic hydroxyl group and either one carboxyl group or one hydroxyl group, or a specific benzoic acid compound containing in the molecule two carboxylic acid groups are further incorporated in this powder coating composition.

Inventors

  • 👤 Shunji Matsuo
  • 👤 Kiichiro Sasaguri
  • 👤 Katsuyuki Nakamura
  • 👤 Yoshio Matsumoto
  • 👤 Mikio Sato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:19
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/068; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/32; C08G59/3209; C08G59/40; C08G59/62; C08G59/625; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/13; C09D125/00; C09D125/02; C09D125/04; C09D125/08; C09D125/14; C09D133/18; C09D133/20

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 54 words
A powder coating composition comprising (A) 100 parts by weight of an epoxy group-containing copolymer of 1. from 3 to 35% by weight, based on said copolymer, of a monomer represented by the following general formula ##STR37## wherein R 1 and R 2 stand for a hydrogen atom or a methyl group, and 2.
Claim 2
Dependent Claim 54 words
A powder coating composition comprising (A) 100 parts by weight of an epoxy group-containing copolymer of 1. from 3 to 35% by weight, based on said copolymer, of a monomer represented by the following general formula ##STR37## wherein R 1 and R 2 stand for a hydrogen atom or a methyl group, and 2.
Claim 3
Dependent Claim 109 words
from 97 to 65% by weight of an ethylenically unsaturated monomer selected from the group consisting of acrylic acid esters, methacrylic acid esters, acrylonitrile, methacrylonitrile, styrene, vinyltoluene and α-methylstyrene, said copolymer having a glass transition point of 30° to 90° C, and (B) 3 to 40 parts by weight of at least one of compounds represented by the general formula ##STR38## wherein R 3 stands for a hydrocarbon radical having 2 to 20 carbon atoms or a linking group containing, at least at its both terminals, hydrocarbon radicals and in its main chain at least one member selected from the group consisting of an ether linkage, ester linkage, urethane
Claim 4
Dependent Claim 109 words
from 97 to 65% by weight of an ethylenically unsaturated monomer selected from the group consisting of acrylic acid esters, methacrylic acid esters, acrylonitrile, methacrylonitrile, styrene, vinyltoluene and α-methylstyrene, said copolymer having a glass transition point of 30° to 90° C, and (B) 3 to 40 parts by weight of at least one of compounds represented by the general formula ##STR38## wherein R 3 stands for a hydrocarbon radical having 2 to 20 carbon atoms or a linking group containing, at least at its both terminals, hydrocarbon radicals and in its main chain at least one member selected from the group consisting of an ether linkage, ester linkage, urethane
Claim 5
Dependent Claim 38 words
linkage and amide linkage, and having totally 4 to 20 carbon atoms. 2. A powder coating composition according to claim 1 wherein in said compound (B), R 3 is a hydrocarbon radical having 2 to 10 carbon atoms.
Claim 6
Dependent Claim 24 words
A powder coating composition according to claim 1 wherein the compound (B) is employed in an amount of 10 to 40 parts by weight.
Claim 7
Dependent Claim 21 words
A powder coating composition according to claim 1 wherein said compound (B) has at its both terminals p-hydroxybenzoic acid ester structures.
Claim 8
Dependent Claim 32 words
A powder coating composition according to claim 1 which further comprises a compound represented by the formula ##STR39## wherein R 7 stands for a hydrocarbon radical having 2 to 20 carbon atoms.
Claim 9
Dependent Claim 53 words
A powder coating composition according to claim 1 which further comprises a compound represented by the general formula ##STR40## wherein R 8 stands for an alkylene, polyoxyalkylene or cycloalkylene group having 2 to 10 carbon atoms and R 9 stands for an arylene, alkylene or cycloalkylene group having 2 to 20 carbon atoms.
Claim 10
Dependent Claim 42 words
A powder coating composition according to claim 1 which further comprises a compound represented by the general formula ##STR41## wherein R 10 stands for an alkylene having 1 to 20 carbon atoms and y stands for an integer of at least 1.
Claim 11
Dependent Claim 36 words
A powder coating composition according to claim 1 which further comprises a compound represented by the general formula ##STR42## wherein R 11 stands for an alkyl, cycloalkyl or polyoxyalkyl group having 1 to 10 carbon atoms.
Claim 12
Dependent Claim 33 words
A powder coating composition according to claim 1 which further comprises a compound represented by the general formula ##STR43## wherein R 12 stands for a hydrocarbon radical having 2 to 10 carbon atoms.
Claim 13
Dependent Claim 65 words
A powder coating composition according to claim 1 wherein said copolymer (A) has a glass transition point of 40° to 75° C and comprises 10 to 25 parts by weight of a glycidyl methacrylate monomer and 90 to 75 parts by weight of an ethylenically unsaturated monomer selected from the group consisting of acrylic acid esters, methacrylic acid esters, acrylonitrile, methacrylonitrile, styrene, vinyltoluene and α-methylstyrene.

References Cited (Backward Citations)

US2934521A Cited
US2947717A Cited
US2935488A Cited
US3509230A Cited
US3753917A Cited
US3752870A Cited
US3758634A Cited
US3781380A Cited
US3787520A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-13 1981-08-15 1982-02-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-13 1985-08-15 1986-02-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-13 1989-08-15 1990-02-14 $7700.00 Window Closed / Lapsed

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