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US4072776A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the flameproofing of textile materials

Assignee: Hoechst AG
•
Filing: 1975-10-10
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Granted: 1978-02-07
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Expires: 1995-10-10
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Abstract

Abstract A process for the flameproofing of fiber material, which comprises applying (meth-)acrylic acid-alkyl-esters of the general formula ##STR1## in which n and m are 0 or 1 and (n+m) are 0 or 1, and R 1 stands for a saturated or unsaturated aliphatic hydrocarbon radical having from 1 to 8, preferably from 1 to 4 carbon atoms, which radical may also be substituted, preferably mono-substituted, by chlorine, bromine, the nitrile group, or the radicals --OR 4 or --COOR 4 , R 2 has the same meaning as R 1 and -- for n= 0 and m= 1 -- may also be a group of the formula ##STR2## Z, Z 1 , Z 2 represent straight-chain or branched (C 1 -C 3 )-alkylene radicals which may also be substituted, preferably mono-substituted, by chlorine, bromine or the hydroxy group, X stands for a hydrogen, a chlorine or a bromine atom, a hydroxy or a methyl group, R 3 represents a hydrogen atom or a methyl group, and R 4 is a hydrogen atom or an alkyl group having from 1 to 8 carbon atoms, and R 5 is a hydrogen atom, the methyl or the chloromethyl group, onto the fiber material, the said (meth-)acrylic acid-alkyl-esters being dissolved in an inert solvent, and subjecting the latter substances to a polymerization by using radicals.

Inventors

  • 👤 Fritz Linke
  • 👤 Walter Dursch
  • 👤 Hans-Jerg Kleiner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 02:46
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/10; D06M13/184; D06M13/203; D06M14/00; Y; Y10; Y10S; Y10S260/00; Y10S260/24; Y10T; Y10T442/00; Y10T442/20; Y10T442/2631; Y10T442/2672; Y10T442/2697

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 220 words
A process for the flameproofing of fiber material, which comprises applying (meth-)acrylic acid-alkyl-esters of the general formula ##STR28## in which n and m and 0 or 1 and (n+m) are 0 or 1, and R 1 stands for a saturated or unsaturated aliphatic hydrocarbon radical having from 1 to 8, preferably from 1 to 4 carbon atoms, which radical may also be substituted, preferably mono-substituted, by chlorine, bromine, the nitrile group, or the radicals --OR 4 or --COOR 4 , R 2 has the same meaning as R 1 and if n is 0 and m is 1 may also be a group of the formula ##STR29## Z, Z 1 , Z 2 represent straight-chain or branched (C 1 -C 3 )-alkylene radicals which may also be substituted, preferably mono-substituted, by chlorine, bromine or the hydroxy group, X stands for a hydrogen, a chlorine or a bromine atom, a hydroxy or a methyl group, R 3 represents a hydrogen atom or a methyl group, and R 4 is a hydrogen atom or an alkyl group having from 1 to 8 carbon atoms, and R 5 is a hydrogen atom, the methyl or the chloromethyl group, onto the fiber material, the said (meth-)acrylic acid-alkyl-esters being dissolved in an inert solvent, and subjecting the latter substances to a polymerization by using radicals.
Claim 2
Dependent Claim 220 words
A process for the flameproofing of fiber material, which comprises applying (meth-)acrylic acid-alkyl-esters of the general formula ##STR28## in which n and m and 0 or 1 and (n+m) are 0 or 1, and R 1 stands for a saturated or unsaturated aliphatic hydrocarbon radical having from 1 to 8, preferably from 1 to 4 carbon atoms, which radical may also be substituted, preferably mono-substituted, by chlorine, bromine, the nitrile group, or the radicals --OR 4 or --COOR 4 , R 2 has the same meaning as R 1 and if n is 0 and m is 1 may also be a group of the formula ##STR29## Z, Z 1 , Z 2 represent straight-chain or branched (C 1 -C 3 )-alkylene radicals which may also be substituted, preferably mono-substituted, by chlorine, bromine or the hydroxy group, X stands for a hydrogen, a chlorine or a bromine atom, a hydroxy or a methyl group, R 3 represents a hydrogen atom or a methyl group, and R 4 is a hydrogen atom or an alkyl group having from 1 to 8 carbon atoms, and R 5 is a hydrogen atom, the methyl or the chloromethyl group, onto the fiber material, the said (meth-)acrylic acid-alkyl-esters being dissolved in an inert solvent, and subjecting the latter substances to a polymerization by using radicals.
Claim 3
Dependent Claim 121 words
A process as claimed in claim 1 wherein a (meth-)acrylic acid-alkyl ester of the formula ##STR30## is used, in which n and m are 0 or 1 and (n+m) are 0 or 1, and R 1 is saturated or unsaturated alkyl with 1 to 4 carbon atoms, R 2 has the same meaning as R 1 and --for n = 0 and m = 1--may also be a group of the formula ##STR31## Z, Z 1 , Z 2 are straight-chain or branched (C 1 -C 3 )-alkylene which may be substituted, preferably mono-substituted, by chlorine, bromine or hydroxy, X is hydrogen, chlorine, bromine, hydroxy or methyl, R 3 is hydrogen or methyl, and R 5 is hydrogen, methyl or chloro-methyl.
Claim 4
Dependent Claim 13 words
A process as claimed in claim 1 wherein the insert solvent is water.
Claim 5
Dependent Claim 27 words
A process as claimed in claim 1 which comprises effecting the polymerization by using radicals at a temperature in the range of from 80° to 180° C.
Claim 6
Dependent Claim 19 words
A process as claimed in claim 1 which comprises adding compounds having a cross-linking effect to the impregnation bath.
Claim 7
Dependent Claim 16 words
A process as claimed in claim 1 which comprises adding plastic dispersions to the impregnation baths.

References Cited (Backward Citations)

US3695925A Cited
US3855359A Cited
US3854989A Cited
US3817779A Cited
US3830769A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-06 1981-08-08 1982-02-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-06 1985-08-08 1986-02-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-06 1989-08-08 1990-02-07 $7700.00 Window Closed / Lapsed

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