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US4072649A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of foundry cores and molds

Assignee: Bayer AG
•
Filing: 1975-08-07
•
Granted: 1978-02-07
•
Expires: 1995-08-07
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Abstract

Abstract Foundry cores and molds are produced from foundry sand and/or other inert fillers, polyhydroxyl compounds, polyisocyanates and tertiary amine catalysts. The precatalyzed mixtures can be stored for long periods of time without any adverse effects on the subsequent processing or core properties when at least 80% by weight of the polyisocyanate used is of the diphenyl alkane series in which the isocyanate groups are sterically hindered solely by substituents in at least one ortho position.

Inventors

  • 👤 Rolf Kubens

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 16:59
CPC Classifications
B; B22; B22C; B22C1/00; B22C1/16; B22C1/20; B22C1/22; B22C1/2233; B22C1/2273; B22C1/162; C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/74; C08G18/76; C08G18/7657; C08G18/7664

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 64 words
In a process for the production of foundry cores and molds wherein a mixture of inert fillers, polyhydroxyl compounds, polyisocyanates and tertiary amines is cured in a mold, the improvement wherein at least 80% by weight of the polyisocyanate component used consists of polyisocyanates of the diphenyl alkane series which solely contain isocyanate groups sterically hindered by substituents in at least one ortho position.
Claim 2
Dependent Claim 64 words
In a process for the production of foundry cores and molds wherein a mixture of inert fillers, polyhydroxyl compounds, polyisocyanates and tertiary amines is cured in a mold, the improvement wherein at least 80% by weight of the polyisocyanate component used consists of polyisocyanates of the diphenyl alkane series which solely contain isocyanate groups sterically hindered by substituents in at least one ortho position.
Claim 3
Dependent Claim 16 words
The process of claim 1 wherein at least 90% of said sterically hindered polyisocyanate is used.
Claim 4
Dependent Claim 14 words
The process of claim 1 wherein said sterically hindered polyisocyanate is 4,4'-diisocyanato-3,3'-dimethyl diphenyl methane.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein said polyhydroxyl compound is a phenol resin containing hydroxyl groups.
Claim 6
Dependent Claim 12 words
The process of claim 1 wherein said inert filler is foundry sand.
Claim 7
Dependent Claim 14 words
The process of claim 1 wherein the NCO/OH ratio is between 2:1 and 1:2.
Claim 8
Dependent Claim 11 words
The process of claim 1 wherein the NCO/OH ratio is 1:1.
Claim 9
Dependent Claim 55 words
The process of claim 1 wherein said polyisocyanate is ##STR4## where R 1 represents an aliphatic hydrocarbon radical having from 1 to 4 carbon atoms, R 2 and R 3 are the same or different and represent hydrogen or the radical R 1 , and n is 0 or an integer from 1 to 8.
Claim 10
Dependent Claim 21 words
The process of claim 8 wherein R 1 = methyl, R 2 and R 3 = hydrogen and n = 0.
Claim 11
Dependent Claim 15 words
The process of claim 8 wherein n is an integer of from 1 to 3.

References Cited (Backward Citations)

US3180883A Cited
US3403721A Cited
US3499861A Cited
US3428110A Cited
US3676392A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-06 1981-08-08 1982-02-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-06 1985-08-08 1986-02-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-06 1989-08-08 1990-02-07 $7700.00 Window Closed / Lapsed

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