US4071600A — Process for improved 3-way emission control

Claim 1

Independent Claim 130 words

A process for improved three-way stiochiometric type automotive emissions control comprising the steps of contacting the emissions stream with a first catalyst consisting of rhodium supported on a refractory substrate to effect the selective chemical reduction of nitric oxide to nitrogen, said rhodium being present in an amount of at least about 0.002% by weight of the catalyst, said emissions stream being then contacted with a second catalyst separated from said first catalyst and consisting of at least one of the noble metals selected from the group of platinum and palladium, said noble metal being present in a small but effective amount to accomplish the oxidation of the hydrocarbons and carbon monoxide left in said emissions stream, said process being accomplished without the addition of oxygen to said emissions stream.

Claim 2

Dependent Claim 130 words

A process for improved three-way stiochiometric type automotive emissions control comprising the steps of contacting the emissions stream with a first catalyst consisting of rhodium supported on a refractory substrate to effect the selective chemical reduction of nitric oxide to nitrogen, said rhodium being present in an amount of at least about 0.002% by weight of the catalyst, said emissions stream being then contacted with a second catalyst separated from said first catalyst and consisting of at least one of the noble metals selected from the group of platinum and palladium, said noble metal being present in a small but effective amount to accomplish the oxidation of the hydrocarbons and carbon monoxide left in said emissions stream, said process being accomplished without the addition of oxygen to said emissions stream.

Claim 3

Dependent Claim 140 words

A process for improved three-way control of an automotive exhaust stream having a composition which fluctuates from rich to lean about its stoichiometric composition comprising the steps of first contacting said exhaust stream with a catalyst consisting of rhodium supported on alumina to effect the chemical reduction of nitric oxide to nitrogen, said rhodium being present in an amount as small as about 0.002% by weight of the catalyst, then contacting said exhaust stream with a second catalyst to oxidize the hydrocarbons and carbon monoxide remaining in said exhaust stream, said second catalyst being separated from said first catalyst and consisting of at least one of the noble metals platinum and palladium supported on alumina in an amount of at least about 0.05% by weight of said catalyst, the addition of oxygen between said first and second catalyst being omitted.

Claim 4

Dependent Claim 140 words

A process for improved three-way control of an automotive exhaust stream having a composition which fluctuates from rich to lean about its stoichiometric composition comprising the steps of first contacting said exhaust stream with a catalyst consisting of rhodium supported on alumina to effect the chemical reduction of nitric oxide to nitrogen, said rhodium being present in an amount as small as about 0.002% by weight of the catalyst, then contacting said exhaust stream with a second catalyst to oxidize the hydrocarbons and carbon monoxide remaining in said exhaust stream, said second catalyst being separated from said first catalyst and consisting of at least one of the noble metals platinum and palladium supported on alumina in an amount of at least about 0.05% by weight of said catalyst, the addition of oxygen between said first and second catalyst being omitted.

Claim 5

Dependent Claim 43 words

A process in accordance with claim 2 wherein said rhodium catalyst is pre-treated by thermal aging in air for about 24 hours at a temperature of about 900° C to decrease the amount of ammonia formation during contact of the exhaust stream therewith.

Claim 6

Dependent Claim 123 words

The process of reducing the nitrogen oxide content of an automotive exhaust gas stream and oxidizing the carbon monoxide and hydrocarbons content thereof, without producing substantial quantities of ammonia, characterized by the step of passing the gas stream through a first bed having rhodium as the catalytically effective material and then, without the addition of oxygen, through a second bed having at least one of the nobel metals platinum and palladium as the predominant catalytically effective material, the amount of rhodium contacted by the gas stream in the first bed being about 4 to 10% by weight of the amount of platinum metal and about 10 to 25% by weight of palladium metal being contacted by the gas stream in the second bed.

Claim 7

Dependent Claim 123 words

The process of reducing the nitrogen oxide content of an automotive exhaust gas stream and oxidizing the carbon monoxide and hydrocarbons content thereof, without producing substantial quantities of ammonia, characterized by the step of passing the gas stream through a first bed having rhodium as the catalytically effective material and then, without the addition of oxygen, through a second bed having at least one of the nobel metals platinum and palladium as the predominant catalytically effective material, the amount of rhodium contacted by the gas stream in the first bed being about 4 to 10% by weight of the amount of platinum metal and about 10 to 25% by weight of palladium metal being contacted by the gas stream in the second bed.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1981-01-30	1981-08-01	1982-01-31	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1985-01-30	1985-08-01	1986-01-31	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1989-01-30	1989-08-01	1990-01-31	$7700.00	Window Closed / Lapsed

Process for improved 3-way emission control

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