Triboelectrically controlled covalently dyed toner materials

Claim 2

An electrostatographic toner composition for use in developing electrostatic latent images on a recording surface, said toner composition comprising finely-divided toner particles having an average particle diameter of less than about 30 microns, said toner particles comprising an aminolyzed polymer selected from the group consisting of styrenealkylmethacrylate and styrene-alkylacrylate, said polymer being covalently bonded with a reactive dye wherein said toner particles are characterized as possessing controlled triboelectric charging properties provided by the controlled aminolysis of said polymer, and wherein said dye is substantially metabolically inaccessible.

Claim 3

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer is obtained by systematic aminolysis of the pendant ester functions of said polymer to provide structural-triboelectric property relationships in said aminolyzed polymer.

Claim 4

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer is provided by varying the degree of aminolysis of said polymer stoichiometrically.

Claim 5

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer is provided by varying the degree of aminolysis of said polymer kinetically.

Claim 6

An electrostatographic toner composition in accidance with claim 1 wherein said controlled triboelectric properties of said toner particles are a function of the molecular structure of said aminolyzed polymer.

Claim 7

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer is the product of aminolysis with aminoalcohols of pendant ester functions of said polymer.

Claim 8

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer comprises a polymer having aromatic groups selected from electron releasing and electron withdrawing substituents.

Claim 9

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer has the general structure ##STR2## where X may be NH 2 , OH, NHCOC 6 H 4 R, OCOC 6 H 4 R and H, and wherein R may be an electron donating or an electron releasing substituent.

Claim 10

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer has reactive sites for covalent attachment of triboelectric charge modifiers.

Claim 11

An electrostatographic toner composition in accordance with claim 1 wherein said reactive dye contains chlorotriazinyl moieties.

Claim 12

An electrostatographic toner composition in accordance with claim 1 wherein said toner composition is obtained by direct polymerization to provide said reactive dye in the polymer backbone of said aminolyzed polymer.

Claim 13

An electrostatographic toner composition in accordance with claim 1 wherein said toner composition is obtained by direct polymerization with said dye pendent.

Claim 14

An electrostatographic toner composition in accordance with claim 1 wherein said toner composition is obtained by post polymerization attachment of said reactive dye.

Claim 15

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer contains 6-hydroxyhexylamide moieties.

Claim 16

An electrostatographic toner composition in accordance with claim 1 wherein said aminolyzed polymer contains 6-aminohexylamide side chains.

Claim 17

An electrostatographic toner composition in accordance with claim 1 wherein said polymer has been chemically modified by aminolysis of its ester groups with diamines to provide N-(aminoalkyl) carboxamide side chains in said aminolyzed polymer.

Claim 18

An electrostatographic developer mixture comprising finely-divided toner particles electrostatically clining to the surface of carrier particles, said carrier particles having an average particle diameter between about 50 microns and about 1,000 microns, and said toner particles having an average particle diameter of less than about 30 microns, said toner particles comprising an aminolyzed polymer selected from the group consisting of styrene-alkylmethacrylate and styrene-alkylacrylate, said polymer being covalently bonded with a reactive dye wherein said toner particles are characterized as possessing controlled triboelectric charging properties provided by the controlled aminolysis of said polymer, and said dye is substantially metabolically inaccessible in said toner particles.

Claim 19

An electrostatographic developer mixture comprising finely-divided toner particles electrostatically clining to the surface of carrier particles, said carrier particles having an average particle diameter between about 50 microns and about 1,000 microns, and said toner particles having an average particle diameter of less than about 30 microns, said toner particles comprising an aminolyzed polymer selected from the group consisting of styrene-alkylmethacrylate and styrene-alkylacrylate, said polymer being covalently bonded with a reactive dye wherein said toner particles are characterized as possessing controlled triboelectric charging properties provided by the controlled aminolysis of said polymer, and said dye is substantially metabolically inaccessible in said toner particles.

Claim 20

A process for preparing an electrostatographic toner composition for use in developing electrostatic latent images on a recording surface, said process comprising covalently bonding an amonlyzed polymer selected from the group consisting of styrene-alkylmethacrylate and styrenealkylacrylate having pendant reactive sites with a reactive dye, and reducing the average particle diameter of the product to less than about 30 microns to provide toner particles characterized as possessing controlled triboelectric charging properties and wherein said reactive dye is substantially metabolically inaccessible.

Claim 21

A process for preparing an electrostatographic toner composition for use in developing electrostatic latent images on a recording surface, said process comprising covalently bonding an amonlyzed polymer selected from the group consisting of styrene-alkylmethacrylate and styrenealkylacrylate having pendant reactive sites with a reactive dye, and reducing the average particle diameter of the product to less than about 30 microns to provide toner particles characterized as possessing controlled triboelectric charging properties and wherein said reactive dye is substantially metabolically inaccessible.