US4069244A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Fluorinated amphoteric and cationic surfactants
Assignee: Novartis Corp
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Filing: 1975-01-03
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Granted: 1978-01-17
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Expires: 1995-01-03
Abstract
Abstract The invention is directed to fluorinated compounds of the formula ##STR1## wherein R f is a perfluoroalkyl or perfluoroalkoxy-perfluoroalkyl group, R 1 is a branched or straight chain alkylene, alkylenethioalkylene, alkyleneoxyalkylene or alkyleneiminoalkylene group, X is oxygen or an amino group, Q is an organic group containing at least one amino group and y is zero or 1, and the corresponding succinimides. These compounds are useful as surfactants.
Inventors
- 👤 Karl Friedrich Mueller
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 20:46
CPC Classifications
C; C07; C07D; C07D207/00; C07D207/02; C07D207/30; C07D207/34; C07D207/36; C07D207/40; C07D207/416; C07D213/00; C07D213/02; C07D213/04; C07D213/06; C07D213/16; C07D213/20; C07D213/24; C07D213/36; C07D213/38; C07D213/60; C07D213/72; C07D213/75; C07D215/00; C07D215/02; C07D215/12; C07D215/14; C07D215/16; C07D215/38; C07D239/00; C07D239/02; C07D239/24; C07D239/28; C07D239/32; C07D239/42; C07D295/00; C07D295/04; C07D295/12; C07D295/125; C07D295/13; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/03; Y10S516/04; Y10S516/05; Y10S516/06; Y10S516/07
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
149 words
A compound of the formula ##STR71## or its amphoteric tautomer or of the formula ##STR72## or its amphoteric tautomer or a mixture thereof wherein R f is straight or branched chain perfluoroalkyl of 1 to 18 carbon atoms or said perfluoroalkyl substituted by perfluoroalkoxy of 2 to 6 carbon atoms; R 1 is branched or straight chain alkylene of 1 to 12 carbon atoms; Y is 1 or zero; R is hydrogen, alkyl of 1 to 6 carbon atoms or hydroxyalkyl of 1 to 6 carbon atoms, and Q is an aliphatic amino group of the formula ##STR73## wherein R 2 is a linear or branched alkylene of 2 to 12 carbon atoms; k is 1 or zero; R 3 and R 4 are independently of each other hydrogen, alkyl of 1 to 20 carbon atoms or said alkyl substituted by an alkyl group of 1 to 5 carbons.
Claim 2
Dependent Claim
149 words
A compound of the formula ##STR71## or its amphoteric tautomer or of the formula ##STR72## or its amphoteric tautomer or a mixture thereof wherein R f is straight or branched chain perfluoroalkyl of 1 to 18 carbon atoms or said perfluoroalkyl substituted by perfluoroalkoxy of 2 to 6 carbon atoms; R 1 is branched or straight chain alkylene of 1 to 12 carbon atoms; Y is 1 or zero; R is hydrogen, alkyl of 1 to 6 carbon atoms or hydroxyalkyl of 1 to 6 carbon atoms, and Q is an aliphatic amino group of the formula ##STR73## wherein R 2 is a linear or branched alkylene of 2 to 12 carbon atoms; k is 1 or zero; R 3 and R 4 are independently of each other hydrogen, alkyl of 1 to 20 carbon atoms or said alkyl substituted by an alkyl group of 1 to 5 carbons.
Claim 3
Dependent Claim
36 words
A compound of claim 1 represented by formula I or II wherein R 1 is alkylene Q is an aliphatic amino group of the formula ##STR74## where R 3 and R 4 are hydrogen or alkyl.
Claim 4
Dependent Claim
37 words
A compound of claim 1 wherein R 2 is straight or branched chain alkylene of 2 to 5 carbon atoms, Y is zero, R 3 and R 4 are each alkyl group of 1 to 5 carbons.
Claim 5
Dependent Claim
20 words
A compound of claim 3 wherein R 1 is ethylene and R 3 and R 4 are methyl or ethyl.
Claim 6
Dependent Claim
48 words
A compound of claim 4 of formula I or II wherein R f is C 8 F 17 --, R is H--, R 2 is --CH 2 -- 3 , k is one and R 3 and R 4 are each CH 3 --, or a mixture thereof.
Claim 7
Dependent Claim
77 words
A compound of claim 4 of formula I or II wherein about 25% of R f are perfluoroalkyl groups of 6 carbon atoms, about 50% of R f are perfluoroalkyl groups of 8 carbon atoms and about 25% of R f are perfluoroalkyl groups of 10 carbon atoms, R is H--, R 2 is --CH 2 -- 3 , k is one and R 3 and R 4 are each CH 3 --, or a mixture thereof.
Claim 8
Dependent Claim
40 words
A compound of claim 4 of formula I or II wherein R f is C 8 F 17 --, R is H--, k is zero, and R 3 and R 4 are each CH 3 --, or a mixture thereof.
Claim 9
Dependent Claim
50 words
A compound of claim 4 of formula I or II wherein R f is C 8 F 17 --, R is H--, R 2 is --CH 2 -- 2 , k is one and R 3 and R 4 are each C 2 H 5 --, or a mixture thereof.
Claim 10
Dependent Claim
50 words
A compound of claim 4 of formula I or II wherein R f is C 8 F 17 --, R is CH 3 --, R 2 is --CH 2 -- 3 , k in one and R 3 and R 4 are each CH 3 --, or a mixture thereof.
Claim 11
Dependent Claim
48 words
A compound of claim 4 of formula I or II wherein R f is C 8 F 17 --, R is H--, R 2 is --CH 2 -- 2 , k is one and R 3 and R 4 are each CH 3 --, or a mixture thereof.
Claim 12
Dependent Claim
78 words
A compound of claim 4 of formula I or II wherein about 25% of R f are perfluoroalkyl groups of 6 carbon atoms, 50% of R f are perfluoroalkyl groups of 8 carbon atoms and about 25% of R f are perfluoroalkyl groups of 10 carbon atoms, R is CH 3 --, R 2 is --CH 2 CH 2 --, k is one and R 3 and R 4 are each CH 3 --, or a mixture thereof.
Claim 13
Dependent Claim
80 words
A compound of claim 4 of formula I or II wherein about 25% of R f are perfluoroalkyl groups of 6 carbon atoms, 50% of R f are perfluoroalkyl groups of 8 carbon atoms and about 25% of R f are perfluoroalkyl groups of 10 carbon atoms, R is C 2 H 5 --, R 2 is --CH 2 CH 2 --, k is one and R 3 and R 4 are each CH 3 --, or a mixture thereof.
Claim 14
Dependent Claim
36 words
A compound of claim 1 wherein R' is ethylene, y is zero, R is hydrogen, R 2 is ethylene, k is one and R 3 and R 4 are each methyl, or a mixture of isomers.
References Cited (Backward Citations)
US3471518A
Cited
US3839425A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-01-16 | 1981-07-18 | 1982-01-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-01-16 | 1985-07-18 | 1986-01-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-01-16 | 1989-07-18 | 1990-01-17 | $7700.00 | Window Closed / Lapsed |