US4069029A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process and apparatus for producing and using cold ammonia
Assignee: LaRoche Industries Inc
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Filing: 1976-09-27
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Granted: 1978-01-17
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Expires: 1996-09-27
Abstract
Abstract Cold ammonia, preferably cold liquid anhydrous ammonia at substantially ambient or atmospheric pressure is applied (1) to the soil as a fertilizer and (2) to feed grains, forages and anaerobically fermentable plant material to supply thereto and provide therein non-protein nitrogen (NPN). The cold ammonia is obtained by (1) introducing a stream of ambient temperature, pressurized liquid ammonia at a velocity of at least about 5000 feet per minute into an expansion chamber, (2) imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia formed in the chamber. Cold ammonia, which is predominantly in the liquid form, is recovered from the expansion chamber operated under substantially adiabatic conditions, at a temperature of about -28 DEG F.
Inventors
- 👤 John William Hudson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 00:43
CPC Classifications
C; C05; C05C; C05C3/00; A; A01; A01C; A01C23/00; A01C23/02; A01C23/023; A01C23/024; A01F; A01F25/00; A23; A23K; A23K50/00; A23K50/10; A23K50/15; F; F17; F17C; F17C7/00; F17C7/02; F17C7/04; F17C2201/00; F17C2201/01; F17C2201/0104; F17C2201/0119; F17C2201/05; F17C2201/054; F17C2205/00; F17C2205/01; F17C2205/0153; F17C2205/0157; F17C2205/0161; F17C2205/03; F17C2205/0302; F17C2205/0323; F17C2205/0352; F17C2205/0364; F17C2221/00; F17C2221/01; F17C2221/014; F17C2223/00; F17C2223/01; F17C2223/0146; F17C2223/0153; F17C2223/0161; F17C2250/00; F17C2250/06; F17C2250/0605; F17C2250/0636; F17C2265/00; F17C2265/01; F17C2265/015; F17C2270/00; F17C2270/01; F17C2270/0165; F17C2270/0168; Y; Y10; Y10S; Y10S111/00; Y10S111/925
Claims Analysis
Total Claims: 36
Claim 1
Independent Claim
255 words
A method for carrying out the substantially adiabatic expansion of a pressurized stream of ambient-temperature liquid ammmonia to produce a stream of cold liquid ammonia at substantially ambient or atmospheric pressure and a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure, which comprises (1) introducing at a velocity of at least about 5000 feet per minute a stream of ambient-temperature, pressurized liquid ammonia into an expansion chamber, (2) imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia in the chamber, and wherein the expansion chamber is provided with an outlet useful for the removal of gaseous ammonia therefrom which outlet is located above the path of liquid flow and another outlet useful for the removal of cold liquid ammonia therefrom, said outlets being provided at opposite ends of said expansion chamber, (3) directing the flow of the cold substantially ambient or atmospheric pressure liquid ammonia within said expansion chamber to said outlet useful for the withdrawal of cold ambient or atmospheric pressure liquid ammonia from said expansion chamber to effect separation between cold liquid ammonia and cold gaseous ammonia within said expansion chamber, and (4) withdrawing through said outlet useful for the removal of gaseous ammonia a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure and a stream of cold liquid ammonia at substantially ambient or atmospheric pressure via said other outlet.
Claim 2
Independent Claim
255 words
A method for carrying out the substantially adiabatic expansion of a pressurized stream of ambient-temperature liquid ammmonia to produce a stream of cold liquid ammonia at substantially ambient or atmospheric pressure and a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure, which comprises (1) introducing at a velocity of at least about 5000 feet per minute a stream of ambient-temperature, pressurized liquid ammonia into an expansion chamber, (2) imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia in the chamber, and wherein the expansion chamber is provided with an outlet useful for the removal of gaseous ammonia therefrom which outlet is located above the path of liquid flow and another outlet useful for the removal of cold liquid ammonia therefrom, said outlets being provided at opposite ends of said expansion chamber, (3) directing the flow of the cold substantially ambient or atmospheric pressure liquid ammonia within said expansion chamber to said outlet useful for the withdrawal of cold ambient or atmospheric pressure liquid ammonia from said expansion chamber to effect separation between cold liquid ammonia and cold gaseous ammonia within said expansion chamber, and (4) withdrawing through said outlet useful for the removal of gaseous ammonia a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure and a stream of cold liquid ammonia at substantially ambient or atmospheric pressure via said other outlet.
Claim 3
Dependent Claim
28 words
Method of claim 1 wherein the stream of ammonia entering the expansion chamber enters at a flow rate of between about 500 and about 8000 pounds per hour.
Claim 4
Dependent Claim
31 words
Method of claim 2 wherein the expansion chamber has a weight of less than about 100 pounds and the volume of the expansion chamber is less than about 8 cubic feet.
Claim 5
Dependent Claim
69 words
Method as in claim 3 wherein between about 15 and about 25 percent of the pressurized liquid ammonia entering the expansion chamber is converted to gaseous ammonia which cools the balance of the liquid ammonia in the chamber so that it remains in the liquid state at substantially ambient or atmospheric pressures and wherein the volume of the expansion chamer is between about 0.4 and about 2 cubic feet.
Claim 6
Dependent Claim
39 words
Method as in claim 1 wherein the expansion chamber is in the form of a vertically elongated cylinder and wherein the liquid ammonia is introduced through an opening near the mid-point of the vertical height on the cylinder wall.
Claim 7
Dependent Claim
42 words
Method as in claim 5 wherein the bottom of the expansion chamber contains a barrier strip to break the spinning motion and thereby facilitate the discharge of the liquid ammonia from the expansion chamber through the outlet for the cold liquid ammonia.
Claim 8
Dependent Claim
58 words
Method as in claim 1 additionally comprising (1) directing the cold gaseous ammonia stream which leaves the expansion chamber through a mist eliminator to thereby separate liquid ammonia droplets suspended in the gaseous stream, and (2) collecting the separated liquid ammonia from the gaseous stream and combining it with the cold liquid ammonia stream from the expansion chamber.
Claim 9
Dependent Claim
58 words
Method as in claim 7 wherein the expansion chamber and mist eliminator are combined into one unitary apparatus wherein combination apparaus has a total weight of less than 100 pounds and wherein the high pressure liquid ammonia is being introduced into the expansion chamber at a flow rate of from about 3000 to about 8000 pounds per hour.
Claim 10
Dependent Claim
50 words
Method as in claim 8 wherein the expansion chamber is in the form of a vertically elongated cylinder and wherein the high pressure liquid ammonia is introduced through a control valve in a feed line which enters an opening near the mid-point of the vertical height of the cylinder wall.
Claim 11
Dependent Claim
39 words
Method as in claim 7 wherein between about 15 and about 25 weight percent of the high pressure liquid ammonia entering the expansion chamber is converted into gas thereby cooling the liquid and gaseous ammonia in the expansion chamber.
Claim 12
Dependent Claim
43 words
Method as in claim 7 wherein a barrier strip is utilized at the bottom of the expansion chamber to guide the flow of the cold liquid ammonia flowing around the inside of the expansion chamber to the outlet for the cold liquid ammonia.
Claim 13
Dependent Claim
91 words
A method of treating soil comprising (1) producing a stream of cold liquid ammonia at substantially ambient or atmospheric pressure and a separate stream of cold gaseous ammonia at substantially ambient or atmospheric pressure according to the method of claim 7 and (2) dividing the cold liquid ammonia stream into two or more separate streams and applying these separate streams to the ground in a spaced arrangement and the covering the liquid ammonia which has been applied to the soil with additional soil to prevent loss of ammonia into the atmosphere.
Claim 14
Dependent Claim
48 words
Method as in claim 12 wherein the gaseous ammonia stream is directed below the surface of the soil and at the same time the cold liquid ammonia streams and gaseous ammonia streams are regulated to obtain substantially uniform coverage of the soil with ammonia for crop fertilization purposes.
Claim 15
Dependent Claim
44 words
Method as in claim 13 wherein the expansion chamber and liquid and gaseous streams going into the soil are mounted on a field cultivator being used in the field to break up the ground and fertilize the ground in preparation for growing of crops.
Claim 16
Dependent Claim
70 words
Method of applying ammonia to forage for use as animal feed comprising (1) forming a separate cold liquid ammonia stream and a separate cold gaseous ammonia stream at substantially ambient or atmospheric pressures according to the method of claim 7 and (2) applying these ammonia streams to forage in quantities and in a manner to provide substantially uniform distribution of ammonia throughout the forage to provide an improved animal feed.
Claim 17
Independent Claim
268 words
A method for carrying out the substantially adiabatic expansion of a pressurized stream of ambient-temperature liquid ammonia to produce a stream of cold liquid anhydrous ammonia at substantially ambient or atmospheric pressure and a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure, which comprises (1) introducing a stream of ambient temperature, pressurized liquid ammonia at a pressure between about 80 and about 200 psig through a flow control valve tangentially into a cylinderical expansion chamber having a weight of less than about 100 pounds at a location on the chamber walls about midway from the top and bottom of the chamber, (2) imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior circumference of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia in the chamber, and wherein the chamber is provided with an outlet useful for the removal of cold liquid ammonia therefrom, said outlets being provided at opposite ends of said expansion chamber, (3) directing the flow of the cold substantially ambient or atmospheric pressure liquid ammonia from the chamber walls to said outlet useful for the withdrawal of cold ambient or atmospheric pressure liquid ammonia from said expansion chamber to effect separation between cold liquid ammonia and cold gaseous ammonia within said expansion chamber and (4) withdrawing through said outlet useful for the removal of gaseous ammonia a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure and a stream of cold liquid ammonia at substantially ambient or atmospheric pressure via said other outlet.
Claim 18
Independent Claim
268 words
A method for carrying out the substantially adiabatic expansion of a pressurized stream of ambient-temperature liquid ammonia to produce a stream of cold liquid anhydrous ammonia at substantially ambient or atmospheric pressure and a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure, which comprises (1) introducing a stream of ambient temperature, pressurized liquid ammonia at a pressure between about 80 and about 200 psig through a flow control valve tangentially into a cylinderical expansion chamber having a weight of less than about 100 pounds at a location on the chamber walls about midway from the top and bottom of the chamber, (2) imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior circumference of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia in the chamber, and wherein the chamber is provided with an outlet useful for the removal of cold liquid ammonia therefrom, said outlets being provided at opposite ends of said expansion chamber, (3) directing the flow of the cold substantially ambient or atmospheric pressure liquid ammonia from the chamber walls to said outlet useful for the withdrawal of cold ambient or atmospheric pressure liquid ammonia from said expansion chamber to effect separation between cold liquid ammonia and cold gaseous ammonia within said expansion chamber and (4) withdrawing through said outlet useful for the removal of gaseous ammonia a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure and a stream of cold liquid ammonia at substantially ambient or atmospheric pressure via said other outlet.
Claim 19
Dependent Claim
57 words
Method as in claim 16 additionally comprising (1) directing the cold gaseous ammonia stream leaving the expansion chamber through a stationary fan mist eliminator to thereby separate substantially all liquid ammonia droplets from the gaseous ammonia stream and (2) collecting this separated liquid ammonia and combining it with the cold liquid ammonia stream from the expansion chamber.
Claim 20
Dependent Claim
42 words
Method as in claim 17 wherein the liquid ammonia is introduced into the expansion chamber at a flow rate of between about 500 and about 8000 pounds per hour and has an entering velocity of greater than about 5000 feet per minute.
Claim 21
Dependent Claim
37 words
Method as in claim 18 wherein between about 15 and about 25 weight percent of liquid ammonia enter the expansion chamber is converted into gaseous ammonia which cools the liquid and gaseous ammonia in the expansion chamber.
Claim 22
Dependent Claim
47 words
Method as in claim 17 wherein the bottom of the expansion chamber contains a spiral shaped barrier strip attached to the chamber wall and the liquid outlet at the bottom of the chamber in a manner to facilitate smooth flow from the chamber wall to the outlet.
Claim 23
Dependent Claim
15 words
Method as in claim 17 wherein the cylindrical expansion chamber is in a vertical position.
Claim 24
Dependent Claim
32 words
Method as in claim 17 wherein the liquid ammonia is introduced into the expansion chamber by means of an inlet having an average diameter of between about 1/2 and about 4 inches.
Claim 25
Dependent Claim
58 words
Method as in claim 18 wherein the expansion chamber and mist eliminator are combined into one unitary apparatus wherein combination apparatus has a total weight of less than 100 pounds and wherein the high pressure liquid ammonia is being introduced into the expansion chamber at a flow rate of from about 3000 to about 8000 pounds per hour.
Claim 26
Dependent Claim
91 words
A method of treating soil comprising (1) producing a stream of cold liquid ammonia at substantially ambient or atmospheric pressure and a separate stream of cold gaseous ammonia at substantially ambient or atmospheric pressure according to the method of claim 17 and (2) dividing the cold liquid ammonia stream into two or more separate streams and applying these separate streams to the ground in a spaced arrangement and then covering the liquid ammonia which has been applied to the soil with additional soil to prevent loss of ammonia into the atmosphere.
Claim 27
Dependent Claim
48 words
Method as in claim 24 wherein the gaseous ammonia stream is directed below the surface of the soil and at the same time the cold liquid ammonia streams and gaseous ammonia streams are regulated to obtain substantially uniform coverage of the soil with ammonia for crop fertilization purposes.
Claim 28
Dependent Claim
261 words
Apparatus for carrying out the substantially adiabatic expansion of a pressurized stream of ambient-temperature liquid ammonia to produce a stream of cold liquid ammonia at substantially ambient or atmospheric pressure and a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure, which comprises (1) means for introducing at a velocity of at least about 5000 feet per minute a stream of ambient-temperature, pressurized liquid ammonia into an axially elongated expansion chamber, (2) means for imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia formed in the chamber, and wherein the expansion chamber is provided with (3) a first outlet means for the removal of gaseous ammonia therefrom which outlet means is located above the path of liquid flow and (4) a second outlet means useful for the removal of cold liquid ammonia therefrom, said first and second outlet means being provided at opposite ends of said expansion chamber, (5) means for directing the flow of the cold substantially ambient or atmospheric pressure liquid ammonia within said expansion chamber to said second outlet means to effect separation between cold liquid ammonia and cold gaseous ammonia within said expansion chamber, and (6) means for withdrawing through said first outlet means a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure and (7) means for withdrawing a stream of cold liquid ammonia at substantially ambient or atmospheric pressure via said second outlet means.
Claim 29
Dependent Claim
261 words
Apparatus for carrying out the substantially adiabatic expansion of a pressurized stream of ambient-temperature liquid ammonia to produce a stream of cold liquid ammonia at substantially ambient or atmospheric pressure and a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure, which comprises (1) means for introducing at a velocity of at least about 5000 feet per minute a stream of ambient-temperature, pressurized liquid ammonia into an axially elongated expansion chamber, (2) means for imparting a high velocity spinning motion to the liquid ammonia entering the chamber such that rapid flow is produced around the interior of the chamber to thereby provide rapid separation of the liquid and gaseous ammonia formed in the chamber, and wherein the expansion chamber is provided with (3) a first outlet means for the removal of gaseous ammonia therefrom which outlet means is located above the path of liquid flow and (4) a second outlet means useful for the removal of cold liquid ammonia therefrom, said first and second outlet means being provided at opposite ends of said expansion chamber, (5) means for directing the flow of the cold substantially ambient or atmospheric pressure liquid ammonia within said expansion chamber to said second outlet means to effect separation between cold liquid ammonia and cold gaseous ammonia within said expansion chamber, and (6) means for withdrawing through said first outlet means a stream of cold gaseous ammonia at substantially ambient or atmospheric pressure and (7) means for withdrawing a stream of cold liquid ammonia at substantially ambient or atmospheric pressure via said second outlet means.
Claim 30
Dependent Claim
28 words
Apparatus of claim 26 wherein the stream of ammonia entering the expansion chamber enters at a flow rate of between about 500 and about 8000 pounds per hour.
Claim 31
Dependent Claim
60 words
Apparatus as in claim 27 additionally comprising means for directing the cold gaseous ammonia stream leaving the expansion chamber through a stationary fan mist eliminator means to thereby separate substantially all liquid ammonia droplets from the gaseous ammonia stream and means for collecting this separated liquid ammonia and combining it with the cold liquid ammonia stream from the expansion chamber.
Claim 32
Dependent Claim
31 words
Apparatus of claim 28 wherein the expansion chamber has a weight of less than about 100 pounds and the volume of the expansion chamber is less than about 8 cubic feet.
Claim 33
Dependent Claim
70 words
Apparatus as in claim 29 wherein between about 15 and about 25 percent of the pressurized liquid ammonia entering the expansion chamber is converted to a gaseous ammonia which cools the balance of the liquid ammonia in the chamber so that it remains in the liquid state at substantially adiabatic or atmospheric pressures and wherein the volume of the expansion chamber is between about 0.4 and about 2 cubic feet.
Claim 34
Dependent Claim
47 words
Apparatus as in claim 30 wherein the expansion chamber is in the form of a vertically elongated cylinder and wherein the liquid ammonia is introduced through a control valve in a feed line entering an opening near the mid-point of the vertical height of the cylinder wall.
Claim 35
Dependent Claim
86 words
Apparatus as in claim 31 wherein the bottom of the expansion chamber contains a barrier means in the form of a spiral strip with one end of the spiral strip near the chamber wall and the other end of the spiral strip near the second outlet means for the cold liquid ammonia such that the centrifugal flow of cold liquid ammonia at the inner surface of the chamber wall is smoothly directed to the outlet for the cold liquid ammonia in the bottom of the chamber.
Claim 36
Dependent Claim
94 words
Apparatus for treating soil comprising (1) means for producing a stream of cold liquid ammonia at substantially ambient or atmospheric pressure and a separate stream of cold gaseous ammonia at substantially ambient or atmospheric pressure according to claim 28, (2) means for dividing the cold liquid ammonia stream into two or more separate streams, (3) means for applying these separate streams to the ground in a spaced arrangement and (4) means for covering the liquid ammonia which has been applied to the soil with additional soil to prevent loss of ammonia into the atmosphere.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-01-16 | 1981-07-18 | 1982-01-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-01-16 | 1985-07-18 | 1986-01-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-01-16 | 1989-07-18 | 1990-01-17 | $7700.00 | Window Closed / Lapsed |