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US4069024A Expired / Lapsed US ⏱️ 0.0 years remaining

Two-stage gasification system

Assignee: Combustion Engineering Inc
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Filing: 1977-05-09
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Granted: 1978-01-17
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Expires: 1997-05-09
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Abstract

Abstract A two-stage coal gasification system in which high temperature synthesis gas produced in a downflowing gasifier containing a high quantity of sensible heat is subsequently reacted in a pyrolyzing reactor with a charge of carbonaceous material and limestone at a reduced temperature to utilize the sensible heat contained in the gas and simultaneously produce an increase in the hydrocarbon content thereof.

Inventors

  • 👤 John Henry Fernandes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 14:03
CPC Classifications
C; C10; C10J; C10J3/00; C10J3/58; C10J3/60; C10J3/64; C10J3/66; C10B; C10B49/00; C10B49/02; C10B49/04; C10B49/06; C10J3/02; C10J3/06; C10J3/08; C10J3/20; C10J3/46; C10J3/48; C10J3/482; C10K; C10K1/00; C10K1/04; C10K1/046; C10J2300/00; C10J2300/09; C10J2300/0903; C10J2300/0909; C10J2300/18; C10J2300/1807; C10J2300/1823

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 283 words
A method of producing a fuel gas from a carbonaceous material which comprises the steps of: a. providing an upright gasifier with an oxidation zone intermediate a preheating zone and a subjacent reducing zone, b. introducing devolatilized carbonaceous material and limestone to said preheating zone of the gasifier, c. oxidizing the carbonaceous material to form a gaseous product, a char containing carbon, and a molten slag, d. reacting said gaseous product with steam and carbon from said char to form a hot reducing type synthesis gas, e. providing a vertical shaft pyrolyzing furnace having a "restricted throat" section intermediate a disengaging section and a subjacent reaction section, f. introducing the hot synthesis gas from the bottom of the gasifier to the bottom portion of the pyrolyzing furnace in the reaction thereof, g. introducing a charge of carbonaceous material and limestone to the top of the pyrolyzing furnace in the disengaging section thereof, h. maintaining an upward flow of said hot synthesis gas through the pyrolyzing furnace in opposition to the descending flow of carbonaceous material and limestone whereby said carbonaceous material is heated and partially volatilized to permit the volatile constituents thereof to combine with the synthesis gas passing therethrough to increase the hydrocarbon content thereof before it is exhausted as a final product gas said restricted throat section being formed so as to cause the descending carbonaceous material to be slowed down at first, and then be propelled upward and outward thereby causing circulation of the carbonaceous material in the form of a spouting bed, i. and transferring devolatilized carbonaceous material and limestone from the bottom of the pyrolyzing furnace to the gasifier as feedstock for the gasifier according to step (b).
Claim 2
Independent Claim 283 words
A method of producing a fuel gas from a carbonaceous material which comprises the steps of: a. providing an upright gasifier with an oxidation zone intermediate a preheating zone and a subjacent reducing zone, b. introducing devolatilized carbonaceous material and limestone to said preheating zone of the gasifier, c. oxidizing the carbonaceous material to form a gaseous product, a char containing carbon, and a molten slag, d. reacting said gaseous product with steam and carbon from said char to form a hot reducing type synthesis gas, e. providing a vertical shaft pyrolyzing furnace having a "restricted throat" section intermediate a disengaging section and a subjacent reaction section, f. introducing the hot synthesis gas from the bottom of the gasifier to the bottom portion of the pyrolyzing furnace in the reaction thereof, g. introducing a charge of carbonaceous material and limestone to the top of the pyrolyzing furnace in the disengaging section thereof, h. maintaining an upward flow of said hot synthesis gas through the pyrolyzing furnace in opposition to the descending flow of carbonaceous material and limestone whereby said carbonaceous material is heated and partially volatilized to permit the volatile constituents thereof to combine with the synthesis gas passing therethrough to increase the hydrocarbon content thereof before it is exhausted as a final product gas said restricted throat section being formed so as to cause the descending carbonaceous material to be slowed down at first, and then be propelled upward and outward thereby causing circulation of the carbonaceous material in the form of a spouting bed, i. and transferring devolatilized carbonaceous material and limestone from the bottom of the pyrolyzing furnace to the gasifier as feedstock for the gasifier according to step (b).
Claim 3
Dependent Claim 38 words
The method of claim 1 including the step of maintaining the temperature of the devolatilized carbonaceous material being transferred from the pyrolyzer to the gasifier at a temperature that does not exceed the fusion temperature of such material.
Claim 4
Dependent Claim 27 words
The method of claim 1 including the step of maintaining the temperature of the synthesis gas exhausting from the gasifier at from 2000° F to 2500° F.
Claim 5
Dependent Claim 37 words
The method of claim 3 including the step of maintaining the temperature of the synthesis gas being directed into the pyrolyzer furnace by the admixture of a quantity of cooled product gas exhausting from the pyrolyzing furnace.
Claim 6
Dependent Claim 47 words
The method of claim 4 including the step of maintaining the temperature of the product gas exhausting from the pyrolyzer from 1200° F to 1300° F to insure the vaporization of volatile matter contained in the char and in the reducing gas but to avoid uncontrolled agglomeration.
Claim 7
Dependent Claim 50 words
The method as defined in claim 5 wherein the charge of carbonaceous material and limestone added into the pyrolyzer furnace first traverses a free falling disengaging zone where said charge is flash heated before it descends to a restricted throat section that retards flow therethrough and provides prolonged heating thereof.
Claim 8
Dependent Claim 65 words
The method of claim 1 including cooling the product gas by directing it in heat exchange relation with the carbonaceous material and limestone being directed into the pyrolyzing furnace, and tempering the synthesis gas with cool product gas prior to its entry into the bottom of the pyrolyzer whereby the temperature of the product gas exhausting from the pyrolyzer does not exceed about 1300° F.
Claim 9
Dependent Claim 36 words
The method of claim 7 including passing the product gas exhausting from the pyrolyzer through cleaning apparatus that removes particulate matter therefrom, and directing said particulate matter into the synthesis gas in advance of said pyrolyzer.
Claim 10
Dependent Claim 26 words
The method of claim 1 including passing said gas mixture through condensing apparatus in heat exchange relation with a cooler fluid to remove tarry liquids therefrom.
Claim 11
Dependent Claim 30 words
The method of claim 9 including the step of adding tarry liquids condensed from the product gas to the carbonaceous material and limestone passing from the pyrolyzer to the gasifier.
Claim 12
Dependent Claim 37 words
The method of claim 1 including the step of bypassing a portion of the char descending through the pyrolyzing furnace around the throat therein whereby it will be moved from the disengaging section to the reaction section.
Claim 13
Dependent Claim 40 words
The method of claim 11 including the step of compressing the char by-passing the throat section of the pyrolyzing furnace to form a high density cake of char before it is introduced into the reaction section of the pyrolyzing furnace.
Claim 14
Dependent Claim 31 words
The method of claim 12 including the step of adding tarry liquids removed from the product gas to the char being bypassed around said throat to provide a bonding agent therefor.

References Cited (Backward Citations)

US2657124A Cited
US3136705A Cited
US3782913A Cited
US3847563A Cited
US3920417A Cited
US3981690A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-16 1981-07-18 1982-01-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-16 1985-07-18 1986-01-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-16 1989-07-18 1990-01-17 $7700.00 Window Closed / Lapsed

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